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    Limited play optical devices with interstitial reactive layer and methods of making same
    41.
    发明授权
    Limited play optical devices with interstitial reactive layer and methods of making same 失效
    有限播放具有间隙反应层的光学器件及其制造方法

    公开(公告)号：US06756103B2

    公开(公告)日：2004-06-29

    申请号：US10163474

    申请日：2002-06-05

    申请人： Robert F. Thompson ,  Neil Exter ,  Yannis Bakos ,  Richard A. Minns ,  Larry Takiff

    发明人： Robert F. Thompson ,  Neil Exter ,  Yannis Bakos ,  Richard A. Minns ,  Larry Takiff

    IPC分类号： B32B302

    CPC分类号： G11B20/00608 ,  G06F21/80 ,  G11B7/24038 ,  G11B7/244 ,  G11B7/246 ,  G11B7/252 ,  G11B7/253 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2542 ,  G11B7/256 ,  G11B7/257 ,  G11B7/2578 ,  G11B7/258 ,  G11B7/259 ,  G11B7/2595 ,  G11B7/263 ,  G11B20/00086 ,  G11B20/00586 ,  G11B20/00927 ,  G11B23/282 ,  Y10T428/21 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31551

    摘要： Methods and apparatus are provided for making an optically readable storage media in which the reading beam passes through a bonding layer configured with a reactive material that transforms from an optically transparent state to an optically opaque state after exposure to a predefined stimulus, thereby inhibiting access to the data encoded on the optically readable storage media. The method includes steps of synthesizing a blocked dye combining the blocked dye with a carrier material curing the resultant combination deblocking the dye to produce a reduced dye in the resultant bonding layer exposing the optically readable storage media with the reactive material in its bonding layer to a predetermined stimulus. In a further aspect of the present invention methods and apparatus are provided for making an optically readable storage media wherein the reading light passes through the bonding layer and the data encoded information is encoded on the L1 substrate. In yet another aspect of the present invention methods and apparatus are provided for making an optically readable storage media with at least two mechanisms for limiting access to the encoded data of the optically readable storage media.

    摘要翻译： 提供了用于制造光学可读存储介质的方法和装置，其中读取光束通过配置有在暴露于预定义的刺激之后从光学透明状态转换为光学不透明状态的反应性材料的结合层，从而禁止访问 编码在光学可读存储介质上的数据。 该方法包括以下步骤：合成封闭的染料与封端染料组合的载体材料，固化所得组合物解封染料以在所得粘合层中产生还原染料，将光学可读存储介质与其粘结层中的反应性材料暴露于 预定刺激。 在本发明的另一方面，提供了用于制造光学可读存储介质的方法和装置，其中读取光通过结合层，并且数据编码信息被编码在L1基板上。 在本发明的另一方面，提供了用于制造具有用于限制对光学可读存储介质的编码数据的访问的至少两种机制的光学可读存储介质的方法和装置。

    Process and composition for generation of acid
    42.
    发明授权
    Process and composition for generation of acid 有权
    生成酸的方法和组成

    公开(公告)号：US06307085B1

    公开(公告)日：2001-10-23

    申请号：US09627939

    申请日：2000-07-28

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： C07F902

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。

    Process and composition for generation of acid
    43.
    发明授权
    Process and composition for generation of acid 失效
    生成酸的方法和组成

    公开(公告)号：US5914213A

    公开(公告)日：1999-06-22

    申请号：US944284

    申请日：1997-10-06

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/004 ,  G03C1/492 ,  G03C1/494 ,  G03C1/76

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736 5,441,850和5,453,345。

    Polymers containing decahalopentacyclodecyl groups
    47.
    发明授权
    Polymers containing decahalopentacyclodecyl groups 失效
    聚合物含有十氢五环癸基

    公开(公告)号：US4426505A

    公开(公告)日：1984-01-17

    申请号：US352085

    申请日：1982-02-25

    申请人： Richard A. Minns

    发明人： Richard A. Minns

    IPC分类号： C08F20/24 ,  C08F20/30 ,  C08F20/58 ,  G02B1/04

    CPC分类号： C08F20/58 ,  C08F20/24 ,  C08F20/30 ,  G02B1/04

    摘要： New polymers are disclosed comprising recurring units of the formula ##STR1## wherein R is hydrogen or lower alkyl containing from 1 to 5 carbon atoms, L is a divalent linking group, and each X is independently chloro or bromo. The polymers are capable of providing a relatively high index of refraction in combination with a relatively high Abbe number and can be utilized as raw materials in the manufacture of plastic optical articles or elements such as lenses or prisms and in the manufacture of optical films and coatings.

    摘要翻译： 公开了新的聚合物，其包含式IMA的重复单元，其中R是氢或含有1至5个碳原子的低级烷基，L是二价连接基团，并且每个X独立地是氯或溴。 聚合物能够提供相对较高的折射率与较高的阿贝数相结合，并且可用作塑料光学制品或诸如透镜或棱镜的元件的制造中的原材料，并且在制造光学膜和涂层 。