Method of Preparing Positive Electrode Active Material for Secondary Battery

    公开(公告)号:US20220246925A1

    公开(公告)日:2022-08-04

    申请号:US17627243

    申请日:2020-08-05

    Abstract: A method of preparing a positive electrode active material for a secondary battery, is disclosed herein. In some embodiments, a method includes mixing a positive electrode active material precursor, a lithium source material, a first firing additive, a second firing additive, and a third firing additive a to form a mixture, wherein the positive electrode active material precursor contains nickel, cobalt, and manganese and has a nickel content of 60 mol % or more relative to a total molar amount of metals in the positive electrode active material precursor, and performing primary firing of the mixture to form a lithium transition metal oxide, wherein the first firing additive is a lithium-containing compound, the second firing additive is a carbonate ion-containing compound, and the third firing additive is a boron-containing compound.

    Lithium Secondary Battery
    50.
    发明申请

    公开(公告)号:US20250118743A1

    公开(公告)日:2025-04-10

    申请号:US18294616

    申请日:2022-10-05

    Abstract: The present invention relates to a lithium secondary battery which includes a positive electrode including an overlithiated manganese-based oxide, in which an amount of manganese among total metals excluding lithium is greater than 50 mol % and a ratio (Li/Me) of the number of moles of the lithium to the number of moles of the total metals excluding the lithium is greater than 1, as a positive electrode active material; a negative electrode including a silicon-based negative electrode active material; a separator disposed between the positive electrode and the negative electrode; and an electrolyte, and satisfies Equation (1). 0.25 A ≤ B ≤ 0 . 6 ⁢ A Equation ⁢ ( 1 ) In Equation (1), A is a discharge curve area in a voltage range of 2.0 V to 4.6 V of a dQ/dV graph obtained by differentiating a graph of battery discharge capacity Q and voltage V after one cycle which are measured while charging the lithium secondary battery at 0.1 C to 4.6 V and then discharging the lithium secondary battery at 0.1 C to 2.0 V, and B is a discharge curve area in a voltage range of 2.0 V to 3.5 V of the dQ/dV graph.

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