摘要:
The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, d) wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.
摘要:
A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, including a heteropolyacid. Contacting the zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution from the multifunctional catalyst precursor and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support.
摘要:
The present invention relates to a process for upgrading refinery heavy residues to petrochemicals, comprising the following steps of: (a) separating a hydrocarbon feedstock in a distillation unit into a to overhead stream and a bottom stream (b) feeding said bottom stream to a hydrocracking reaction area (c) separating reaction products, which are generated from said reaction area of step (b) into a stream rich in mono-aromatics and in a stream rich in poly-aromatics (d) feeding said stream rich in mono-aromatics to a gasoline hydrocracker (GHC) unit, (e) feeding said stream rich in poly-aromatics to a ring opening reaction area.
摘要:
The invention relates to a process for producing C2 and C3 hydrocarbons, comprising a) subjecting a mixed hydrocarbon carbon stream comprising a middle distillate to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream, b) subjecting a second hydrocracking feed stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream, wherein the second hydrocracking is more severe than the first hydrocracking and c) subjecting a C4 hydrocracking feed stream to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to obtain a C4 hydrocracking product stream, wherein the C4 hydrocracking is more severe than the second hydrocracking, wherein the first hydrocracking product stream, the second hydrocracking product stream and the C4 hydrocracking product stream are fed to a separation system which provides —the second hydrocracking feed stream separated from the first hydrocracking product stream, —the C4 hydrocracking feed stream separated from the second hydrocracking product stream, —a first recycle stream to be recycled back to the first hydrocracking, —a second recycle stream to be recycled back to the second hydrocracking, —a third recycle stream to be recycled back to the C4 hydrocracking, —a hydrogen recycle stream of H2 or H2 and C1 to be recycled back to the first hydrocracking, the second hydrocracking and/or the C4 hydrocracking and —a C2 and C3 product stream of C3− hydrocarbons, wherein the second hydrocracking feed stream is a stream of C12− hydrocarbons excluding C10-C12 hydrocarbons having di-ring structures, wherein the first recycle stream is a stream of C13+ and C10-C12 hydrocarbons having di-ring structures, wherein the C4 hydrocracking feed stream is a stream of C5−, C4− or iC4−, wherein the second recycle stream is a stream of C6+, C5+ or nC4+ 30 wherein the third recycle stream is a stream of nC4+ or C4+.
摘要:
The invention relates to a process for producing C2 and C3 hydrocarbons, comprising a) subjecting a mixed hydrocarbon feedstream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide a light hydrocarbon stream comprising C4− hydrocarbons and c) subjecting the light hydrocarbon stream to C4 hydrocracking in the presence of a C4 hydrocracking catalyst to obtain a C4 hydrocracking product stream comprising C2 and C3 hydrocarbons.
摘要:
Methods and apparatuses for processing hydrocarbons are provided. In one embodiment, a method for processing a hydrocarbon stream including lighter hydrocarbons and heavier hydrocarbons includes hydrocracking the lighter hydrocarbons in a hydrocracking reactor. After hydrocracking the lighter hydrocarbons, the method hydrocracks the heavier hydrocarbons in the hydrocracking reactor. The method includes removing from the hydrocracking reactor a hydrocracking effluent comprising a mixture of components formed by hydrocracking the lighter hydrocarbons and hydrocracking the heavier hydrocarbons.
摘要:
A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a second hydrocarbon stream in a hydrocracking unit. The hydrocracking unit and the hydrotreating unit may share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. The second hydrocarbon stream may be a diesel stream from the hydrotreating unit. The diesel stream may be a diesel and heavier stream from a bottom of a hydrotreating fractionation column.
摘要:
A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. In the once-through upgrade system, little if any of the unconverted material and slurry catalyst mixture is recycled back to the system for further upgrading. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. The slurry catalyst feed comprises an active metal catalyst having an average particle size of at least 1 micron in a hydrocarbon oil diluent, at a concentration of greater than 500 wppm of active metal catalyst to heavy oil feedstock.
摘要:
The present invention relates to a process for converting Fischer-Tropsch wax to high quality lube basestocks using a molecular sieve Beta catalyst followed by a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/Beta catalyst followed by a second bed Pt/ZSM-48 catalyst is highly selective for wax isomerization and lube hydrodewaxing with minimal gas formation.