Heat-sensitive positive working lithographic printing plate precursor with a high resistance to chemicals

    公开(公告)号:US20060130689A1

    公开(公告)日:2006-06-22

    申请号:US10526138

    申请日:2003-08-28

    IPC分类号: B41N1/00

    摘要: Heat-sensitive element comprising (a) an optionally pre-treated substrate (b) a positive working heat-sensitive coating comprising (i) at least one novolak resin, (ii) at least one component which reduces the aqueous alkaline developer solubility of novolak, wherein said reduction in solubility is reversed upon the application of heat, and (iii) at least one acidic polyvinyl acetal comprising the structural units (A), (B), (C) (A) (B) (C) and (D) wherein (D) is at least one unit selected from (D-1), (D-2), and (D-3): (D-1) (D-2) (D-3) wherein R1 is a hydrogen atom or a C1-C4 alkyl group, R2 is a hydrogen atom or a C1-C18 alkyl group, R3 is a hydrogen atom or a C1-C4 alkyl group, R4 is a hydrogen atom or a C1-C4 alkyl group, R5 is —COOH, —(CH2)a—COOH, —O—(CH2)a—COOH, —SO3H, —PO3H2 or —PO4H2, a is an integer from 1 to 8, and X is selected from —(CR6R7)n— and —CR8═CR9— wherein n is an integer of 1 to 6, each R6 and R7 is independently selected from a hydrogen atom and C1-C6 alkyl group, and R8 and R9 are independently selected from a hydrogen atom and a C1-C6 alkyl group or R8 and R9 together with the two carbon atoms to which they are bonded, form an optionally substituted aryl or heteroaryl group, wherein components (i) and (ii) do not have to be present as separate substances but may be used in the form of an appropriately functionalized novolak.

    Process for the production of meso-substituted cyanine dyes
    43.
    发明申请
    Process for the production of meso-substituted cyanine dyes 审中-公开
    用于生产中间取代花青染料的方法

    公开(公告)号:US20060128961A1

    公开(公告)日:2006-06-15

    申请号:US10537389

    申请日:2003-12-04

    摘要: A single-step process for the production of meso-substituted cyanine dyes is provided comprising the reaction of a dye (III), with (a) a methylene compound (IV) or (V) or a quaternary salt (VI) or (VII) and (b) a compound selected from functionalized (hetero)aromatic compounds Ar—B, saturated cyclic amines (IV) and heteroaromatic compounds (V).

    摘要翻译: 提供了用于生产中间取代花青染料的单步方法,其包括染料(III)与(a)亚甲基化合物(IV)或(V)或季盐(VI)或(VII )和(b)选自官能化(杂)芳族化合物Ar-B,饱和环胺(IV)和杂芳族化合物(V))的化合物。

    Thermal digital lithographic printing plate
    44.
    发明授权
    Thermal digital lithographic printing plate 有权
    热数码平版印刷版

    公开(公告)号:US06358669B1

    公开(公告)日:2002-03-19

    申请号:US09469489

    申请日:1999-12-22

    IPC分类号: G03F709

    摘要: A thermally imageable element, useful as a lithographic printing plate precursor is disclosed. The element comprises a hydrophilic substrate; an underlayer comprising a first polymeric material; and an ink-receptive top layer comprising a second polymeric material. Preferably, the top layer comprises a compound that functions as a solubility-suppressing component. The solubility-suppressing component may be a separate dissolution inhibitor compound and/or the second polymeric material may also function as a solubility-suppressing component. On thermal exposure the exposed regions of the top layer becomes more readily soluble in an aqueous developer, allowing the developer to remove the top layer and reveal the surface of the hydrophilic substrate. The lithographic printing plate thus formed has excellent properties, including the absence of sludging of the developer.

    摘要翻译: 公开了可用作平版印刷版原版的可热成像元件。 元件包括亲水基底; 包含第一聚合物材料的底层; 以及包含第二聚合物材料的吸墨顶层。 优选地,顶层包含用作溶解度抑制成分的化合物。 溶解性抑制成分可以是单独的溶解抑制剂化合物和/或第二聚合物材料也可以作为溶解度抑制成分起作用。 在热曝光的情况下,顶层的暴露区域变得更容易溶于水性显影剂,使显影剂除去顶层并露出亲水基材的表面。 这样形成的平版印刷版具有优异的性能,包括不存在显影剂的污泥。

    Sulfonamido substituted acetal polymers and use thereof in
photo-sensitive compositions and lithographic printing plates
    46.
    发明授权
    Sulfonamido substituted acetal polymers and use thereof in photo-sensitive compositions and lithographic printing plates 失效
    磺酰胺取代的缩醛聚合物及其在光敏组合物和平版印刷版中的应用

    公开(公告)号:US5698360A

    公开(公告)日:1997-12-16

    申请号:US677703

    申请日:1996-07-10

    IPC分类号: C08F8/34 G03F7/021 G03F7/033

    摘要: The present invention relates to binders and photosensitive compositions comprising said binders. The binder comprises units A, B, C and D, wherein A is present in an amount of 0.5 to 15 wt. % and is of the formula ##STR1## B is present in an amount of 10 to 35 wt. % and is of the formula ##STR2## C is present in an amount of 10 to 50 wt. % and is of the formula ##STR3## wherein R.sup.1 is methyl, ethyl, propyl or isopropyl, and D is present in an amount of 25 to 70 wt. % and is of the formula ##STR4## wherein n is an integer of from 1 to 3 and R.sup.2, R.sup.3 are hydrogen or methyl and R.sup.4 is alkyl, aralkyl or aryl.

    摘要翻译: 本发明涉及包含所述粘合剂的粘合剂和光敏组合物。 粘合剂包含单元A,B,C和D,其中A的存在量为0.5-15wt。 (A)B以10〜35重量%的量存在。 %,并且具有式50重量% %,并且具有式(C)的式(C)其中R 1是甲基,乙基,丙基或异丙​​基,D以25至70重量%的量存在。 %,并且具有式(D)的式(I)其中n是1至3的整数,R 2,R 3是氢或甲基,R 4是烷基,芳烷基或芳基。