摘要:
A particulate graft polymer comprising (a) a core formed by a crosslinked homopolymer of a conjugated diene or a copolymer thereof with up to 10% by weight of styrene or acrylonitrile; (b) a first shell formed by a crosslinked homopolymer of an acrylic acid alkyl ester or a copolymer thereof with up to 30% by weight of vinyl monomers; (c) a second shell formed by a polymer of resin-forming monomers, a process for manufacturing these graft polymers by means of a multi-stage emulsion polymerization, and their application as molding compositions, optionally together with rigid thermoplastic resins.
摘要:
A process for the continuous processing of vinyl polymer latices to produce thermoplastically processible vinyl polymer powder by coagulating a stream of a vinyl polymer latex by the addition of a stream of a coagulant with intensive mixing and shearing in a cascade of vessels at an average residence time per vessel of 10 to 60 minutes and at temperatures from 50 to 120.degree. C., volatile auxiliary substances and residual monomers in the polymer being optionally removed by steam distillation and part of the serum separated from the vinyl polymer being added to the stream of coagulant.
摘要:
A thermoplastic moulding composition comprising a polymer mixture of (A) 25 to 95% by weight of a graft polymer of 70 to 30% by weight of a mixture of styrene (95 to 50% by weight) and acrylonitrile (5 to 50% by weight) on 30 to 70% by weight of polybutadiene or a butadiene-styrene copolymer, and (B) 5 to 75% by weight of a terpolymer containing 10 to 30 parts by weight of acrylonitrile, 7.5 to 15 parts by weight of maleic acid anhydride, and 82.5 to 55 parts by weight of styrene in copolymerized form.
摘要:
A thermoplastic molding composition having improved flow, toughness. and heat distortion comprising a polymer mixture of (A) 25 to 95% by weight of a graft polymer of 70 to 30% by weight of a mixture of styrene (95 to 50% by weight) and acrylonitrile (5 to 50% by weight) on 30 to 70% by weight of an EPDM-rubber, and (B) 50 to 75% by weight of a terpolymer of acrylonitrile, maleic acid anhydride and styrene, the terpolymer containing 10 to 30 parts by weight of acrylonitrile, 7.5 to 15 parts by weight of maleic acid anhydride, and 82.5 to 55 parts by weight of styrene in copolymerised form.
摘要:
This invention relates to thermostable thermoplastic moulding compounds consisting of a thermoplastic aromatic polycarbonate resin, a graft polymer and optionally a thermoplastic vinyl polymer wherein the graft or vinyl polymer is emulsion polymerized with an emulsifier which is the reaction product of 2 mols of certain carboxylic anhydrides and 1 mole of certain diols.
摘要:
Graft polymers of vinyl monomers or vinyl monomer mixtures on block copolymers of recurring structural units from the polysiloxane series and recurring structural units from the series comprising homo- and copolymers of conjugated dienes as grafting bases.
摘要:
Block copolymers of recurring structural units of the series of polysiloxanes and recurring structural units of the series of aliphatic polyesters, polyethers or polyetheresters with rubber properties, the polymeric block-forming polymers in each case producing rubber-type products with glass transition temperatures below practical temperatures of use and a process for the production thereof.
摘要:
Trialkylsilyloxy-1,1-diphenyl ethylenes corresponding to general formula I, new polymers produced therewith terminated by aryl trialkylsilyl ether groups or by phenolic hydroxyl groups and a process for the production of these polymers by anionic polymerization ##STR1## in which R.sup.1, R.sup.2 .dbd.H, C.sub.1 -C.sub.4 alkyl, OCH.sub.3,R.sup.3 .dbd.H, C.sub.1 -C.sub.4 alkyl, O--C.sub.1 -C.sub.4 alkyl,R.sup.4 .dbd.H, C.sub.1 -C.sub.4 alkyl,R.sup.5 .dbd.C.sub.1 -C.sub.4 alkyl,R.sup.6 .dbd.H, C.sub.1 -C.sub.4 alkyl.
摘要:
Copolymers of blocks of polymers of cyclic aliphatic carbonates, cyclic aliphatic esters or cyclic aliphatic carbonates and cyclic aliphatic esters on the one hand and blocks of polymers of cyclic aromatic carbonates on the other hand and a process for their production by multistage polymerization, in which a block polymer is initially prepared from the aliphatic monomer and the aromatic polymer is produced in the presence of this block.
摘要:
Multi-block copolymers of recurring structural units of polysiloxanes and recurring structural units of aliphatic polyesters, polyethers or polyetheresters with rubber properties, the individual polymeric blocks constituting rubber-type products with glass transition temperatures below practical usefulness and a process for their production.