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    Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators
    43.
    发明授权
    Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
    酰化氨基苯基磺酰脲 作为除草剂和植物生长调节剂的制备和使用

    公开(公告)号：US5658854A

    公开(公告)日：1997-08-19

    申请号：US268274

    申请日：1994-06-30

    Applicant: Gerhard Schnabel ,  Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer

    Inventor： Gerhard Schnabel ,  Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer

    IPC: C07D239/42 ,  A01N47/36 ,  A01N47/46 ,  A01P13/02 ,  C07C309/89 ,  C07C311/39 ,  C07C311/65 ,  C07D239/47 ,  C07D239/48 ,  C07D251/44 ,  C07D251/46 ,  C07D251/48 ,  C07D251/52 ,  C07D521/00 ,  C07D239/69 ,  A01N43/54

    CPC classification number: C07D521/00 ,  A01N47/36 ,  C07C309/89 ,  C07C311/39 ,  C07C311/65

    Abstract: Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).

    Abstract translation: 酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2） （G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基， 或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长 农作物的监管者。 类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯 杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

    Crop-protecting compositions containing isoxazolines or isothiazdines, novel isoxazolines, and their preparation
    44.
    发明授权
    Crop-protecting compositions containing isoxazolines or isothiazdines, novel isoxazolines, and their preparation 失效
    含有异恶唑啉或异噻嗪类的抗坏血酸组合物，新异恶唑及其制备方法

    公开(公告)号：US5536698A

    公开(公告)日：1996-07-16

    申请号：US467934

    申请日：1995-06-06

    Applicant: Heinz-Josef Loher ,  Klaus Bauer ,  Hermann Bieringer

    Inventor： Heinz-Josef Loher ,  Klaus Bauer ,  Hermann Bieringer

    IPC: A01N25/32 ,  C07D261/04 ,  C07D275/02 ,  C07D275/03 ,  C07F7/08

    CPC classification number: C07D275/03 ,  A01N25/32 ,  C07D261/04 ,  C07F7/0812

    Abstract: Crop-protecting compositions containing isoxazolines or isothiazolines, novel isoxazolines and isothiazolines, and their preparationCrop-protecting compositions which contain isoxazolines or isothiazolines of the formula ##STR1## in which X is oxygen or sulfur, R is hydroxyl or has the meanings given in the description, Z is halogen, nitro, cyano, in each case optionally substituted alkyl, alkoxy, alkylmercapto, cycloalkyl, amino, hydroxymethyl, alkylamino, dialkylamino, alkoxymethyl, aryl or aryloxy and n is an integer from 0 to 5. Novel isoxazolines and isothiazolines of this formula, a process for their preparation, and their use as a protection against phytotoxic secondary effects of herbicides.

    Abstract translation: 含有异恶唑啉或异噻唑啉的抗割草组合物，新的异恶唑啉和异噻唑啉及其制备含有式为“IMAGE”的异恶唑啉或异噻唑的作物保护组合物，其中X为氧或硫，R为羟基或具有 描述，Z是卤素，硝基，氰基，在各种情况下是任选取代的烷基，烷氧基，烷基巯基，环烷基，氨基，羟甲基，烷基氨基，二烷基氨基，烷氧基甲基，芳基或芳氧基，n是0-5的整数。新的异恶唑烷和异噻唑啉 的这种配方，其制备方法及其作为防止除草剂植物毒性次要作用的用途。

    Substituted isoxazolines, process for their preparation, composition containing them, and their use of safeners
    46.
    发明授权
    Substituted isoxazolines, process for their preparation, composition containing them, and their use of safeners 失效
    取代的异恶唑啉，其制备方法，含有它们的组合物及其使用安全剂

    公开(公告)号：US5516750A

    公开(公告)日：1996-05-14

    申请号：US306110

    申请日：1994-09-14

    Applicant: Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer

    Inventor： Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer

    IPC: C07D261/04 ,  A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/80 ,  A01N47/36 ,  A01P13/00 ,  C07D413/04 ,  C07D413/06 ,  A01N43/72 ,  C07D261/02

    CPC classification number: A01N25/32 ,  A01N43/80

    Abstract: Substituted isoxazolines, process for their preparation, compositions containing them, and their use as safeners.Compounds of the formula (I) and salts thereof, ##STR1## in which R.sup.1 is carboxyl, formyl or another acyl radical or a derivative of the last-mentioned 3 groups,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.8 -alkenyloxy, C.sub.2 -C.sub.8 -alkynyloxy, C.sub.1 -C.sub.18 -alkylthio, C.sub.2 -C.sub.8 -alkenylthio, each of the last-mentioned 9 radicals in each case being unsubstituted or substituted, or (C.sub.1 -C.sub.8 -alkoxy)carbonyl, andR.sup.3 and R.sup.4 independently of one another are an aliphatic, araliphatic or heteroaraliphatic radical having 1 to 30 carbon atoms which is unsubstituted or substituted by one or more functional groups, oran aromatic or heteroaromatic radical which is unsubstituted or substituted,are suitable as safenets for pesticides, preferably herbicides, in crop plants. The compounds can be prepared from alkenes (II) and nitrile oxides (III) by the process of claim 6.

    Abstract translation: 取代的异恶唑啉，其制备方法，含有它们的组合物及其作为安全剂的用途。 式（I）化合物及其盐，其中R1是羧基，甲酰基或另一个酰基或最后提到的3个基团的衍生物，其中R 2是氢，卤素，C 1 -C 18 - 烷基 ，C 3 -C 8 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 8 - 炔基，C 1 -C 18 - 烷氧基，C 2 -C 8 - 烯氧基，C 2 -C 8 - 炔氧基，C 1 -C 18烷硫基， 在每种情况下最后提及的9个基团是未取代的或取代的，或（C 1 -C 8 - 烷氧基）羰基，且R 3和R 4彼此独立地是具有1至30个碳原子的脂族，芳脂族或杂脂族基团，其是未取代的 或被一个或多个官能团取代，或未取代或取代的芳族或杂芳族基团适合作为农作物的保藏剂，优选除草剂在作物植物中。 化合物可以通过权利要求6的方法由烯烃（II）和氧化腈（III）制备。

    N-sultamsulfonamides
    49.
    发明授权
    N-sultamsulfonamides 失效
    N-SULTAMSULFONAMIDES

    公开(公告)号：US5103004A

    公开(公告)日：1992-04-07

    申请号：US749158

    申请日：1991-08-23

    Applicant: Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer ,  Helmut Burstell

    Inventor： Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer ,  Helmut Burstell

    IPC: A01N47/36 ,  C07D417/12 ,  C07D521/00

    CPC classification number: C07D521/00 ,  A01N47/36

    Abstract: Heterocyclically substituted N-sultamsulfonamides, processes for their preparation and their use as herbicides and plant growth regulators.Compounds of the formula I or their salts ##STR1## wherein R.sup.1 and R.sup.2 denote H, halogen, alkyl, alkenyl, alkynyl or alkoxy, which can be substituted, or denote --(CH.sub.2).sub.n --COOR.sup.11 ;R.sup.3 denotes H, alkyl, alkenyl or alkynyl;R.sup.4 denotes a heterocyclic radical of the formulae ##STR2## where E is CH or N; X is O or S and a, b, c, d, e in each case denote 0, 1 or 2, with the proviso that c+d+e.gtoreq.2, possess excellent herbicidal and plant growth-regulating properties.

    1,2-disubstituted piperidines, processes for their preparation and their use in plant protection
    50.
    发明授权
    1,2-disubstituted piperidines, processes for their preparation and their use in plant protection 失效
    1,2-二取代的哌啶，其制备方法及其在植物保护中的应用

    公开(公告)号：US4838931A

    公开(公告)日：1989-06-13

    申请号：US3202

    申请日：1987-01-14

    Applicant: Rainer Liebl ,  Michael Frey ,  Hilmar Mildenberger ,  Klaus Bauer ,  Hermann Bieringer

    Inventor： Rainer Liebl ,  Michael Frey ,  Hilmar Mildenberger ,  Klaus Bauer ,  Hermann Bieringer

    IPC: A01N57/16 ,  A01N47/36 ,  A01N57/32 ,  C07D211/22

    CPC classification number: C07D211/22 ,  A01N47/36

    Abstract: 1,2-Disubstituted piperidines of the general formula I ##STR1## in which X denotes oxygen or sulfur; R denotes alkyl, R.sup.1 and R.sup.2 denote hydrogen, alkyl or benzyl, R.sup.3 denotes hydrogen, (substituted) alkyl, (substituted) benzyl or a radical of the formulae ##STR2## Y and X denote S or O; Z denotes S, O or NR.sup.1 ; R.sup.4 denotes hydrogen, (substituted) alkyl, (substituted) phenyl, (substituted) naphthyl or (substituted) pyridyl, A denotes (substituted) phenyl or (substituted) naphthyl and m denotes 0, 1 or 2, possess advantageous herbicidal properties.

    Abstract translation: 其中X表示氧或硫的通式I的1,2-二取代哌啶; R表示烷基，R 1和R 2表示氢，烷基或苄基，R 3表示氢，（取代的）烷基，（取代的）苄基或式的基团Y表示S或O; Z表示S，O或NR1; R 4表示氢，（取代的）烷基，（取代的）苯基，（取代的）萘基或（取代的）吡啶基，A表示（取代的）苯基或（取代的）萘基，m表示0,1或2，具有有利的除草性质。

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