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86 条记录 (耗时 0.025 秒)

    Activated cathode and process for preparation thereof
    41.
    发明授权
    Activated cathode and process for preparation thereof 有权
    活性阴极及其制备方法

    公开(公告)号：US06312571B1

    公开(公告)日：2001-11-06

    申请号：US09511989

    申请日：2000-02-24

    申请人： Miwako Nara ,  Masashi Tanaka ,  Yoshinori Nishiki ,  Shuji Nakamatsu

    发明人： Miwako Nara ,  Masashi Tanaka ,  Yoshinori Nishiki ,  Shuji Nakamatsu

    IPC分类号： C25B900

    CPC分类号： C25B11/0484

    摘要： An activated cathode comprising an electrically conductive substrate, an interlayer comprising a nickel oxide formed on the surface of the electrically conductive substrate, and a catalyst layer containing at least one lanthanum component selected from oxides and hydroxides of lanthanum metals and at least one platinum component selected from platinum metals and silver and oxides and hydroxides thereof formed on the interlayer. A process for the preparation of an activated cathode is also disclosed which comprises forming an interlayer comprising a nickel oxide on the surface of an electrically conductive substrate, and then forming a catalyst layer containing at least one lanthanum component selected from oxides and hydroxides of lanthanum metals and at least one platinum. component selected from platinum metals and silver and oxides and hydroxides thereof on the surface of the interlayer.

    摘要翻译： 包括导电基底的活化阴极，包含形成在导电基底表面上的氧化镍的中间层和包含至少一种镧组分的催化剂层，所述镧组分选自镧金属的氧化物和氢氧化物以及至少一种铂组分 由铂金属和银和其在中间层上形成的氧化物和氢氧化物组成。 还公开了一种制备活性阴极的方法，其包括在导电基材的表面上形成包含氧化镍的中间层，然后形成含有至少一种选自镧金属的氧化物和氢氧化物的镧组分的催化剂层 和至少一个铂。 组分选自铂金属和银，以及它们在中间层表面上的氧化物和氢氧化物。

    Apparatus for producing electrolytic water
    42.
    发明授权
    Apparatus for producing electrolytic water 失效
    电解水生产设备

    公开(公告)号：US06235186B1

    公开(公告)日：2001-05-22

    申请号：US09315945

    申请日：1999-05-21

    申请人： Masashi Tanaka ,  Yoshinori Nishiki ,  Naoya Hayamizu ,  Naoaki Sakurai

    发明人： Masashi Tanaka ,  Yoshinori Nishiki ,  Naoya Hayamizu ,  Naoaki Sakurai

    IPC分类号： C25B146

    CPC分类号： C02F1/46109 ,  C02F1/42 ,  C02F1/4618 ,  C02F1/4674 ,  C02F9/00 ,  C02F2001/46142 ,  C02F2001/46161 ,  C02F2201/46115 ,  C02F2201/46195 ,  C02F2209/04

    摘要： An apparatus for producing electrolytic water in which the yielded electrolytic water does not suffer quality deterioration caused by chemical species, e.g., hydrogen ions, moving to the counter-electrode chamber. A diaphragm 4 of a two-chamber type electrolytic cell comprises two or more ion-exchange membranes 3, and a noble-metal layer 2 or another layer may be formed in the diaphragm. Use of the ion-exchange membranes produces an enhanced physical screening effect, while formation of the noble-metal layer produces catalytic effect to decompose chemical species. Both the ion-exchange membranes and the anode-metal layer are effective in diminishing the movement of chemical species to the counter-electrode chamber.

    摘要翻译： 一种生产电解水的设备，其中产生的电解水不会由于移动到对电极室的化学物质例如氢离子而引起质量劣化。 两室式电解池的隔膜4包括两个或更多个离子交换膜3，并且可以在隔膜中形成贵金属层2或另一层。 使用离子交换膜产生增强的物理筛选效果，而贵金属层的形成产生催化作用以分解化学物质。 离子交换膜和阳极 - 金属层都有效地减少化学物质向对电极室的移动。

    Cathode for hydrogen generation
    43.
    发明授权
    Cathode for hydrogen generation 有权
    生成氢气的阴极

    公开(公告)号：US07959774B2

    公开(公告)日：2011-06-14

    申请号：US12398234

    申请日：2009-03-05

    申请人： Miwako Nara ,  Tomohisa Suzuki ,  Masashi Tanaka ,  Yoshinori Nishiki

    发明人： Miwako Nara ,  Tomohisa Suzuki ,  Masashi Tanaka ,  Yoshinori Nishiki

    IPC分类号： C25B11/06 ,  C25B11/08

    CPC分类号： C25B11/0478 ,  C25B11/0473 ,  C25B11/0484 ,  Y02E60/366

    摘要： The present invention provides a cathode for hydrogen generation comprising a cathode substrate having provided thereon a catalytic layer, wherein the catalytic layer contains at least three components of platinum, cerium and lanthanum in amounts of 50 to 98 mol %, 1 to 49 mol % and 1 to 49 mol %, respectively, in the form of metal, metal oxide or metal hydroxide.

    摘要翻译： 本发明提供了一种用于氢气生成的阴极，其包括在其上设置有催化剂层的阴极基底，其中所述催化剂层含有至少三种组分的铂，铈和镧，含量为50至98摩尔％，1至49摩尔％，和 分别为金属，金属氧化物或金属氢氧化物形式的1〜49摩尔％。

    Cathode assembly and method of reactivation
    44.
    发明授权
    Cathode assembly and method of reactivation 有权
    阴极装配和再活化方法

    公开(公告)号：US6165333A

    公开(公告)日：2000-12-26

    申请号：US419904

    申请日：1999-10-18

    申请人： Masashi Tanaka ,  Shuji Nakamatsu ,  Yoshinori Nishiki

    发明人： Masashi Tanaka ,  Shuji Nakamatsu ,  Yoshinori Nishiki

    IPC分类号： C25B11/00 ,  C25B11/03 ,  C25B11/04 ,  C25B11/12

    CPC分类号： C25B11/035 ,  C25B11/00

    摘要： A cathode assembly comprising a cathode, an ion-exchange membrane, and an electroconductive porous member permeable to gas and liquid sandwiched between the cathode and the membrane. The porous member may have, deposited on a part thereof, a catalyst active in hydrogen generation. The porous member preferably is in the form of a plate, sheet, fibers, web, paper, net, or sinter of any of these, and comprises at least a carbonaceous material and has a thickness of from 0.05 to 5 mm and a porosity of from 10 to 95%. Also disclosed is a method of reactivating a cathode assembly, which comprises conducting electrolysis using the cathode assembly until its activity decreases, and then depositing a catalyst active in hydrogen generation on the porous member.

    摘要翻译： 一种阴极组件，其包括阴极，离子交换膜和可渗透于阴极和膜之间的气体和液体的导电多孔构件。 多孔构件可以在其一部分上沉积氢生成活性的催化剂。 多孔构件优选为其中任何一种的板，片，纤维，纤维网，纸，网或烧结体的形式，并且至少包含碳质材料，并且具有0.05至5mm的厚度和孔隙率 从10％到95％。 还公开了一种重新激活阴极组件的方法，其包括使用阴极组件进行电解，直到其活性降低，然后在多孔构件上沉积生成氢气的催化剂。

    ACTIVATED CATHODE FOR HYDROGEN EVOLUTION
    45.
    发明申请
    ACTIVATED CATHODE FOR HYDROGEN EVOLUTION 有权
    用于氢演化的活化阴极

    公开(公告)号：US20120305389A1

    公开(公告)日：2012-12-06

    申请号：US13576811

    申请日：2011-01-18

    申请人： Miwako Nara ,  Eri Miyakawa ,  Yoshinori Nishiki

    发明人： Miwako Nara ,  Eri Miyakawa ,  Yoshinori Nishiki

    IPC分类号： C25B11/08 ,  C25B1/02 ,  C25B11/06

    CPC分类号： C25B11/0494 ,  C25B11/0484 ,  Y02E60/366

    摘要： The present invention aims to provide an activated cathode enabling a long-time stable operation with hydrogen overvoltage maintained at a low value, keeping a high remaining rate of the catalyst element after a cease of operation for a short-circuiting and after an electrolysis operation at a high current density, restricting catalyst loss to a little, and having a strong resistance to contamination caused by electrolyte impurity elements.The present invention relates to a cathode for hydrogen evolution with a catalyst layer formed on the cathode substrate, having, at least, three elements comprising platinum, cerium and palladium, as essential element, in a state of metal, metal oxide, or hydroxide, contained, where the mole fraction of respective element being x, y, and z, within a range of 5 mol %≦x≦90 mol %, 5 mol %≦y≦55 mol %, 5 mol %≦z≦65 mol %.

    摘要翻译： 本发明的目的在于提供一种能够在氢过电压保持低值的情况下进行长时间稳定运行的活性阴极，在短路运转停止后和电解运转后保持催化剂元素的高残留率 高电流密度，将催化剂损失限制到少许，并且对电解质杂质元素引起的污染具有很强的抵抗力。 本发明涉及在金属，金属氧化物或氢氧化物的状态下，在阴极基板上形成有催化剂层的阴极，其具有至少三种包含铂，铈和钯作为必需元素的元素， 含有，其中各元素的摩尔分数为x，y和z在5mol％＆amp; NlE; x＆amp; NlE; 90mol％，5mol％＆amp; NlE; y＆amp; NlE; 55mol％，5mol％和nlE; z＆ 65摩尔％。

    Electrode for generation of hydrogen
    46.
    发明授权
    Electrode for generation of hydrogen 有权
    用于产生氢的电极

    公开(公告)号：US08070924B2

    公开(公告)日：2011-12-06

    申请号：US12053652

    申请日：2008-03-24

    申请人： Takeo Ohsaka ,  Shunsuke Sata ,  Miwako Nara ,  Yoshinori Nishiki

    发明人： Takeo Ohsaka ,  Shunsuke Sata ,  Miwako Nara ,  Yoshinori Nishiki

    IPC分类号： C25B11/10 ,  C25B11/08 ,  C25B1/02

    CPC分类号： C25B1/04 ,  C25B11/0484 ,  H01M4/8657 ,  H01M4/9016 ,  H01M4/92 ,  H01M4/921 ,  H01M8/023 ,  H01M8/0234 ,  H01M8/0245 ,  Y02E60/366

    摘要： The present invention provides an electrode for generation of hydrogen comprising: a conductive substrate; a catalytic layer formed on the conductive substrate and containing at least one platinum group metal selected from the group consisting of Pt, Ir, Ru, Pd and Rh; and a hydrogen adsorption layer formed on the catalytic layer. The present invention also provides an electrode for generation of hydrogen comprising: a conductive substrate, a catalytic layer formed on the conductive substrate and containing: at least one platinum group metal selected from the group consisting of Pt, Ir, Ru, Pd and Rh and/or at least one oxide of said platinum group metals; and at least one metal selected from the group consisting of lanthanum series metals, valve metals, iron series metals and silver and/or at least one oxide of said metals; and a hydrogen adsorption layer formed on the catalytic layer.

    摘要翻译： 本发明提供一种用于产生氢的电极，包括：导电基板; 形成在所述导电性基板上并含有选自Pt，Ir，Ru，Pd和Rh中的至少一种铂族金属的催化剂层; 和形成在催化层上的氢吸附层。 本发明还提供了一种用于产生氢的电极，包括：导电基底，形成在导电基底上的催化层，并含有：选自Pt，Ir，Ru，Pd和Rh中的至少一种铂族金属和 /或所述铂族金属的至少一种氧化物; 和选自镧系金属，阀金属，铁系金属和银的至少一种金属和/或所述金属的至少一种氧化物; 和形成在催化层上的氢吸附层。

    Hydrogen evolving cathode
    48.
    发明授权
    Hydrogen evolving cathode 失效
    氢气放出阴极

    公开(公告)号：US07232509B2

    公开(公告)日：2007-06-19

    申请号：US11224081

    申请日：2005-09-13

    申请人： Miwako Nara ,  Yoshinori Nishiki ,  Tsuneto Furuta

    发明人： Miwako Nara ,  Yoshinori Nishiki ,  Tsuneto Furuta

    IPC分类号： C25B11/08 ,  C25B11/06

    CPC分类号： C25B11/0478 ,  C25B11/0494

    摘要： Highly active hydrogen evolving cathode using a platinum group metal catalyst in an amount smaller than that used in the conventional hydrogen evolving cathode. The hydrogen evolving cathode includes a conductive substrate, and a catalyst layer comprising at least one selected from the group consisting of silver and a silver oxide compound, and at least one selected from the group consisting of a platinum group metal, a platinum group metal oxide and a platinum group metal hydroxide, formed on a surface of the conductive substrate.

    摘要翻译： 使用比常规放氢阴极中使用的量小的铂族金属催化剂的高活性氢放出阴极。 放氢阴极包括导电性基板和包含选自银和氧化银化合物中的至少一种的催化剂层，以及选自铂族金属，铂族金属氧化物 和铂族金属氢氧化物，形成在导电性基板的表面上。