PBI modification and cross-linking methods

    公开(公告)号:US09873768B2

    公开(公告)日:2018-01-23

    申请号:US14979039

    申请日:2015-12-22

    IPC分类号: C08G73/18 C08G73/06

    CPC分类号: C08G73/18 C08G73/0677

    摘要: The present disclosure provides methods for modifying and cross-linking polybenzimidazoles, PBI. In one embodiment, the polybenzimidazole reacts with a compound, which has a halogen and a double bond functionality and which comprises a halogen and an organic group to form modified polymers by means of a nucleophilic substitution of the amine proton of the benzimidazole functionality in a solution, and a functional group is connected via each resulting free double bond and/or the polymers that are thus modified are cross-linked.

    Aromatic polymer ion exchange membranes, its composite membrane, and its application in acidic electrolyte flow battery
    10.
    发明授权
    Aromatic polymer ion exchange membranes, its composite membrane, and its application in acidic electrolyte flow battery 有权
    芳香族聚合物离子交换膜,其复合膜及其在酸性电解液流动电池中的应用

    公开(公告)号:US09276282B2

    公开(公告)日:2016-03-01

    申请号:US13395991

    申请日:2010-06-25

    摘要: A polymer ion exchange membrane for acidic electrolyte flow battery. The membrane is nitrogen heterocycles aromatic polymer, especially polybenzimidazole type polymer. A nitrogen heterocycles in the membrane interact with acid in the electrolyte to form donor-receptor proton transport network, so as to keep the proton transport performance of the membrane. The preparation condition for the membrane is mild, and the process is simplicity. The preparation method is suitable for mass production. The membrane is used in acidic electrolyte flow battery, especially in vanadium flow energy storage battery. The membrane has excellent mechanical stability and thermostability. In vanadium redox flow battery, the membrane has excellent proton conduct performance and excellent resistance to the permeation of vanadium ions.

    摘要翻译: 一种用于酸性电解液流动电池的聚合物离子交换膜。 膜是氮杂环芳族聚合物,特别是聚苯并咪唑型聚合物。 膜中的氮杂环与电解质中的酸相互作用以形成供体 - 受体质子转运网络,以保持膜的质子转运性能。 膜的制备条件温和,工艺简单。 该制备方法适合批量生产。 该膜用于酸性电解液流动电池,特别是在钒流量蓄能电池中。 膜具有优异的机械稳定性和热稳定性。 在钒氧化还原液流电池中,膜具有优异的质子传导性能和优异的耐钒离子渗透性。