Polyhydroxyl compounds, a process for their production and their use in
coating compositions
    41.
    发明授权
    Polyhydroxyl compounds, a process for their production and their use in coating compositions 失效
    多羟基化合物,其制备方法及其在涂料组合物中的应用

    公开(公告)号:US5422421A

    公开(公告)日:1995-06-06

    申请号:US93246

    申请日:1993-07-16

    摘要: The present invention relates to a process for the production of polyhydroxyl compounds having a hydroxyl group content of 2 to 10% by weight and a viscosity at 23.degree. C. of 250 to 80,000 mPa.s by the radically initiated polymerization at a reaction temperature of 80.degree. to 220.degree. C. ofa) 100 parts by weight of a mixture of olefinically unsaturated monomers containing at least 1% by weight of monomers containing alcoholic hydroxyl groups in the presence ofb) 5 to 500 total parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more cyclic compounds which, in the presence of initiator compounds containing alcoholic hydroxyl groups, are capable of a ring-opening polymerization reaction andc) 2 to 300 parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more polyhydric alcohols having a molecular weight of 62 to 1000.The present invention also relates to the polyhydroxyl compounds obtained by this process and to their use in combination with suitable hardeners as binders for one-component or two-component coating compositions.

    摘要翻译: 本发明涉及一种生产羟基含量为2〜10重量%,在23℃下的粘度为250〜80,000mPa.s的多羟基化合物的方法,通过自由基引发的聚合反应, 80℃至220℃的a)100重量份的含有至少1重量%的含醇羟基的单体的烯属不饱和单体的混合物在b)5至500重量份的存在下,其可以 在反应开始时或在反应期间加入一种或多种环状化合物,其在含有醇羟基的引发剂化合物的存在下能够开环聚合反应,c)2〜300份 重量,其可以在反应开始时存在或在反应期间加入一种或多种分子量为62至1000的多元醇。本发明还涉及多羟基 通过该方法获得的化合物及其与合适的硬化剂的组合使用作为单组分或双组分涂料组合物的粘合剂。

    Powder coating compositions containing polyurethanes having
(meth)acryloyl groups as binders
    43.
    发明授权
    Powder coating compositions containing polyurethanes having (meth)acryloyl groups as binders 失效
    含有(甲基)丙烯酰基作为粘合剂的聚氨酯的粉末涂料组合物

    公开(公告)号:US5068305A

    公开(公告)日:1991-11-26

    申请号:US556223

    申请日:1990-07-20

    摘要: The present invention relates to powder coating compositions which can be cured in the presence of heat and/or high energy radiation and contain polyurethanes which melt at temperatures of 50.degree. to 180.degree. C., have 3 to 10% by weight of olefinic double bonds in the form of (meth)acryloyl groups (calculated as .dbd.C.dbd.C.dbd., molecular weight=24) and are based on the reaction product ofA) 40 to 80 parts by weight of one or more organic polyisocyanates withB) 15 to 50 parts of weight of one or more monohydric alcohols containing (meth)acryloyl groups andC) 2 to 20 parts by weight one or more compounds which are free from (meth)acryloyl groups and contain isocyanate reactive groups.

    摘要翻译: 本发明涉及粉末涂料组合物,其可以在热和/或高能量辐射的存在下固化,并且包含在50-180℃的温度下熔化的聚氨酯,具有3至10重量%的烯属双键 以(甲基)丙烯酰基的形式(以C = C =分子量= 24计算),并且基于A)的反应产物:40至80重量份的一种或多种有机多异氰酸酯与B)15至 50重量份的一种或多种含(甲基)丙烯酰基的一元醇和C)2至20重量份的一种或多种不含(甲基)丙烯酰基并含有异氰酸酯反应性基团的化合物。

    Process for the production of coatings based on unsaturated polyester
resins by hardening under infra-red radiation
    44.
    发明授权
    Process for the production of coatings based on unsaturated polyester resins by hardening under infra-red radiation 失效
    通过红外辐射硬化生产基于不饱和聚酯树脂的涂料的方法

    公开(公告)号:US5068125A

    公开(公告)日:1991-11-26

    申请号:US572348

    申请日:1990-08-27

    CPC分类号: C08G63/676 C09D167/06

    摘要: A coating is obtained on a substrate by applying to the substrate a composition containing as a binder an unsaturated polyester and hardening the coating by infra-red radiation, wherein the binder is a monomer-free olefinically unsaturated polyester resin having a viscosity of 2,000 to 5,000 mPa.s at 23.degree. C. and consists essentially of the esterification reaction product of:A) 1.0 mol of an unsatured dicarboxylic acid component selected from the group consisting of maleic acid, maleic anhydride, fumaric acid and mixtures thereof,B) 0.5 to 1.2 mol of a diol component which is a dihydric alcohol with 2 to 8 carbon atoms,C) 0.5 to 1.1 mol of at least one unsaturated ether component which is a monofunctional hydroxy compound containing one or more .beta.,.gamma.-ethylenically unsaturated alkenyl ether moieties in the molecule, andD) 0 to 0.55 mol of an alcohol component which is a saturated monohydric alcohol with 4 to 10 carbon atoms.and the coating composition is useful as an automotive body repair putty.

    摘要翻译: 通过向基材施加包含作为粘合剂的不饱和聚酯并通过红外辐射硬化涂层的组合物,在基材上获得涂层,其中粘合剂是粘度为2,000至5,000的不含单体的烯属不饱和聚酯树脂 mPa.s,基本上由以下酯化反应产物组成:A)1.0mol选自马来酸,马来酸酐,富马酸及其混合物的未成型二羧酸组分,B)0.5至 1.2摩尔碳原子数为2〜8的二元醇的二醇成分,C)0.5〜1.1摩尔的至少一种不饱和醚成分,它是含有一个或多个β,γ-烯属不饱和烯基醚部分的单官能羟基化合物 和D)0〜0.55mol作为碳原子数为4〜10的饱和一元醇的醇成分。 并且涂料组合物可用作汽车车身修理油灰。