Catalyst for polymerizing aromatic vinyl compound and process for
producing polymer of aromatic vinyl compound
    52.
    发明授权
    Catalyst for polymerizing aromatic vinyl compound and process for producing polymer of aromatic vinyl compound 失效
    用于芳族乙烯基化合物聚合的催化剂和芳族乙烯基化合物聚合物的制备方法

    公开(公告)号:US5342813A

    公开(公告)日:1994-08-30

    申请号:US960705

    申请日:1992-10-14

    申请人: Akira Miyashita

    发明人: Akira Miyashita

    摘要: A catalyst for polymerizing an aromatic vinyl compound is provided which is composed of a catalyst component (A) and a catalyst component (B); the catalyst component (A) being a reaction product derived by reacting an organic transition metal compound having a substituted or unsubstituted cyclopentadienyl group, with an alkylaluminum compound, and represented by the general formula (I): ##STR1## where C.sub.5 R.sup.1.sub.m is a substituted or unsubstituted cyclopentadienyl group: R is hydrogen or a hydrocarbon group having 1 to 20 carbons, each R.sub.1 being independent; R.sup.2 is an alkylene group having 1 to 4 carbons, a dialkylsilicon group, a dialkylgermanium group, an alkylphoshine group, or an alkylamine group, the alkylene or alkyl group, and R.sup.2 crosslinks the two (C.sub.5 R.sup.1.sub.m) rings; m is an integer of 0 to 5; n is 0 or 1; when n=0, m=5, Q is an alkyl group or a halogen atom; R.sup.3 is a hydrocarbon group having 1 to 18 carbons; and M is a metal of Group IVB of Periodic Table; and the catalyst component (B) being an aluminoxane represented by the general formula (II) or (III): ##STR2## where p is an integer of 4 to 30, and R.sup.4 is a hydrocarbon group. A process for producing a polymer of an aromatic vinyl compound is also provided which comprises polymerizing the aromatic vinyl compound in the presence of the catalyst specified above.

    摘要翻译: 提供由催化剂组分(A)和催化剂组分(B)组成的用于聚合芳族乙烯基化合物的催化剂; 催化剂组分(A)是通过使具有取代或未取代的环戊二烯基的有机过渡金属化合物与烷基铝化合物反应而得到并由通式(I)表示的反应产物:R为 氢或碳原子数1〜20的烃基,每个R 1独立; R2是具有1至4个碳原子的亚烷基,二烷基硅烷基,二烷基锗基,烷基膦基或烷基胺基,亚烷基或烷基,和R2交联两个(C5R1m)环; m为0〜5的整数。 n为0或1; 当n = 0时,m = 5,Q是烷基或卤素原子; R3是碳原子数1〜18的烃基, M为周期表IVB族金属; 催化剂组分(B)是由通式(II)或(III)表示的铝氧烷:其中p是4-30的整数,R4是烃 组。 还提供了一种制备芳族乙烯基化合物聚合物的方法,其包括在上述催化剂存在下使芳族乙烯基化合物聚合。

    Crystal comprising an indolinospirobenzothiopyran derivative and its
ring opened isomer
    53.
    发明授权
    Crystal comprising an indolinospirobenzothiopyran derivative and its ring opened isomer 失效
    包含吲哚螺四苯并噻喃衍生物及其开环异构体的晶体

    公开(公告)号:US5320784A

    公开(公告)日:1994-06-14

    申请号:US938045

    申请日:1992-11-12

    申请人: Akira Miyashita

    发明人: Akira Miyashita

    CPC分类号: C07D495/10 G03C1/685

    摘要: The object of this invention is to provide a novel compound suited for use as a piezochromic material.This invention relates to a crystal comprising an indolinospirobenzothiopyran derivative of the following general formula and its ring opened isomer. ##STR1## wherein R.sup.1 stands for C.sub.1-20 alkyl, aralkyl, methacryloxymethyl or a methacryloxyethyl; R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 may for example be hydrogen; R.sup.8 may for example be hydrogen or methacryloxymethyl.The invention further relates to a process for producing the crystal.

    摘要翻译: PCT No.PCT / JP92 / 00294 Sec。 371日期:1992年11月12日 102(e)日期1992年11月12日PCT 1991年3月11日PCT公布。 公开号WO92 / 16531 日本公开日1992年10月1日。本发明的目的是提供一种适用于压电色素材料的新型化合物。 本发明涉及包含以下通式的吲哚螺四苯并噻喃衍生物及其开环异构体的晶体。 其中R1代表C1-20烷基,芳烷基,甲基丙烯酰氧基甲基或甲基丙烯酰氧基乙基; R2,R3,R4,R5,R6和R7可以例如是氢; R8可以例如是氢或甲基丙烯酰氧基甲基。 本发明还涉及一种生产该晶体的方法。

    Clear liquid skin cosmetic compositions
    54.
    发明授权
    Clear liquid skin cosmetic compositions 失效
    透明液体皮肤化妆品组合物

    公开(公告)号:US4481187A

    公开(公告)日:1984-11-06

    申请号:US462720

    申请日:1983-02-01

    摘要: Disclosed is a clear liquid skin cosmetic composition (e.g., a lotion) in which one or more oily substances (such as oil-soluble perfumes, hormones and the like) are solubilized in water with the aid of a solubilizing agent comprising an 18.alpha.-glycyrrhizin (18.alpha.-glycyrrhizic acid sodium salt, potassium salt or ammonium salt) that is a novel compound derived from a conventional glycyrrhizin (i.e., any form of 18.beta.-glycyrrhizin extracted from licorice root) or a glycyrrhizin composition consisting of an 18.alpha.-glycyrrhizin and an 18.beta.-glycyrrhizin. This skin cosmetic composition is not irritative to the skin as contrasted with skin cosmetic compositions prepared by using a synthetic surface-active agent as the solubilizing agent, and is not subject to gelation in a slightly acidic to acidic pH range as contrasted with skin cosmetic compositions prepared by using an 18.beta.-glycyrrhizin alone as the solubilizing agent. Moreover, this skin cosmetic composition exerts a mild action on the skin without causing irritation thereto, gives an agreeable feeling, and has excellent fluidity, usability and storage stability.

    摘要翻译: 公开了一种透明的液体皮肤化妆品组合物(例如洗剂),其中一种或多种油性物质(例如油溶性香料,激素等)借助于包含18α- 甘草甜素(18α-甘草酸钠盐,钾盐或铵盐),其是衍生自常规甘草酸的新化合物(即从甘草根提取的任何形式的18β-甘草甜素)或由18α- 甘草甜素和18β-甘草甜素。 与通过使用合成表面活性剂作为增溶剂制备的皮肤化妆品组合物相比,该皮肤化妆品组合物对皮肤不刺激,并且与皮肤化妆品组合物相比,在略微酸性至酸性pH范围内不经历凝胶化 通过使用单独的18β-甘草甜素作为增溶剂制备。 此外,该皮肤化妆品组合物对皮肤施加温和的作用而不会引起刺激,产生舒适的感觉,并且具有优异的流动性,可用性和储存稳定性。