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公开(公告)号：US4006101A
公开(公告)日：1977-02-01
申请号：US608898
申请日：1975-08-29
摘要： A process for the production of polyolefins is disclosed, which is carried out in the presence of catalysts prepared according to the invention. The catalysts comprise a carrier resulting from the reaction of anhydrous magnesium halide, silicon tetrachloride and an alcohol represented by the general formulaROHwhere R is an organic group of 1 to 20 carbon atoms, and a titanium and/or a vanadium compound supported on said carrier. Such catalysts are activated by an organoaluminum and/or an organozinc compound when in use.
摘要翻译： 公开了一种生产聚烯烃的方法，其在根据本发明制备的催化剂的存在下进行。 催化剂包含由无水卤化镁，四氯化硅和由通式ROH表示的醇反应得到的载体，其中R是1至20个碳原子的有机基团，并且钛和/或钒化合物负载在所述 载体 当使用时，这种催化剂被有机铝和/或有机锌化合物活化。
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公开(公告)号：US5013802A
公开(公告)日：1991-05-07
申请号：US427941
申请日：1989-10-25
IPC分类号： C08F2/14 , C08F4/60 , C08F4/62 , C08F4/64 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F210/16 , Y10S526/905
摘要： A process for preparing an ethylene polymer by a two-stage polymerization of ethylene or ethylene and an .alpha.-olefin in an inert hydrocarbon at 50.degree.-100.degree. C. using a coordination polymerization catalyst containing a solid component and an organoaluminum compound, said solid component containing a transition metal compound, which process comprises:(a) in a first stage, producing 10-90% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.0001 to 0.5 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid product obtained by supporting chromium trioxide or a compound which on calcining forms chromium oxide at least partially, on an inorganic oxide carrier followed by calcining, and using as said organoaluminum compound a compound of the general formula ##STR1## wherein R is a hydrocarbon radical having 1 to 18 carbon atoms and n is 2.ltoreq.n.ltoreq.100; and(b) in a second stage, producing 90-10% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.01 to 50 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid material containing at least magnesium and titanium, and using as said organoaluminum compound a compound of the general formula AlR'.sub.p X.sub.3-p wherein R' is a hydrocarbon radical having 1 to 20 carbon atoms, X is halogen and/or alkoxy and p is 0
摘要翻译： 一种通过使用含有固体组分和有机铝化合物的配位聚合催化剂在50-100℃下在惰性烃中进行乙烯或乙烯和α-烯烃两步聚合制备乙烯聚合物的方法，所述固体 含有过渡金属化合物的组分，该方法包括：（a）在熔融指数在0.0001至0.5g / 10min范围内的聚合物的总聚合物量的第一阶段中，产生10-90重量％ 根据ASTM D 1238-73，条件E测量，使用通过将无机氧化物载体上的三氧化铬或煅烧至少部分形成的氧化铬上的化合物或三价氧化物得到的固体产物作为所述固体成分进行煅烧，并使用 所述有机铝化合物是通式为“IMAGE”的化合物，其中R为具有1至18个碳原子的烃基，n为2
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公开(公告)号：US5006633A
公开(公告)日：1991-04-09
申请号：US395803
申请日：1989-08-18
摘要： An electroactive polymer is obtained by doping a copolymer represented by the following general formula (I): ##STR1## wherein R.sup.1 is hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 is hydrogen, a hydrocarbon residue having 1 to 20 carbon atoms, furyl, pyridyl, nitrophenyl, chlorophenyl, or methoxyphenyl; l is an integer not smaller than 2; m is an integer not smaller than 1; and n is an integer not smaller than 2.
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公开(公告)号：US4507448A
公开(公告)日：1985-03-26
申请号：US374627
申请日：1982-05-04
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/906
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of a catalyst system comprising the combination of at least one organometallic compound with a component resulting from the reaction of (a) a magnesium halide, (b) a compound represented by the formula, Al(OR).sub.n X.sub.3-n, where R is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a hydrogen atom, and n is 0.ltoreq.n.ltoreq.3, (c) a compound represented by the formula, Si(OR').sub.m X.sub.4-m, where R' is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a halogen atom, and m is 0.ltoreq.m.ltoreq.4, and (d) a titanium compound and/or a vanadium compound. The resulting polymers have a large bulk density and a narrow range of molecular weight distribution.
摘要翻译： 公开了一种用于烯烃均聚或共聚的方法，该催化剂体系包括至少一种有机金属化合物与由（a）卤化镁反应得到的组分的组合的催化剂体系，（b） 由式Al（OR）nX3-n表示的化合物，其中R是具有1至20个碳原子的烃残基，X是氢原子，n是0
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公开(公告)号：US4451688A
公开(公告)日：1984-05-29
申请号：US413829
申请日：1982-09-01
CPC分类号： C08F10/00
摘要： Olefins are polymerized in the presence of a catalyst which comprises the combination of:[I] a solid substance obtained by the reaction of at least the following two components:(i) a magnesium compound represented by the general formula R.sup.1.sub.m (OR.sup.2).sub.n MgX.sub.2-m-n wherein R.sup.1 and R.sup.2 are each a hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m.ltoreq.2 and n is 0.ltoreq.n.ltoreq.2, provided 0.ltoreq.m+n.ltoreq.2, and(ii) a titanium compound and/or a vanadium compound;[II] a silicon compound represented by general formula R.sup.1 mSi(OR.sup.2).sub.n X.sub.4-m-n wherein R.sup.1 and R.sup.2 are each hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m
摘要翻译： 烯烃在催化剂的存在下聚合，该催化剂包含以下组合的组合：[I]通过至少以下两种组分的反应获得的固体物质：（i）由通式R 1 m（OR 2）表示的镁化合物nMgX2- mn其中R 1和R 2各自是具有1至24个碳原子的烃基，X是卤素原子，m是0≤n≤2且n是0
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公开(公告)号：US4371679A
公开(公告)日：1983-02-01
申请号：US229167
申请日：1981-01-28
申请人： Nobuyuki Kuroda , Akira Sano , Toru Nakamura , Kazuo Matsuura , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Akira Sano , Toru Nakamura , Kazuo Matsuura , Mituji Miyoshi
CPC分类号： C08F10/00 , Y10S526/909
摘要： This invention provides a process for preparing polyolefins by polymerizing or copolymerizing olefins using as the catalyst a titanium compound-containing solid component and an organometal compound, said solid component comprising a substance obtained by copulverizing (1) magnesium halide and/or manganese halide, (2) an organic halide compound, (3) a chain or cyclic silicone compound with a recurring structural unit represented by the general formula ##STR1## wherein R' and R" respectively represent a hydrogen, alkyl, aryl, alkoxy or hydroxyl group and (4) tetravalent and/or trivalent titanium compound(s).
摘要翻译： 本发明提供一种通过使用含钛化合物的固体组分和有机金属化合物作为催化剂聚合或共聚烯烃来制备聚烯烃的方法，所述固体组分包括通过共混（1）卤化镁和/或卤化锰得到的物质（ 2）有机卤化物，（3）具有由通式“IMAGE”表示的重复结构单元的链或环状硅氧烷化合物，其中R'和R“分别表示氢，烷基，芳基，烷氧基或羟基， （4）四价和/或三价钛化合物。
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公开(公告)号：US4065611A
公开(公告)日：1977-12-27
申请号：US722859
申请日：1976-09-10
申请人： Mituji Miyoshi , Kazuo Matsuura , Nobuyuki Kuroda , Shiro Ogawa
发明人： Mituji Miyoshi , Kazuo Matsuura , Nobuyuki Kuroda , Shiro Ogawa
CPC分类号： C08F10/00
摘要： Processes for the production of polyolefins are disclosed in which olefins are polymerized in the presence of Ziegler catalyst components carried on magnesium oxide. The polymerization is effected in the presence of a solid catalyst comprising a transition metal halide carried on magnesium oxide, such oxide having been pretreated with an organic halide, and another catalyst component selected from the group consisting of organoaluminum compounds and alkylzinc. The combination of these catalysts contributes to increased polymer yields based on both carrier and transition metal.
摘要翻译： 公开了用于生产聚烯烃的方法，其中在氧化镁载带的齐格勒催化剂组分存在下使烯烃聚合。 聚合反应在包含负载在氧化镁上的过渡金属卤化物的固体催化剂存在下进行，这种氧化物已用有机卤化物预处理，另一种催化剂组分选自有机铝化合物和烷基锌。 这些催化剂的组合有助于基于载体和过渡金属的增加的聚合物产率。
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公开(公告)号：US4064334A
公开(公告)日：1977-12-20
申请号：US705606
申请日：1976-07-15
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of a catalyst consisting of a solid component and an organometallic compound component, characterized in that said solid component is obtained by copulverizing1. a magnesium halide,2. a compound represented by the general formula Al(OR)mX.sub.3-m wherein R is alkyl and/or aralkyl having 1 to 20 carbon atoms and may be the same or different, X is halogen and O
摘要翻译： 根据本发明，提供了一种在由固体组分和有机金属化合物组分组成的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，其特征在于所述固体组分通过共混获得。1.镁 卤化物，2.一般化合物表示的化合物Al（OR）mX3-m其中R是具有1至20个碳原子的烷基和/或芳烷基并且可以相同或不同，X是卤素，且O < 3，三价钛化合物，和4.一种三价钛化合物，其中该有机元素化合物组分是一种混合物。5.一种三乙基铝和六种一般化合物表示的化合物AlR'nX3-n，其中R'是 具有1-10个碳原子的烷基可以相同或不同，X是卤素且O
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公开(公告)号：US4061857A
公开(公告)日：1977-12-06
申请号：US683965
申请日：1976-05-06
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using as catalyst a solid component containing a titanium compound and/or a vanadium compound, and an organoaluminum compound and/or an organozinc compound, said solid component being obtained by copulverizing (1) a magnesium halide and/or a manganese halide, (2) an aluminum oxyhalide and (3) a titanium compound and/or a vanadium compound.
摘要翻译： 根据本发明，提供了一种制备聚烯烃的方法，其包括使用含有钛化合物和/或钒化合物的固体组分和有机铝化合物和/或有机锌化合物作为催化剂聚合或共聚烯烃，所述固体 通过共混（1）卤化镁和/或卤化锰获得的组分，（2）卤氧化铝和（3）钛化合物和/或钒化合物。
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公开(公告)号：US5708523A
公开(公告)日：1998-01-13
申请号：US633932
申请日：1996-04-17
申请人： Takaya Kubo , Hiroshi Kobayashi , Yoshinori Nishikitani , Nobuyuki Kuroda , Tetsuya Seike , Junichi Nagai
发明人： Takaya Kubo , Hiroshi Kobayashi , Yoshinori Nishikitani , Nobuyuki Kuroda , Tetsuya Seike , Junichi Nagai
CPC分类号： G02F1/155
摘要： A counterelectrode for a smart window contains a transparent electrically conductive substrate and a plurality of electrically conductive dots arrayed on the transparent electrically conductive substrate. Each of the electrically conductive dots contains fine particles having capacitance of not less than 1 farad/g or fine particles capable of storing electrical charge of not less than 1 coulomb/g. A smart window contains the aforementioned counterelectrode.
摘要翻译： 用于智能窗的反电极包含透明导电衬底和排列在透明导电衬底上的多个导电点。 每个导电点包含具有不小于1法拉德/克的电容的细颗粒或能够存储不少于1库伦/克的电荷的微粒。 智能窗口包含上述的反电极。
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