Abstract:
A polybenzimidazole based polymer in which substituted or non-substituted benzyl groups are introduced to the two nitrogen atoms of benzimidazole ring. The benzimidazole ring is not decomposed by the attack of hydroxide ions but shows excellent alkali resistance, and thus maintains high ion conductivity. The polybenzimidazole based polymers are particularly useful for not only solid alkali exchange membrane fuel cells (SAEMFC) but also various industrial fields in which polybenzimidazole based polymers are used.
Abstract:
A polymer electrolyte membrane fuel cell is provided. The polymer electrolyte membrane fuel cell includes a phosphoric acid-doped polyimidazole electrolyte membrane and a complex catalyst. In the complex catalyst, an alloy or mixture of a metal and a chalcogen element is supported on a carbon carrier. The polymer electrolyte membrane fuel cell exhibits further improved long-term operation, power generation efficiency, and operational stability at high temperature. The complex catalyst can be produced by a simple method.
Abstract:
Provided are a ceria-based composition having an undoped or metal-doped ceria and an undoped or metal-doped bismuth oxide, wherein the undoped or metal-doped bismuth oxide is present in an amount equal to or more than about 10 wt % and less than about 50 wt % based on the total weight of the ceria-based composition, and at least one selected from the ceria and the bismuth oxide is metal-doped. The ceria-based composition may ensure high sintering density even at a temperature significantly lower than the known sintering temperature of about 1400° C., i.e., for example at a temperature of about 1000° C. or lower, and increase ion conductivity as well.
Abstract:
Provided are a perfluorinated sulfonic acid polymer membrane having a porous surface layer, which includes a surface layer and a bottom layer present at the bottom of the surface layer, wherein the surface layer is a porous layer, and the bottom layer is non-porous dense layer, and a method for preparing the same through a solvent evaporation process.
Abstract:
Provided is poly(benzimidazole-co-benzoxazole) having polybenzimidazole to which benzoxazole units are introduced, as a polymer electrolyte material. The polymer electrolyte material has both high proton conductivity and excellent mechanical properties even when it is obtained by in-situ phosphoric acid doping. The polymer electrolyte material may substitute for the conventional phosphoric acid-doped polybenzimidazole in a polymer electrolyte membrane fuel cell, particularly in a high-temperature polymer electrolyte membrane fuel cell.