摘要:
Olefin polymerization catalyst systems including a high molecular weight catalyst compound and a low molecular weight catalyst compound, and methods of making same are provided. High molecular weight catalysts include metallocene catalysts and low molecular weight catalysts include non-metallocene compounds including biphenyl phenol compounds. Generally catalyst systems may include less than about 5.0 mol % of the high molecular weight catalyst compound relative to said low molecular weight catalyst. Methods for olefin polymerization including the aforementioned catalyst systems, and polyolefins and products made therefrom.
摘要:
A film comprising a polyethylene composition, the polyethylene composition in one embodiment comprising a high molecular weight component having a weight average molecular weight of greater than 50,000 amu and a low molecular weight component having a weight average molecular weight of less than 50,000 amu; the polyethylene composition possessing a density of between 0.940 and 0.970 g/cm3, and an I21 value of less than 20 dg/min; characterized in that the polyethylene composition extrudes at an advantageously high specific throughput at an advantageously low melt temperature, and wherein the film has a gel count of less than 100.
摘要翻译:一种包含聚乙烯组合物的膜,一个实施方案中的聚乙烯组合物包含重均分子量大于50,000amu的高分子量组分和重均分子量小于50,000amu的低分子量组分; 所述聚乙烯组合物具有0.940至0.970g / cm 3的密度和小于20dg / min的I 21 N值; 其特征在于,所述聚乙烯组合物在有利的低熔融温度下以有利的高比生产量挤出,并且其中所述膜的凝胶计数小于100。
摘要:
A film comprising a polyethylene composition, the polyethylene composition in one embodiment comprising a high molecular weight component having a weight average molecular weight of greater than 50,000 amu and a low molecular weight component having a weight average molecular weight of less than 50,000 amu; the polyethylene composition possessing a density of between 0.940 and 0.970 g/cm3, and an I21 value of less than 20 dg/min; characterized in that the polyethylene composition extrudes at an advantageously high specific throughput at an advantageously low melt temperature, and wherein the film has a gel count of less than 100.
摘要:
Methods of tailoring polyethylenes are contemplated utilizing 0.5 to 7.95 volume percent oxygen containing gases. The tailoring occurs in a melt-conveying zone of a mixer/extruder, and not in the feed or melting zones of a mixer/extruder. The effect of tailoring is to increase elasticity (G′/G″) of the polyethylenes more than 10 percent over similar polyethylenes that are extruded/mixed in the substantial absence of oxygen of oxygen containing gases.
摘要:
A film comprising a polyethylene composition, the polyethylene composition in one embodiment comprising a high molecular weight component having a weight average molecular weight of greater than 50,000 amu and a low molecular weight component having a weight average molecular weight of less than 50,000 amu; the polyethylene composition possessing a density of between 0.940 and 0.970 g/cm3, and an I21 value of less than 20 dg/min; characterized in that the polyethylene composition extrudes at an advantageously high specific throughput at an advantageously low melt temperature, and wherein the film has a gel count of less than 100.
摘要翻译:一种包含聚乙烯组合物的膜,一个实施方案中的聚乙烯组合物包含重均分子量大于50,000amu的高分子量组分和重均分子量小于50,000amu的低分子量组分; 所述聚乙烯组合物具有0.940至0.970g / cm 3的密度和小于20dg / min的I 21 N值; 其特征在于,所述聚乙烯组合物在有利的低熔融温度下以有利的高比生产量挤出,并且其中所述膜的凝胶计数小于100。
摘要:
A process for the preparation of an unsaturated polyester which comprises (i) reacting an organic diol with a cyclic akylene carbonate in the presence of a first catalyst to thereby form a polyalkoxy diol, and (ii) optionally adding thereto a further amount of cyclic alkylene carbonate in the presence of a second catalyst, and (iii) subsequently polycondensing the resulting mixture with a dicarboxylic acid.