公开(公告)号：US09150782B2

公开(公告)日：2015-10-06

申请号：US14562148

申请日：2014-12-05

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Stephen Bullock ,  Nicholas Zeese

IPC: G01N21/64 ,  C09K11/02 ,  C09K11/06 ,  C11D3/42 ,  C11D3/00 ,  C11D3/37 ,  C11D3/20 ,  C11D3/34

CPC classification number: C09K11/025 ,  B65D65/46 ,  C08J5/18 ,  C08J2300/14 ,  C08J2329/04 ,  C08K5/0041 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1088 ,  C11D3/0005 ,  C11D3/2096 ,  C11D3/3418 ,  C11D3/3753 ,  C11D3/42 ,  G01N21/6428 ,  G01N33/58 ,  G01N33/582 ,  G01N2021/6439 ,  C08L29/04

Abstract: Disclosed herein are fluorescent tracer compositions and water-soluble polymer compositions containing fluorescent compounds for tracing one or more components in the polymer compositions. More particularly, the disclosure relates to fluorescent tracer compositions including a fluorophore and a bitterant aversive component to be incorporated into a water-soluble polymer composition such as a water-soluble film. An aversive compound such as a bitterant is desirably incorporated into the polymer composition as a deterrent to ingestion of the polymer composition (or an article made therefrom). Qualitative or quantitative detection of the fluorophore in the polymer composition can be correlated to a qualitative or quantitative detection of a corresponding traced material in the polymer composition, for example the bitterant aversive component. Related articles and methods for making and using the polymer compositions are also disclosed.

Abstract translation: 本文公开了含有用于跟踪聚合物组合物中的一种或多种组分的荧光化合物的荧光示踪剂组合物和水溶性聚合物组合物。 更具体地，本公开涉及包含荧光团和掺入到水溶性聚合物组合物如水溶性膜中的苦味厌恶成分的荧光示踪剂组合物。 希望将厌恶性化合物如苦味剂掺入聚合物组合物中，作为摄入聚合物组合物（或由其制成的制品）的威慑物。 聚合物组合物中荧光团的定性或定量检测可以与聚合物组合物中相应的追踪物质的定性或定量检测相关，例如苦味厌恶成分。 还公开了制备和使用聚合物组合物的相关文章和方法。

公开(公告)号：US20150159082A1

公开(公告)日：2015-06-11

申请号：US14562148

申请日：2014-12-05

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Stephen Bullock ,  Nicholas Zeese

IPC: C09K11/02 ,  C11D3/42 ,  G01N21/64 ,  C11D3/37 ,  C11D3/20 ,  C11D3/34 ,  C09K11/06 ,  C11D3/00

CPC classification number: C09K11/025 ,  B65D65/46 ,  C08J5/18 ,  C08J2300/14 ,  C08J2329/04 ,  C08K5/0041 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1088 ,  C11D3/0005 ,  C11D3/2096 ,  C11D3/3418 ,  C11D3/3753 ,  C11D3/42 ,  G01N21/6428 ,  G01N33/58 ,  G01N33/582 ,  G01N2021/6439 ,  C08L29/04

Abstract: Disclosed herein are fluorescent tracer compositions and water-soluble polymer compositions containing fluorescent compounds for tracing one or more components in the polymer compositions. More particularly, the disclosure relates to fluorescent tracer compositions including a fluorophore and a bitterant aversive component to be incorporated into a water-soluble polymer composition such as a water-soluble film. An aversive compound such as a bitterant is desirably incorporated into the polymer composition as a deterrent to ingestion of the polymer composition (or an article made therefrom). Qualitative or quantitative detection of the fluorophore in the polymer composition can be correlated to a qualitative or quantitative detection of a corresponding traced material in the polymer composition, for example the bitterant aversive component. Related articles and methods for making and using the polymer compositions are also disclosed.

Abstract translation: 本文公开了含有用于跟踪聚合物组合物中的一种或多种组分的荧光化合物的荧光示踪剂组合物和水溶性聚合物组合物。 更具体地，本公开涉及包含荧光团和掺入到水溶性聚合物组合物如水溶性膜中的苦味厌恶成分的荧光示踪剂组合物。 希望将厌恶性化合物如苦味剂掺入聚合物组合物中，作为摄入聚合物组合物（或由其制成的制品）的威慑物。 聚合物组合物中荧光团的定性或定量检测可以与聚合物组合物中相应的追踪物质的定性或定量检测相关，例如苦味厌恶成分。 还公开了制备和使用聚合物组合物的相关文章和方法。

公开(公告)号：US20150096130A1

公开(公告)日：2015-04-09

申请号：US14506269

申请日：2014-10-03

Applicant: MONOSOL, LLC

Inventor： Stephen Bullock ,  Percy Bromby, II ,  Jennifer L. Childers ,  Jonathon Knight ,  David M. Lee ,  Sumeet Kumar ,  Nicholas Zeese

IPC: C11D17/00 ,  C11D11/00 ,  C11D3/395

CPC classification number: C11D17/0039 ,  C11D3/0052 ,  C11D3/3953 ,  C11D11/0017 ,  C11D17/042 ,  Y10T428/2982

Abstract: Disclosed herein are capsules for delayed release of an active ingredient contained therein, in particular water-soluble capsules for delayed release of water-sensitive, gas-generating compositions into an aqueous liquid medium. The delayed release capsules incorporate one or more gas-relief pinholes for gas-generating water-sensitive compositions contained in the capsules, such as inorganic bleach or other alkaline compositions intended for delayed release into a wash medium during a laundry cycle. The pinholes permit gas generated within the capsule due to exposure to environmental water vapor to escape from the capsule interior, preventing pressure build-up and capsule deformation during storage. The pinholes are sized to prevent or otherwise substantially limit the passage of liquids when submerged in a liquid medium (e.g., liquid water in an aqueous liquid medium). Related articles and methods for delivering the capsules in combination with a detergent or other laundry composition are also disclosed.

Abstract translation: 本文公开了用于延迟释放其中包含的活性成分的胶囊，特别是用于将水敏感的气体发生组合物延迟释放到水性液体介质中的水溶性胶囊。 延迟释放胶囊包含一个或多个用于气囊产生的水敏感组合物的气体释放针孔，其包含在胶囊中，例如无机漂白剂或其它碱性组合物，用于在洗衣循环期间延迟释放到洗涤介质中。 针孔允许由于暴露于环境水蒸气而在胶囊内产生的气体从胶囊内部逸出，从而防止在储存期间的压力积聚和胶囊变形。 针孔的尺寸设置成防止或以其他方式基本上限制液体浸没在液体介质（例如在液体介质中的液体水）时的通过。 还公开了将胶囊与洗涤剂或其它衣物组合物一起递送的相关物品和方法。

公开(公告)号：US20150093526A1

公开(公告)日：2015-04-02

申请号：US14562342

申请日：2014-12-05

Applicant: MONOSOL, LLC

Inventor： Frank W. Denome ,  Steven G. Friedrich ,  Regine Labeque ,  David M. Lee ,  Roxane Rosmaninho ,  Jichun Shi ,  Andrew P. Verrall

IPC: C08L29/04

Abstract: Disclosed is a pouch having at least one sealed compartment containing a first composition. At least one wall of the at least one sealed compartment is made from a water-soluble film having any suitable thickness. The water-soluble film comprises PVOH polymer such that when the film has a thickness of about 76 microns the film is characterized by a Dissolution Index of about 620 to about 920, or of about 665 to about 920, or about 710 to about 920; and a Stress Index of about 145 to about 626, or about 155 to about 480, or about 165 to about 325.

Abstract translation: 公开了一种具有至少一个包含第一组合物的密封隔室的袋。 至少一个密封隔室的至少一个壁由具有任何合适厚度的水溶性薄膜制成。 该水溶性膜包含PVOH聚合物，使得当该膜的厚度为约76微米时，该膜的特征在于溶解指数为约620至约920，或约665至约920，或约710至约920; 和约145至约626，或约155至约480，或约165至约325的应力指数。

公开(公告)号：US20210087365A1

公开(公告)日：2021-03-25

申请号：US17061056

申请日：2020-10-01

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Jennifer L. Childers

IPC: C08L1/28 ,  C08J5/18 ,  A23L27/30 ,  A23P20/20 ,  A23L29/262 ,  A23L29/288 ,  C08K5/053 ,  C08L29/04 ,  C08K5/1575

Abstract: Disclosed herein are water-soluble films and resulting packets including a water soluble film, wherein the water-soluble film includes a water-soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film is substantially transparent.

公开(公告)号：US10913832B2

公开(公告)日：2021-02-09

申请号：US16679600

申请日：2019-11-11

Applicant: MONOSOL, LLC

Inventor： Steven G. Friedrich ,  David M. Lee ,  Thomas J. Yogan ,  Regine Labeque

IPC: C08J5/18 ,  B65D75/04 ,  B32B1/02 ,  B65D75/08 ,  B65D75/20 ,  B65D75/06 ,  B65D75/12 ,  B65D75/22 ,  B32B1/08 ,  B65D75/32 ,  B65D75/30 ,  C11D3/37 ,  C11D17/04

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.

公开(公告)号：US10808210B2

公开(公告)日：2020-10-20

申请号：US14776460

申请日：2014-03-13

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Nicholas Zeese ,  Jennifer L. Childers ,  Stephen Bullock

IPC: C11D17/04 ,  B65D65/46

Abstract: The disclosure provides a water-soluble film, including polyvinyl alcohol (PVOH) and (PVOH) and an acrylate resin (e.g., methyl acrylate), wherein the water-soluble film remains intact for at least 3 minutes when submerged in water heated to a temperature of about 40° C., as determined by Bleach Compatibility Method A (described herein). The disclosure further provides a packet or pouch comprising water-soluble film of the disclosure. The packet or pouch can optionally include two or more compartments. The disclosure further provides a pouch including a first sealed compartment containing a first composition, the first sealed compartment comprising the water-soluble film according to the disclosure. Optionally, the first composition can include a bleach composition.

公开(公告)号：US20200040288A1

公开(公告)日：2020-02-06

申请号：US16601224

申请日：2019-10-14

Applicant: MONOSOL, LLC

Inventor： Philip Frank Souter ,  Robby Renilde Francois Keuleers ,  Regine Labeque ,  Florence Catherine Courchay ,  Marc Rene Bert Renmans ,  David M. Lee ,  Steven G. Friedrich ,  Lee K. Yeung ,  Shinsuke Nii

IPC: C11D17/04 ,  C08L29/04 ,  C08K5/053 ,  C08K5/00 ,  C08J5/12 ,  C07C57/145 ,  C07C31/20 ,  B65D65/46 ,  B65D53/06 ,  B29C65/00 ,  B29C51/02

Abstract: The present disclosure relates to pouches made from a combination of chemically different water-soluble films and optionally containing a composition (e.g. a household care composition or non-household care composition) that is at least partially enclosed by the water-soluble films in at least one compartment.

公开(公告)号：US10472476B2

公开(公告)日：2019-11-12

申请号：US15519032

申请日：2015-10-13

Applicant: MONOSOL, LLC

Inventor： Steven G. Friedrich ,  David M. Lee ,  Thomas J. Yogan ,  Regine Labeque

IPC: C08J5/18 ,  B65D75/04 ,  B32B1/02 ,  B65D75/08 ,  B65D75/20 ,  B65D75/06 ,  B65D75/12 ,  B65D75/22 ,  B32B1/08 ,  B65D75/32 ,  B65D75/30 ,  C11D3/37 ,  C11D17/04

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.

公开(公告)号：US10443024B2

公开(公告)日：2019-10-15

申请号：US15620316

申请日：2017-06-12

Applicant: MONOSOL, LLC

Inventor： Philip Frank Souter ,  Robby Renilde Francois Keuleers ,  Regine Labeque ,  Florence Catherine Courchay ,  Marc Rene Bert Renmans ,  David M. Lee ,  Steven G. Friedrich ,  Lee K. Yeung ,  Shinsuke Nii

IPC: C11D1/00 ,  C11D17/04 ,  B29C51/02 ,  B29C65/00 ,  B65D53/06 ,  B65D65/46 ,  C07C31/20 ,  C07C57/145 ,  C08J5/12 ,  C08K5/00 ,  C08K5/053 ,  C08L29/04 ,  B29K29/00

Abstract: The present disclosure relates to pouches made from a combination of chemically different water-soluble films and optionally containing a composition (e.g. a household care composition or non-household care composition) that is at least partially enclosed by the water-soluble films in at least one compartment.