公开(公告)号：US6040357A

公开(公告)日：2000-03-21

申请号：US84918

申请日：1998-05-28

申请人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

发明人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

IPC分类号： G02B6/44 ,  C03C25/10 ,  C09D11/10 ,  C09D11/00 ,  C03C17/34 ,  C09D11/02 ,  G02B1/12 ,  G02B6/04

CPC分类号： C09D11/101 ,  C03C25/1055 ,  C03C25/1065

摘要： Provided is radiation-curable ink composition containing a radiation-curable carrier system containing at least one radiation-curable monomer or oligomer and at least one pigment dispersed in the radiation-curable carrier system in an amount sufficient to provide a color which is visible without magnification. The pigment is substantially insoluble in the radiation-curable carrier system whereby the particulate shape of the pigment is substantially retained in the radiation-curable carrier system. The pigment having a particle size that substantially avoids pigment induced microbending of an optical glass fiber coated with the ink coating.

摘要翻译： 本发明提供的辐射固化油墨组合物含有可辐射固化的载体体系，该系统含有至少一种可辐射固化的单体或低聚物和至少一种分散在可辐射固化的载体体系中的颜料，其量足以提供在不放大的情况下可见的颜色 。 颜料基本上不溶于可辐射固化的载体体系，由此颜料的颗粒形状基本上保留在可辐射固化的载体体系中。 该颜料的粒径基本上避免颜料引起涂覆有油墨涂层的光学玻璃纤维的微弯曲。

公开(公告)号：US5891930A

公开(公告)日：1999-04-06

申请号：US694781

申请日：1996-08-09

申请人： Stephen C. Lapin ,  Edward J. Murphy

发明人： Stephen C. Lapin ,  Edward J. Murphy

IPC分类号： C03C25/10 ,  C08F2/50 ,  C08G59/30 ,  C08G59/68 ,  C09D4/06

CPC分类号： C08G59/68 ,  C03C25/106 ,  C08G59/306 ,  C09D4/06

摘要： Provided is a radiation-curable optical glass fiber coating composition adapted to provide the combination of properties of:(i) enhanced resistance to thermal degradation when suitably cured; and(ii) a viscosity sufficient to provide a surface substantially free-of pitting.The composition is formulated from components including:(A) at least one epoxy silicone monomer or oligomer which is crosslinkable via actinic radiation, or mixture thereof;(B) at least one thermoplastic resin which is substantially unreactive to actinic radiation and which is soluble or dispersible in component (A), said thermoplastic resin being present in an amount to provide said composition with a viscosity suitable for application to an optical glass fiber; and(C) a catalytically effective amount of a photoinitiator for catalyzing the crosslinking reaction of component (A) and which is soluble or dispersible in component (A) or a mixture of said component (A) and said thermoplastic resin. Also provided is a method of making the radiation-curable coating composition and a coated optical glass fiber.

摘要翻译： 本发明提供一种可辐射固化光学玻璃纤维涂层组合物，其适用于提供以下特性的组合：（i）当适当固化时增强耐热降解性; 和（ii）足以提供基本上没有点蚀的表面的粘度。 组合物由以下组分配制，包括：（A）至少一种通过光化辐射可交联的环氧硅氧烷单体或低聚物，或其混合物; （B）至少一种对光化辐射基本上不反应并且可溶于或分散在组分（A）中的热塑性树脂，所述热塑性树脂的存在量为所述组合物提供适用于光学玻璃纤维的粘度 ; 和（C）催化有效量的用于催化组分（A）的交联反应并且可溶于或可分散在组分（A）中的光引发剂或所述组分（A）和所述热塑性树脂的混合物。 还提供了制造可辐射固化涂料组合物和涂覆的光学玻璃纤维的方法。

公开(公告)号：US5416126A

公开(公告)日：1995-05-16

申请号：US19365

申请日：1993-02-17

申请人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

发明人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

IPC分类号： C08F2/50 ,  D21H17/53 ,  D21H25/06 ,  D21H27/06 ,  G03G7/00 ,  B32B27/10 ,  C08F263/06

CPC分类号： D21H27/06 ,  D21H17/53 ,  D21H25/06 ,  G03G7/004 ,  Y10T428/2933 ,  Y10T428/3179 ,  Y10T428/31794

摘要： A composition which is cured upon exposure to ultraviolet light in the absence of solvent is disclosed. The liquid composition is prepared by combining a liquid maleate polyester and at least one of a vinyl compound and an allyl functional compound. A photoinitiator is then added to the polymerizable liquid composition. A substrate is impregnated with the polymerizable liquid composition and exposed to actinic energy of a sufficient dosage for a sufficient amount of time to polymerize the composition to a sufficient degree to impart useful properties to the substrate. The composition can be used as a binder for fiberglass insulation, in the manufacture of transparent or semi-transparent paper and to manufacture paper for use in photocopy machines.

摘要翻译： 公开了在不存在溶剂的情况下暴露于紫外线时固化的组合物。 通过将液体马来酸酯聚酯与乙烯基化合物和烯丙基官能化合物中的至少一种组合来制备液体组合物。 然后将光引发剂加入到可聚合液体组合物中。 用可聚合液体组合物浸渍基质并暴露于足够量的光化能量足够的时间以使组合物充分聚合以赋予基底有用的性质。 该组合物可用作玻璃纤维绝缘的粘合剂，用于制造透明或半透明纸并制造用于复印机的纸。

公开(公告)号：US4761435A

公开(公告)日：1988-08-02

申请号：US914989

申请日：1986-10-03

申请人： Edward J. Murphy ,  Ronald S. Conti

发明人： Edward J. Murphy ,  Ronald S. Conti

IPC分类号： C08F2/50 ,  C08F299/04 ,  C09D4/00 ,  C09D4/06 ,  C09D5/00 ,  C08G73/02 ,  C08F265/06

CPC分类号： C09D4/00 ,  C08F299/0435 ,  C09D4/06 ,  Y10S522/904

摘要： Ultraviolet-curable ethylenically unsaturated liquid coating composition are disclosed which consist essentially of:1--polyethylenically unsaturated material in which the ethylenically unsaturated groups are polymerizable groups which are not (meth)acrylate groups;2--a polyamine resin, preferably a polytertiary amine resin; and3--an aryl ketone photosensitizer.

摘要翻译： 公开了紫外线固化型烯属不饱和液体涂料组合物，其基本上由以下物质组成：其中烯属不饱和基团是不是（甲基）丙烯酸酯基团的可聚合基团的1-多烯属不饱和物质; 2-a多胺树脂，优选多胺胺树脂; 和3-芳基酮光敏剂。

公开(公告)号：US4113597A

公开(公告)日：1978-09-12

申请号：US745240

申请日：1976-11-26

申请人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

发明人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

IPC分类号： C25D13/06 ,  C09D5/44 ,  C25D13/10

CPC分类号： C09D5/4411

摘要： A simplified method for the cathodic electrodeposition of polyamine resin from a dispersion thereof in an aqueous electrocoating bath is provided in which the polyamine is selected to be stably dispersible in water in the form of a salt with a solubilizing acid at a pH of from 6.0-7.5, and this polyamine resin is substantially completely neutralized with carbonic acid and dispersed in water in the form of an amine carbonate or bicarbonate. A unidirectional electrical current is passed through an aqueous electrocoating bath containing the amine carbonate or bicarbonate to deposit the polyamine resin at the cathode and cause the release of carbon dioxide. In preferred practice, a proportion of the amine groups in the polyamine resin within the bath, low enough to maintain the pH of the bath at a pH of about 6.0 or higher, is reacted with a relatively nonvolatile solubilizing acid, and the polyamine resin solids in the electrocoating bath are replenished by adding to bath polyamine resin substantially completely neutralized with carbonic acid.

摘要翻译： 提供了一种用于将多胺树脂从其分散体阴极电沉积在水性电涂浴中的简化方法，其中选择多胺以与6.0％的pH下的增溶酸形式的盐稳定分散在水中， 7.5，并且该聚胺树脂基本上完全被碳酸中和并以碳酸亚烃或碳酸氢盐的形式分散在水中。 单向电流通过含有碳酸胺或碳酸氢盐的水性电泳浴，以在阴极上沉积多胺树脂并引起二氧化碳的释放。 在优选的实践中，浴中多胺树脂中的一部分胺基在低于足以将浴的pH保持在约6.0或更高的pH的条件下与相对不挥发的增溶酸反应，并且多胺树脂固体 在电镀浴中通过加入基本上完全用碳酸中和的浴多胺树脂来补充。

公开(公告)号：US07750060B2

公开(公告)日：2010-07-06

申请号：US11250422

申请日：2005-10-17

申请人： Edward P. Zahora ,  Anthony J. Tortorello ,  Edward J. Murphy ,  Anthony F. Toussaint ,  Timothy P. Reichert ,  Kelly A. Hawkinson

发明人： Edward P. Zahora ,  Anthony J. Tortorello ,  Edward J. Murphy ,  Anthony F. Toussaint ,  Timothy P. Reichert ,  Kelly A. Hawkinson

IPC分类号： C08F2/50 ,  C08F2/46 ,  C08J3/28

CPC分类号： C09D175/16 ,  C08G18/4213 ,  C08G18/4238 ,  C08G18/8175 ,  G02B1/048 ,  Y10T428/29 ,  Y10T428/2938 ,  Y10T428/31551 ,  C08G18/42 ,  C08L33/08 ,  C08L33/10 ,  C08L75/04

摘要： The invention relates to a radiation curable composition including a polyester urethane (meth)acrylate oligomer prepared from ortho-carboxylic polyester polyols, where the composition, after cure, has a secant modulus greater than about 600 MPa and an elongation at break of at least about 10%. The invention also relates to coated optical fibers and optical fiber ribbon including at least one coating derived from this composition, and to a process of making these coated optical fibers.

摘要翻译： 本发明涉及一种可辐射固化组合物，其包含由邻羧基聚酯多元醇制备的聚酯氨基甲酸酯（甲基）丙烯酸酯低聚物，其中组合物在固化后具有大于约600MPa的割线模数，断裂伸长率为至少约 10％。 本发明还涉及包含衍生自该组合物的至少一种涂层的涂覆光纤和光纤带，以及制造这些涂覆光纤的方法。

公开(公告)号：US20080085947A1

公开(公告)日：2008-04-10

申请号：US11544677

申请日：2006-10-10

申请人： Jeanette L. Ward ,  Edward J. Murphy ,  Kelly A. Hawkinson ,  James J. Schouten

发明人： Jeanette L. Ward ,  Edward J. Murphy ,  Kelly A. Hawkinson ,  James J. Schouten

IPC分类号： C03C25/10

CPC分类号： C03C25/26 ,  C03C25/326

摘要： Radiation curable compositions suitable for use a optical fiber ribbon matrix materials are provided which have at least two non-silicone urethane(meth)acrylate oligomers, one or more multifunctional diluents and one or more photoinitiators, wherein each of the non-silicone urethane(meth)acrylate oligomers has a number average molecular weight of about 200 or more, but less than about 6000, and the polydispersity index (PDI) of the urethane(meth)acrylate oligomers is from 2:1 to 30:1. The matrix material may be coated and cured on a plurality of optical fibers so as to form an optical fiber ribbon assembly.

摘要翻译： 提供适用于使用光纤带基质材料的辐射固化组合物，其具有至少两种非硅氧烷聚氨酯（甲基）丙烯酸酯低聚物，一种或多种多官能稀释剂和一种或多种光引发剂，其中每种非硅氧烷聚氨酯（甲基） ）丙烯酸酯低聚物的数均分子量为约200以上，但小于约6000，氨基甲酸酯（甲基）丙烯酸酯低聚物的多分散指数（PDI）为2：1〜30：1。 基质材料可以在多根光纤上涂布和固化，以形成光纤带组件。

公开(公告)号：US06130980A

公开(公告)日：2000-10-10

申请号：US72181

申请日：1998-05-05

申请人： Edward J. Murphy ,  Edward P. Zahora ,  David M. Szurn

发明人： Edward J. Murphy ,  Edward P. Zahora ,  David M. Szurn

IPC分类号： C03C25/10 ,  C08F290/06 ,  C09D4/00 ,  C09D4/06 ,  G02B6/44 ,  G02B6/04

CPC分类号： G02B6/4482 ,  C03C25/106 ,  C03C25/1065 ,  C08F290/064 ,  C08F290/067 ,  C09D4/00 ,  C09D4/06 ,  Y10T428/2804 ,  Y10T428/2929 ,  Y10T428/2938

摘要： Provided is a ribbon assembly having the functional capability of providing break-out of ink coated optical glass fibers from said ribbon assembly. The monomers, oligomers and photoinitiator for forming an ink coating on the optical glass fibers contained in the ribbon assembly have been selected to provide an average percentage of reacted acrylate unsaturation which provides a level of adhesion between a matrix material and an ink coating that is less than a level of adhesion between the ink coating and the coated optical glass fiber to provide break-out of the ink coated optical glass fiber from said ribbon assembly. Also provided are ink coating compositions adapted to form ink coatings suitable for use on optical glass fibers contained in the ribbon assembly.

摘要翻译： 提供了具有从所述带组件提供油墨涂覆的光学玻璃纤维的突出功能的色带组件。 已经选择了用于在带组件中包含的光学玻璃纤维上形成油墨涂层的单体，低聚物和光引发剂，以提供反应的丙烯酸酯不饱和度的平均百分比，其提供基体材料和较少的油墨涂层之间的粘合程度 比油墨涂层和涂覆的光学玻璃纤维之间的粘附程度提供了从所述带组件中分离的油墨涂覆的光学玻璃纤维。 还提供了适于形成适用于包含在色带组件中的光学玻璃纤维上的油墨涂料的油墨涂料组合物。

公开(公告)号：US5207871A

公开(公告)日：1993-05-04

申请号：US714856

申请日：1991-06-13

申请人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

发明人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

IPC分类号： C08F2/50 ,  D21H17/53 ,  D21H25/06 ,  D21H27/06 ,  G03G7/00

CPC分类号： D21H27/06 ,  D21H17/53 ,  D21H25/06 ,  G03G7/004 ,  Y10T428/2933 ,  Y10T428/3179 ,  Y10T428/31794

摘要： A composition which is cured upon exposure to ultraviolet light in the absence of solvent is disclosed. The liquid composition is prepared by combining a liquid maleate polyester and at least one of a vinyl compound and an allyl functional compound. A photoinitiator is then added to the polymerizable liquid composition. A substrate is impregnated with the polymerizable liquid composition and exposed to actinic energy of a sufficient dosage for a sufficient amount of time to polymerize the composition to a sufficient degree to impart useful properties to the substrate. The composition can be used as a binder for fiberglass insulation, in the manufacture of transparent or semi-transparent paper and to manufacture paper for use in photocopy machines.

摘要翻译： 公开了在不存在溶剂的情况下暴露于紫外线时固化的组合物。 通过将液体马来酸酯聚酯与乙烯基化合物和烯丙基官能化合物中的至少一种组合来制备液体组合物。 然后将光引发剂加入到可聚合液体组合物中。 用可聚合液体组合物浸渍基质并暴露于足够量的光化能量足够的时间以使组合物充分聚合以赋予基底有用的性质。 该组合物可用作玻璃纤维绝缘的粘合剂，用于制造透明或半透明纸并制造用于复印机的纸。

公开(公告)号：US5011635A

公开(公告)日：1991-04-30

申请号：US353538

申请日：1989-05-18

申请人： Edward J. Murphy ,  John J. Krajewski ,  Robert E. Ansel

发明人： Edward J. Murphy ,  John J. Krajewski ,  Robert E. Ansel

IPC分类号： B29C67/00

CPC分类号： B29C67/0066

摘要： The present invention contemplates a stereolithographic apparatus and method having a liquid organic phase and a fluid phase separated by a membrane that inhibits contact between the phases.

摘要翻译： 本发明考虑了一种立体光刻设备和方法，其具有液体有机相和通过膜分离的流体相，其抑制相之间的接触。