摘要:
The present invention relates to a process for the production of polyhydroxyl compounds having a hydroxyl group content of 2 to 10% by weight and a viscosity at 23.degree. C. of 250 to 80,000 mPa.s by the radically initiated polymerization at a reaction temperature of 80.degree. to 220.degree. C. ofa) 100 parts by weight of a mixture of olefinically unsaturated monomers containing at least 1% by weight of monomers containing alcoholic hydroxyl groups in the presence ofb) 5 to 500 total parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more cyclic compounds which, in the presence of initiator compounds containing alcoholic hydroxyl groups, are capable of a ring-opening polymerization reaction andc) 2 to 300 parts by weight, which may be present at the beginning of the reaction or added during the reaction, of one or more polyhydric alcohols having a molecular weight of 62 to 1000.The present invention also relates to the polyhydroxyl compounds obtained by this process and to their use in combination with suitable hardeners as binders for one-component or two-component coating compositions.
摘要:
A process for the solvent-free production of hydroxy-functional copolymers by copolymerization of unsaturated monomers in a mixture of a polyester component and an unsaturated ester component as reaction medium, the use of the hydroxy-functional copolymers so obtained as binder component in polyurethane powder coatings, a powder coating based on these copolymers and its use for coating any heat resistant substrates.
摘要:
The present invention relates to powder coating compositions which can be cured in the presence of heat and/or high energy radiation and contain polyurethanes which melt at temperatures of 50.degree. to 180.degree. C., have 3 to 10% by weight of olefinic double bonds in the form of (meth)acryloyl groups (calculated as .dbd.C.dbd.C.dbd., molecular weight=24) and are based on the reaction product ofA) 40 to 80 parts by weight of one or more organic polyisocyanates withB) 15 to 50 parts of weight of one or more monohydric alcohols containing (meth)acryloyl groups andC) 2 to 20 parts by weight one or more compounds which are free from (meth)acryloyl groups and contain isocyanate reactive groups.
摘要翻译:本发明涉及粉末涂料组合物,其可以在热和/或高能量辐射的存在下固化,并且包含在50-180℃的温度下熔化的聚氨酯,具有3至10重量%的烯属双键 以(甲基)丙烯酰基的形式(以C = C =分子量= 24计算),并且基于A)的反应产物:40至80重量份的一种或多种有机多异氰酸酯与B)15至 50重量份的一种或多种含(甲基)丙烯酰基的一元醇和C)2至20重量份的一种或多种不含(甲基)丙烯酰基并含有异氰酸酯反应性基团的化合物。
摘要:
A coating is obtained on a substrate by applying to the substrate a composition containing as a binder an unsaturated polyester and hardening the coating by infra-red radiation, wherein the binder is a monomer-free olefinically unsaturated polyester resin having a viscosity of 2,000 to 5,000 mPa.s at 23.degree. C. and consists essentially of the esterification reaction product of:A) 1.0 mol of an unsatured dicarboxylic acid component selected from the group consisting of maleic acid, maleic anhydride, fumaric acid and mixtures thereof,B) 0.5 to 1.2 mol of a diol component which is a dihydric alcohol with 2 to 8 carbon atoms,C) 0.5 to 1.1 mol of at least one unsaturated ether component which is a monofunctional hydroxy compound containing one or more .beta.,.gamma.-ethylenically unsaturated alkenyl ether moieties in the molecule, andD) 0 to 0.55 mol of an alcohol component which is a saturated monohydric alcohol with 4 to 10 carbon atoms.and the coating composition is useful as an automotive body repair putty.
摘要:
Unsaturated polyesters of defined composition with a low content of polyalkylene glycol radicals in a narrow molecular weight range can be dispersed in water without external emulsifiers. These dispersions produce, after hardening, water and chemical resistant coatings with good mechanical properties.