公开(公告)号：US4772628A

公开(公告)日：1988-09-20

申请号：US946202

申请日：1986-12-24

申请人： Norihiro Kakimoto ,  Nobuo Tanaka ,  Isao Sato ,  Katsuyuki Sato

发明人： Norihiro Kakimoto ,  Nobuo Tanaka ,  Isao Sato ,  Katsuyuki Sato

IPC分类号： C07F7/30 ,  A01N9/00 ,  C07D7/30

CPC分类号： C07F7/30

摘要： This invention discloses organogermanium compounds characterized in being expressed by the following formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 respectively denote a hydrogen atom, a lower alkyl group, or a substituted or unsubstituted phenyl group, Y denotes an oxygen or sulfur atom, and Z denotes a hydroxyl group, an amino, or a lower alkoxy group, and antitumor agents comprising as a principal agent these compounds.

摘要翻译： 本发明公开了以下式表示的有机锗化合物：其中R1，R2和R3分别表示氢原子，低级烷基或取代或未取代的苯基，Y表示氧或 硫原子，Z表示羟基，氨基或低级烷氧基，以及包含作为主要试剂的这些化合物的抗肿瘤剂。

公开(公告)号：US4758995A

公开(公告)日：1988-07-19

申请号：US820326

申请日：1986-01-21

申请人： Katsuyuki Sato

发明人： Katsuyuki Sato

IPC分类号： G11C11/401 ,  G06F12/02 ,  G11C7/00 ,  G11C11/409 ,  G11C11/4096 ,  G11C8/00

CPC分类号： G11C11/4096

摘要： An improved DRAM having a plurality of main amplifiers for amplifying and storing signals read out to a plurality of common data lines in accordance with an internal address signal; a main amplifier control circuit for outputting the outputs of the main amplifiers sequentially in synchronism with changes in a column address strobe signal; an address counter for performing an addressing operation midway in the sequential reading operations of the plural main amplifiers; and a column selecting circuit for switching column switches in accordance with the address counter to cause data to be read out continuously at a high speed by extending a nibble mode.

摘要翻译： 一种改进的DRAM，具有多个主放大器，用于根据内部地址信号放大并存储读出到多个公共数据线的信号; 主放大器控制电路，用于与列地址选通信号的变化同步地顺序地输出主放大器的输出; 用于在多个主放大器的顺序读取操作中中途进行寻址操作的地址计数器; 以及列选择电路，用于根据地址计数器切换列开关，以通过扩展半字节模式以高速连续读出数据。

公开(公告)号：US09860901B2

公开(公告)日：2018-01-02

申请号：US13033383

申请日：2011-02-23

申请人： Katsuyuki Sato

发明人： Katsuyuki Sato

IPC分类号： H04L27/00 ,  G10L19/00 ,  H04L27/04 ,  H04N5/38 ,  H04W72/04

CPC分类号： H04W72/0486

摘要： A transmission device includes: a communication unit that communicates with a plurality of reception devices; a transmission data setting unit that compares the number of the reception devices as transmission targets of transmission data representing content and a predetermined threshold value and sets the transmission data to be transmitted to the reception devices to each reception device based on a result of the comparison such that a transmission rate for transmission that represents an amount of data transmission necessary to transmit the transmission data to the reception devices does not exceed a reference transmission rate representing an amount of data transmission at which data can be transmitted in the communication, and the transmission data having relatively high reproduction quality is transmitted to the reception devices as the transmission targets; and a transmission processing unit that concurrently transmits the transmission data set by the transmission data setting unit to the corresponding reception devices as the transmission targets.

公开(公告)号：US09610634B2

公开(公告)日：2017-04-04

申请号：US13496581

申请日：2010-09-10

申请人： Yoshiyama Kaneumi ,  Katsuyuki Sato

发明人： Yoshiyama Kaneumi ,  Katsuyuki Sato

IPC分类号： C09K3/18 ,  B22C3/00 ,  B29C33/62 ,  C08G65/00 ,  A01N1/02 ,  C08G65/335 ,  C08L71/00 ,  B29K105/00 ,  C08K5/5337

CPC分类号： B22C3/00 ,  A01N1/021 ,  B29C33/62 ,  B29K2105/0064 ,  C08G65/007 ,  C08G65/3353 ,  C08G2650/48 ,  C08K5/5337 ,  C08L71/00

摘要： Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: CnF2n+1CH2CH2P(O)(OM1)(OM2) [III] (M1: a hydrogen atom, ammonium salt, or organic amine salt, M2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C3F6O)p(C2F4O)q(CF2O)rRf′ [I] (Rf and Rf′: C1-C5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF2CF2CF2O)nCF2CF3 [II] (n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.

公开(公告)号：US09120833B2

公开(公告)日：2015-09-01

申请号：US13383299

申请日：2010-06-23

申请人： Seiichiro Murata ,  Katsuyuki Sato

发明人： Seiichiro Murata ,  Katsuyuki Sato

IPC分类号： C07F9/02 ,  C07F9/40

CPC分类号： C07F9/4006

摘要： A polyfluoroalkylphosphonic acid ester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2 (R is an alkyl group having 1 to 4 carbon atoms, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3) is produced by a process of reacting a polyfluoroalkyl iodide represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with a trialkyl phosphite represented by the general formula: P(OR)3 or by a process of reacting a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH═CH2 with a dialkyl phosphite represented by the general formula: (RO)2P(O)H.

摘要翻译： 由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OR）2表示的多氟烷基膦酸酯（R是具有1至4个碳原子的烷基，n是 1〜6，a为1〜4的整数，b为1〜3的整数，c为1〜3的整数）通过使由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cI与由通式P（OR）3表示的亚磷酸三烷基酯反应，或通过使由通式C n F 2n + 1表示的多氟-1-烯烃 CH 2 CF 2）a（CF 2 CF 2）b CH = CH 2与由通式（RO）2 P（O）H表示的亚磷酸二烷基酯反应。

公开(公告)号：US08501888B2

公开(公告)日：2013-08-06

申请号：US12677187

申请日：2008-07-16

申请人： Satoshi Kurihara ,  Seiichiro Murata ,  Katsuyuki Sato ,  Masayosi Horiuti ,  Sumiko Mouri ,  Hideki Abe ,  Ji-Shan Jin

发明人： Satoshi Kurihara ,  Seiichiro Murata ,  Katsuyuki Sato ,  Masayosi Horiuti ,  Sumiko Mouri ,  Hideki Abe ,  Ji-Shan Jin

IPC分类号： C08F18/20

CPC分类号： C09K3/18 ,  C08F220/18 ,  C08F220/24 ,  C08F220/26

摘要： A fluorine-containing polymer comprising a fluoroalkyl alcohol (meth)acrylic acid derivative represented by a general formula, CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2 (in the formula, R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, preferably 2 to 4, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3) containing in 5 to 100 wt % as a polymerization unit. A organic solvent solution or aqueous dispersion of the fluorine-containing polymer is effectively used as, for example, a surface-modifying agent such as a water- and oil-repellent or an oil barrier.

摘要翻译： 包含由通式CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cOCOCR = CH2表示的氟烷基醇（甲基）丙烯酸衍生物的含氟聚合物（式中，R为氢原子或 甲基，n为1〜6的整数，优选为2〜4，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数），以5〜100 wt％作为聚合单元。 含氟聚合物的有机溶剂溶液或水分散体有效地用作例如防水防油剂或油屏障的表面改性剂。

公开(公告)号：US08377188B2

公开(公告)日：2013-02-19

申请号：US13395186

申请日：2010-09-08

申请人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

发明人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

IPC分类号： B29C33/60 ,  B29C33/56 ,  B28B7/38 ,  C07F9/40

CPC分类号： C07F9/3808 ,  B29C33/62 ,  C07F9/4006 ,  C08G65/007 ,  C08G65/3353 ,  C08G65/3355 ,  C08G65/337

摘要： Disclosed is a polyfluoroalkylphosphonic acid oxyalkylene ester of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)[O(RO)mR′]d(OH)2-d (RO is a C2-C6 linear or branched oxyalkylene group, R′ is a hydrogen atom or a C1-C20 alkyl group or aralkyl group, n is 1 to 6, a is 1 to 4, b is 1 to 3, c is 1 to 3, d is 1 or 2, and m is 1 to 100), which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms and referred to as having low bioaccumulation potential, and exhibiting, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms. This compound is produced by subjecting a polyfluoroalkylphosphonic acid of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 and a polyalkyleneglycol or a monoether thereof of the formula: HO(RO)mR′ to a condensation reaction.

摘要翻译： 公开了下式的多氟烷基膦酸氧化烯酯：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）[O（RO）mR'] d（OH）2-d（RO是C2- C6直链或支链氧化烯基，R'为氢原子或C1-C20烷基或芳烷基，n为1至6，a为1至4，b为1至3，c为1至3，d为 1或2，m为1〜100），其为具有6以下碳原子的全氟烷基且被认为具有低生物蓄积电位的化合物，并且当用作脱模剂的活性成分时 脱模性能与具有8个以上碳原子的全氟烷基的化合物相当。 该化合物是通过使式CnF 2 n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2的多氟烷基膦酸和式HO（RO）的聚亚烷基二醇或其单醚进行 mR'进行缩合反应。

公开(公告)号：US08361215B2

公开(公告)日：2013-01-29

申请号：US13508124

申请日：2010-10-07

申请人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

发明人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

IPC分类号： B01F17/14 ,  B29C33/60 ,  B29C33/56 ,  B28B7/38 ,  C07F9/38 ,  C09K3/00

CPC分类号： B01F17/0064 ,  B01F17/0035 ,  C07F9/3808

摘要： Disclosed is an emulsifier comprising, as an active ingredient, a polyfluoroalkylphosphonic acid salt represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OM1)(OM2), wherein M′ is a hydrogen atom, an alkali metal, an ammonium base, or an organic amine base, M2 is an alkali metal, an ammonium base, or an organic amine base, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3. An aqueous solution or organic solvent solution of the emulsifier can be effectively used to emulsify a perfluoropolyether oil or a perfluorocarbon compound. The resulting emulsion exhibits excellent emulsification stability, and thus can be effectively used as a mold-releasing agent.

摘要翻译： 公开了一种乳化剂，其包含由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OM1）（OM2）表示的多氟烷基膦酸盐作为活性成分，其中M' 氢原子，碱金属，铵碱或有机胺碱，M2为碱金属，铵碱或有机胺碱，n为1〜6的整数，a为1〜 4，b为1〜3的整数，c为1〜3的整数。乳化剂的水溶液或有机溶剂溶液可以有效地使全氟聚醚油或全氟化碳化合物乳化。 所得乳液表现出优异的乳化稳定性，因此可有效地用作脱模剂。

公开(公告)号：US20120214148A1

公开(公告)日：2012-08-23

申请号：US13508124

申请日：2010-10-07

申请人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

发明人： Yoshiyama Kaneumi ,  Seiichiro Murata ,  Katsuyuki Sato

IPC分类号： A01N1/02 ,  C09K3/00 ,  C09D7/12 ,  C09K3/18 ,  C08K5/56 ,  C08K5/5317

CPC分类号： B01F17/0064 ,  B01F17/0035 ,  C07F9/3808

摘要： Disclosed is an emulsifier comprising, as an active ingredient, a polyfluoroalkylphosphonic acid salt represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OM1)(OM2), wherein M′ is a hydrogen atom, an alkali metal, an ammonium base, or an organic amine base, M2 is an alkali metal, an ammonium base, or an organic amine base, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3. An aqueous solution or organic solvent solution of the emulsifier can be effectively used to emulsify a perfluoropolyether oil or a perfluorocarbon compound. The resulting emulsion exhibits excellent emulsification stability, and thus can be effectively used as a mold-releasing agent.

摘要翻译： 公开了一种乳化剂，其包含由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OM1）（OM2）表示的多氟烷基膦酸盐作为活性成分，其中M' 氢原子，碱金属，铵碱或有机胺碱，M2为碱金属，铵碱或有机胺碱，n为1〜6的整数，a为1〜 4，b为1〜3的整数，c为1〜3的整数。乳化剂的水溶液或有机溶剂溶液可以有效地使全氟聚醚油或全氟化碳化合物乳化。 所得乳液表现出优异的乳化稳定性，因此可有效地用作脱模剂。

公开(公告)号：US20120178075A1

公开(公告)日：2012-07-12

申请号：US13496581

申请日：2010-09-10

申请人： Yoshiyama Kaneumi ,  Katsuyuki Sato

发明人： Yoshiyama Kaneumi ,  Katsuyuki Sato

IPC分类号： A01N1/02 ,  C09D5/00 ,  B28B7/36

CPC分类号： B22C3/00 ,  A01N1/021 ,  B29C33/62 ,  B29K2105/0064 ,  C08G65/007 ,  C08G65/3353 ,  C08G2650/48 ,  C08K5/5337 ,  C08L71/00

摘要： Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: CnF2n+1CH2CH2P(O)(OM1)(OM2) [III] (M1: a hydrogen atom, ammonium salt, or organic amine salt, M2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C3F6O)p(C2F4O)q(CF2O)rRf′ [I] (Rf and Rf′: C1-C5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF2CF2CF2O)nCF2CF3 [II] (n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.

摘要翻译： 公开了使用0.01〜30重量份由通式CnF2n + 1CH2CH2P（O）（OM1）（OM2）[III]（M1）表示的全氟烷基乙基膦酸盐作为乳化剂形成的乳液， ，铵盐或有机胺盐，M2：铵盐或有机胺盐，n：1至6），基于100重量份由通式RfO（C 3 F 6 O）p（C 2 F 4 O）表示的全氟聚醚油） q（CF 2 O）r R f'[I]（Rf和Rf'：C 1 -C 5全氟烷基，p + q + r：2〜200）或通式：F（CF 2 CF 2 CF 2 O）n CF 2 CF 3 [II]（n： ）或全氟化碳化合物。 尽管使用具有低于6个或更少碳原子的全氟烷基的化合物作为乳化剂，据说具有低的生物累积潜力，但乳液表现出优异的乳化稳定性，因此可有效地用作表面处理剂 ，例如脱模剂。