Process for the preparation of lithium or sodium bis(fluorosulphonyl)imide
    42.
    发明授权
    Process for the preparation of lithium or sodium bis(fluorosulphonyl)imide 有权
    制备锂或双(氟磺酰基)酰亚胺钠的方法

    公开(公告)号:US09394172B2

    公开(公告)日:2016-07-19

    申请号:US14476106

    申请日:2014-09-03

    申请人: ARKEMA FRANCE

    发明人: Grégory Schmidt

    摘要: A process for the preparation of a bis(sulphonato)imide salt of formula: (III) (SO3−)—N−—(SO3−)3C+ where C+ represents a monovalent cation, comprising the reaction of amidosulphuric acid of formula: (I) (OH)—SO2—NH2 with a halosulphonic acid of formula: (II) (OH)—SO2—X where X represents a halogen atom, and comprising a reaction with a base which is a salt formed with the cation C+. Also, a process for the preparation of bis(fluorosulphonyl)imide acid of formula: (V) F—(SO2)—NH—(SO2)—F and to a process for the preparation of lithium bis(fluorosulphonyl)imide salt of formula: (VII) F—(SO2)—N−—(SO2)—F Li+.

    摘要翻译: 一种制备式(III)(SO 3 - ) - N - (SO 3 - )3 C +的双(磺酸根)酰亚胺盐的方法,其中C +代表一价阳离子,包括下式的酰胺硫酸:(I )(OH)-SO 2 -NH 2与式(II)(OH)-SO 2 -X的卤代磺酸反应,其中X表示卤素原子,并且与与阳离子C +形成的盐的碱反应。 另外,制备式(V)F-(SO 2)-NH-(SO 2)-F的双(氟磺酰基)酰亚胺酸的方法和制备式(II)的双(氟磺酰基)酰亚胺盐 :(VII)F-(SO 2)-N - (SO 2)-F Li +。

    METHOD FOR PRODUCING LITHIUM OR SODIUM BIS(FLUOROSULFONYL)IMIDE
    43.
    发明申请
    METHOD FOR PRODUCING LITHIUM OR SODIUM BIS(FLUOROSULFONYL)IMIDE 有权
    生产柠檬酸钠或氟化钠(氟化膦)的方法

    公开(公告)号:US20140075746A1

    公开(公告)日:2014-03-20

    申请号:US14115909

    申请日:2012-04-06

    申请人: Grégory Schmidt

    发明人: Grégory Schmidt

    摘要: The invention relates to a process for the preparation of a bis(sulphonato)imide salt of formula: (III) (SO3−)—N−—(SO3)3C+  (III) where C+ represents a monovalent cation, comprising the reaction of amidosulphuric acid of formula: (OH)—SO2—NH2  (I) with a halosulphonic acid of formula: (OH)—SO2—X  (II) where X represents a halogen atom, and comprising a reaction with a base which is a salt formed with the cation C+.The invention also relates to a process for the preparation of bis(fluorosulphonyl)imide acid of formula: F—(SO2)—NH—(SO2)—F  (V) and to a process for the preparation of lithium bis(fluorosulphonyl)imide salt of formula: F—(SO2)—N−—(SO2)—F Li+.  (VII)

    摘要翻译: 本发明涉及一种制备式(III)(SO 3 - ) - N - (SO 3)3 C +(III)的双(磺酸根)酰亚胺盐的方法,其中C +表示一价阳离子,其包括酰胺硫 式(OH)-SO 2 -NH 2(I)的酸与式(OH)-SO 2 -X(II)的卤代磺酸反应,其中X表示卤素原子,并且与形成的盐的碱反应 与阳离子C +。 本发明还涉及一种制备式(F)(SO 2)-NH-(SO 2)-F(V)的双(氟磺酰基)酰亚胺酸的方法和制备双(氟磺酰基)酰亚胺锂的方法 式:F-(SO 2)-N - (SO 2)-F Li +的盐。 (七)

    PROCESS FOR PRODUCING FLUORINE-CONTAINING SULFONYLIMIDE SALT
    44.
    发明申请
    PROCESS FOR PRODUCING FLUORINE-CONTAINING SULFONYLIMIDE SALT 有权
    生产含氟化物磺酰亚胺盐的方法

    公开(公告)号:US20130323155A1

    公开(公告)日:2013-12-05

    申请号:US13985915

    申请日:2012-02-28

    IPC分类号: C01B21/086

    摘要: By reacting a fluorine-containing sulfonylimide ammonium salt such as ammonium N,N-di(fluorosulfonyl)imide with an alkali metal hydroxide such as lithium hydroxide, potassium hydroxide or sodium hydroxide under reduced pressure and at a low temperature of approximately 40° C., a fluorine-containing sulfonylimide alkali metal salt such as lithium N,N-di(fluorosulfonyl)imide, potassium N,N-di(fluorosulfonyl)imide or sodium N,N-di(fluorosulfonyl)imide is obtained.

    摘要翻译: 使N,N-二(氟磺酰基)酰亚胺铵等含氟磺酰亚胺铵盐与碱金属氢氧化物如氢氧化锂,氢氧化钾或氢氧化钠在减压下和约40℃的低温下反应。 得到N,N-二(氟磺酰基)酰亚胺锂,N,N-二(氟磺酰基)酰亚胺钾,N,N-二(氟磺酰基)酰亚胺钠等含氟磺酰亚胺碱金属盐。

    Method for Producing Imide Compound
    45.
    发明申请
    Method for Producing Imide Compound 有权
    生产酰亚胺化合物的方法

    公开(公告)号:US20120020867A1

    公开(公告)日:2012-01-26

    申请号:US13258988

    申请日:2010-03-29

    摘要: Disclosed is a method for producing “a salt or a complex comprising imide and an organic base”, characterized by reacting halogenated sulfuryl or halogenated phosphoryl with ammonia in the presence of an organic base. According to this method, a target imide compound can be produced in a high yield while significantly suppressing the production of by-products. Further, by reacting the obtained imide compound with an alkali metal hydroxide or an alkaline earth metal hydroxide, an imide metal salt can be easily derived.

    摘要翻译: 公开了一种生产“含有酰亚胺和有机碱的盐或络合物”的方法,其特征在于在有机碱存在下使卤代磺酰基或卤代磷酰基与氨反应。 根据该方法,可以高产率地制造目标酰亚胺化合物,同时显着抑制副产物的生成。 此外,通过使所得酰亚胺化合物与碱金属氢氧化物或碱土金属氢氧化物反应,可以容易地得到酰亚胺金属盐。