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公开(公告)号:US10287518B2
公开(公告)日:2019-05-14
申请号:US15538447
申请日:2015-12-15
发明人: Arno Johannes Maria Oprins , Andrew P. Davies , Andrew Mark Ward , Kae Shin Wong , Luis Aramburo , Maikel Van Iersel
摘要: The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon feedstream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream comprising C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, wherein at least part of the middle hydrocarbon stream is recycled back to the first hydrocracking in step a).
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公开(公告)号:US10087378B2
公开(公告)日:2018-10-02
申请号:US15538391
申请日:2015-12-15
发明人: Arno Johannes Maria Oprins , Andrew Mark Ward , Andrew P. Davies , Kae Shin Wong , Luis Aramburo , Maikel Van Iersel
摘要: The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, d) wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.
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公开(公告)号:US20170349843A1
公开(公告)日:2017-12-07
申请号:US15538356
申请日:2015-12-15
发明人: Arno Johannes Maria Oprins , Andrew P. Davies , Andrew Mark Ward , Kae Shin Wong , Luis Aramburo , Maikel Van Iersel
CPC分类号: C10G65/10 , C10G65/00 , C10G65/18 , C10G2400/20 , C10G2400/26 , C10G2400/28 , C10G2400/30
摘要: The invention relates to a process for producing C2 and C3 hydrocarbons, comprising a) subjecting a mixed hydrocarbon feedstream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide a light hydrocarbon stream comprising C4− hydrocarbons and c) subjecting the light hydrocarbon stream to C4 hydrocracking in the presence of a C4 hydrocracking catalyst to obtain a C4 hydrocracking product stream comprising C2 and C3 hydrocarbons.
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公开(公告)号:US09631150B2
公开(公告)日:2017-04-25
申请号:US14180623
申请日:2014-02-14
CPC分类号: C10G65/10 , C10G65/00 , C10G65/12 , C10G65/18 , C10G2300/1059 , C10G2400/02 , C10G2400/04 , C10L1/04 , C10L1/06 , C10L1/08
摘要: Embodiments herein relate to a process flow scheme for the processing of gas oils and especially reactive gas oils produced by thermal cracking of residua using a split flow concept. The split flow concepts disclosed allow optimization of the hydrocracking reactor seventies and thereby take advantage of the different reactivities of thermally cracked gas oils versus those of virgin gas oils. This results in a lower cost facility for producing base oils as well as diesel, kerosene and gasoline fuels while achieving high conversions and high catalyst lives.
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公开(公告)号:US09359566B2
公开(公告)日:2016-06-07
申请号:US13559820
申请日:2012-07-27
申请人: Omer Refa Koseoglu
发明人: Omer Refa Koseoglu
CPC分类号: C10G65/14 , C10G21/16 , C10G67/0418 , C10G67/0445 , C10G2300/1096 , C10G2300/202 , C10G2300/44 , C10G2400/02 , C10G2400/04
摘要: Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatic-rich and aromatic-lean fractions separately, the hydrocracking operating severity and/or catalyst reactor volume requirement decreases.
摘要翻译: 整合芳香提取和加氢裂化工艺,以优化加氢裂化装置的设计和/或性能。 通过分别处理富含芳香族和芳香族馏分,加氢裂化操作严重度和/或催化剂反应器体积要求降低。
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公开(公告)号:US09068132B2
公开(公告)日:2015-06-30
申请号:US13233477
申请日:2011-09-15
申请人: Shuwu Yang , Julie Chabot , Bruce Edward Reynolds , Bo Kou
发明人: Shuwu Yang , Julie Chabot , Bruce Edward Reynolds , Bo Kou
IPC分类号: C10G47/26 , C10G47/32 , C10G47/36 , C10G65/00 , C10G65/10 , C10G65/18 , C10G47/00 , C10G47/02
CPC分类号: C10G47/02 , C10G47/26 , C10G47/32 , C10G47/36 , C10G65/00 , C10G65/10 , C10G65/18 , C10G2300/205 , C10G2300/4075 , C10G2300/701 , C10G2300/802
摘要: A method to reduce metal deposit in the hydroprocessing or upgrade of heavy oil feedstock is provided. The method comprises feeding an improved catalyst feed to the system, with the improved catalyst feed comprising a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed for the heavy oil upgrade system to have at least a 5% reduction in metal contaminant build-up compared to heavy oil upgrade system without the deoiled spent catalyst in the feed.
摘要翻译: 提供了一种在重油原料的加氢处理或升级中减少金属沉积的方法。 该方法包括将改进的催化剂进料进料给系统,改进的催化剂进料包含新鲜的浆料催化剂和脱油的废催化剂,脱油的废催化剂的存在量为重油的催化剂进料的至少10% 升级系统与重油升级系统相比,金属污染物累积量减少至少5%,而在进料中没有脱油废催化剂。
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公开(公告)号:US08927448B2
公开(公告)日:2015-01-06
申请号:US13233491
申请日:2011-09-15
申请人: Bo Kou , Julie Chabot
发明人: Bo Kou , Julie Chabot
CPC分类号: C10G47/02 , C10G47/26 , C10G47/32 , C10G65/00 , C10G65/10 , C10G65/18 , C10G2300/205 , C10G2300/206 , C10G2300/701 , C10G2300/802
摘要: A method to prepare an improved catalyst feed to a system to upgrade heavy oil. The method comprises: providing a spent catalyst that has been used in a hydroprocessing operation has with a solid content ranging from 5 to 50 wt. % in soluble hydrocarbons and having less than 80% but more than 10% of original catalytic activity; removing at least 50% of the soluble hydrocarbons removed in a deoiling step; treating the deoiled spent catalyst with a treating solution containing at least one of plain water, a mineral acid, an oxidizing agent, and combinations thereof to reduce the concentration of at least one metal contaminant in the deoiled spent catalyst by at least 40%. After treatment, the treated deoiled spent catalyst is slurried in a hydrocarbon medium, and fed to the heavy oil upgrade system as part of the catalyst feed system with a fresh slurry catalyst.
摘要翻译: 一种制备改进的催化剂进料到系统以升级重油的方法。 该方法包括:提供已经在加氢操作中使用的废催化剂的固体含量范围为5-50wt。 %的可溶性碳氢化合物,并且具有小于80%但大于10%的原始催化活性; 去除在脱油步骤中去除的至少50%的可溶性烃; 用含有浅水,无机酸,氧化剂及其组合中的至少一种的处理溶液处理脱油的废催化剂,以将去除的废催化剂中的至少一种金属污染物的浓度降低至少40%。 处理后,经处理的脱油废催化剂在烃介质中浆化,并作为催化剂进料系统的一部分用新鲜的浆料催化剂进料至重油升级系统。
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公开(公告)号:US08759242B2
公开(公告)日:2014-06-24
申请号:US13233455
申请日:2011-09-15
申请人: Shuwu Yang , Julie Chabot , Bruce Edward Reynolds
发明人: Shuwu Yang , Julie Chabot , Bruce Edward Reynolds
CPC分类号: C10G47/02 , C10G47/26 , C10G47/32 , C10G65/00 , C10G65/10 , C10G65/18 , C10G2300/701 , C10G2300/802
摘要: An improved slurry catalyst feed system for heavy oil upgraded is provided. The catalyst feed system comprises a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed system. The deoiled spent catalyst is a slurry catalyst that has been used in a hydroprocessing operation resulting in than 80% but more than 10% of original catalytic activity, and containing less than 10 wt. % soluble hydrocarbons as unconverted heavy oil feed. The deoiled spent catalyst is slurried in a hydrocarbon medium as dispersed particles prior to being fed to the heavy oil upgrade system.
摘要翻译: 提供了一种用于重油升级的改进的浆料催化剂进料系统。 催化剂进料系统包括新鲜的浆料催化剂和脱油的废催化剂,脱油的废催化剂的存在量为催化剂进料体系的至少10%。 脱油的废催化剂是在加氢操作中使用的浆料催化剂,其导致比原始催化活性高80%但大于10%,并且含有少于10wt。 %可溶性烃作为未转化的重油进料。 脱油废催化剂在烃介质中作为分散颗粒在进料到重油升级系统之前浆化。
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49.
公开(公告)号:US5525209A
公开(公告)日:1996-06-11
申请号:US330820
申请日:1994-10-24
IPC分类号: B01J23/85 , B01J29/16 , C10G45/08 , C10G45/50 , C10G47/20 , C10G49/04 , C10G49/08 , C10G65/12 , C10G65/18
CPC分类号: C10G65/12
摘要: A process for the joint production of middle distillates and oil bases (viscosity index between 95 and 150) particularly from vacuum distillates and/or deasphalted oils, comprises a first step in which the feedstock is brought into contact with an amorphous catalyst containing at least one metal or metallic compound with a hydro-dehydrogenating function, such as Ni, Mo, W or Co, at a temperature of between 350.degree. C. and 430.degree. C., a pressure of between 5 and 20 MPa, a space velocity of between 0.1 and 5 h.sup.-1 in the presence of hydrogen in a ratio H.sub.2 /HC of 150 to 2,000 by volume. The product from the first step is brought into contact in a second step with a second catalyst comprising a support, a Y zeolite, at least one group VIB element and at least one group VIII metal at a temperature of between 350.degree. C. and 430.degree. C., a pressure of between 5 and 20 MPa and a space velocity of between 0.1 and 5 h.sup.-1.
摘要翻译: 中间馏分和油基(尤其是真空馏分油和/或脱沥青油)粘度指数在95至150之间的联合生产方法包括第一步,其中原料与含有至少一种 具有氢脱氢功能的金属或金属化合物,例如Ni,Mo,W或Co,在350℃至430℃之间的温度下,压力为5至20MPa之间,空间速度介于 0.1和5h -1,在H 2 / HC比为150-2,000的氢存在下。 在第二步骤中,使第二催化剂在350℃和430℃之间的温度下与第二催化剂接触,所述第二催化剂包括载体,Y沸石,至少一种VIB族元素和至少一种VIII族金属 ℃,压力为5〜20MPa,空速为0.1〜5h -1。
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公开(公告)号:US4618412A
公开(公告)日:1986-10-21
申请号:US760835
申请日:1985-07-31
申请人: Carl W. Hudson , Glen P. Hamner
发明人: Carl W. Hudson , Glen P. Hamner
CPC分类号: C10G65/12
摘要: A process for hydrocracking a hydrocarbon feedstock having a propensity to form polynuclear aromatic hydrocarbon compounds to suppress fouling the processing unit. The hydrocracking method includes contacting the hydrocarbon feedstock with a crystalline zeolite hydrocracking catalyst, contacting at least a portion of the resulting unconverted hydrocarbon oil containing polynuclear aromatic compounds with an iron catalyst in the presence of hydrogen to hydrogenate and hydrocrack the polynuclear aromatic hydrocarbon compounds, and recycling unconverted hydrocarbon oil having a reduced concentration of polynuclear aromatic compounds to the hydrocracking zone.
摘要翻译: 用于加氢裂解形成多环芳烃化合物倾向的烃原料以抑制处理单元结垢的方法。 加氢裂化方法包括使烃原料与结晶沸石加氢裂化催化剂接触,使含有多核芳族化合物的所得未转化烃油的至少一部分与铁催化剂在氢气存在下接触以氢化和加氢裂化多核芳族烃化合物,以及 将具有降低的多核芳族化合物浓度的未转化碳氢化合物再循环至加氢裂化区。
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