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1.发明申请公开(公告)号：US20120090504A1
公开(公告)日：2012-04-19
申请号：US13376321
申请日：2010-06-03
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08F214/182
摘要： Disclosed is a graft copolymer in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3). The graft copolymer is an oligomer compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms.
摘要翻译： 公开了一种接枝共聚物，其中聚亚烷基二醇或其烷基醚与下列通式表示的多氟-1-烯烃接枝共聚：CnF2n +（CH2CF2）a（CF2CF2）bCH = CH2（其中n为 1〜6，a为1〜4的整数，b为1〜3的整数）。 接枝共聚物是具有碳原子数6以下的全氟烷基的低聚物化合物，据说具有低的生物蓄积电位，作为脱模剂的活性成分使用时，脱模性能与 具有含有8个以上碳原子的全氟烷基的化合物。
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2.发明申请FLUORINE-CONTAINING POLYMER AND SURFACE-MODIFYING AGENT CONTAINING THE SAME AS ACTIVE INGREDIENT 有权含有含氟聚合物和表面改性剂，其含有活性成分公开(公告)号：US20110009555A1
公开(公告)日：2011-01-13
申请号：US12677187
申请日：2008-07-16
申请人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
发明人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
IPC分类号： C08L27/12 , C08F114/18 , C08F214/18
CPC分类号： C09K3/18 , C08F220/18 , C08F220/24 , C08F220/26
摘要： A fluorine-containing polymer comprising a fluoroalkyl alcohol (meth)acrylic acid derivative represented by a general formula, CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2 (in the formula, R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, preferably 2 to 4, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3) containing in 5 to 100 wt % as a polymerization unit. A organic solvent solution or aqueous dispersion of the fluorine-containing polymer is effectively used as, for example, a surface-modifying agent such as a water- and oil-repellent or an oil barrier.
摘要翻译： 包含由通式CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cOCOCR=CH2表示的氟烷基醇（甲基）丙烯酸衍生物的含氟聚合物（式中，R为氢原子或 甲基，n为1〜6的整数，优选为2〜4，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数），以5〜100 wt％作为聚合单元。 含氟聚合物的有机溶剂溶液或水分散体有效地用作例如防水防油剂或油屏障的表面改性剂。
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3.发明申请Terminally Iodized Polyfluoroalkane Oligomer and Process for Producing the Same 审中-公开末端碘化多氟烷烃低聚物及其制备方法公开(公告)号：US20090018294A1
公开(公告)日：2009-01-15
申请号：US12224469
申请日：2007-02-28
申请人： Masayosi Horiuti , Seiichiro Murata , Katsuyuki Sato , Hideki Abe
发明人： Masayosi Horiuti , Seiichiro Murata , Katsuyuki Sato , Hideki Abe
CPC分类号： C07C19/16 , C07C17/278
摘要： A terminally iodized polyfluoroalkane oligomer represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)t+rI [I] (wherein n is an integer of 1 to 6, s+p is an integer of 1 to 4, showing the number of vinylidene fluoride skeleton, and t+r is an integer of 1 to 6, showing the number of tetrafluoroethylene skeleton, the adjacent group to the CnF2n+1 group being the CH2CF2 group) can be produced by reaction of a terminally iodized polyfluoroalkane, represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)tI with tetrafluoroethylene in the presence of a peroxide initiator.
摘要翻译： 由以下通式表示的末端碘化多氟烷烃低聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）t + I] <？in-line-formula description =“In-line Formulas”end =“tail”？>（其中n为1〜6的整数，s + p为1〜4的整数， 偏氟乙烯骨架，t + r为1〜6的整数，表示四氟乙烯骨架的数量，CnF2n + 1组为CH2CF2组的相邻基团）可以通过末端碘化的多氟烷烃 以下通式：<？in-line-formula description =“In-line Formulas”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）tI <？in-line-formula description =“ 在过氧化物引发剂存在下，使用四氟乙烯在线配方“end =”tail“？”。
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4.发明申请公开(公告)号：US20120180696A1
公开(公告)日：2012-07-19
申请号：US13395186
申请日：2010-09-08
CPC分类号： C07F9/3808 , B29C33/62 , C07F9/4006 , C08G65/007 , C08G65/3353 , C08G65/3355 , C08G65/337
摘要： Disclosed is a polyfluoroalkylphosphonic acid oxyalkylene ester of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)[O(RO)mR′]d(OH)2−d (RO is a C2-C6 linear or branched oxyalkylene group, R′ is a hydrogen atom or a C1-C20 alkyl group or aralkyl group, n is 1 to 6, a is 1 to 4, b is 1 to 3, c is 1 to 3, d is 1 or 2, and m is 1 to 100), which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms and referred to as having low bioaccumulation potential, and exhibiting, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms. This compound is produced by subjecting a polyfluoroalkylphosphonic acid of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 and a polyalkyleneglycol or a monoether thereof of the formula: HO(RO)mR′ to a condensation reaction.
摘要翻译： 公开了下式的多氟烷基膦酸氧化烯酯：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）[O（RO）mR'] d（OH）2-d（RO是C2- C6直链或支链氧化烯基，R'为氢原子或C1-C20烷基或芳烷基，n为1至6，a为1至4，b为1至3，c为1至3，d为 1或2，m为1〜100），其为具有6以下碳原子的全氟烷基且被认为具有低生物蓄积电位的化合物，并且当用作脱模剂的活性成分时 脱模性能与具有8个以上碳原子的全氟烷基的化合物相当。 该化合物是通过使式CnF 2 n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2的多氟烷基膦酸和式HO（RO）的聚亚烷基二醇或其单醚进行 mR'进行缩合反应。
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公开(公告)号：US08163857B2
公开(公告)日：2012-04-24
申请号：US12993571
申请日：2009-06-12
IPC分类号： C07C21/19 , C07C17/25 , C08F214/18 , C08F236/20
CPC分类号： C08F236/20 , C07C17/25 , C07C21/19 , C08F214/18 , C08F214/182
摘要： A mixture of polyfluoroalkadienes represented by the general formulae: CF3(CF2)nCF═CH(CF2)m+1CH═CH2 [Ia] and CF3(CF2)n+1CH═CF(CF2)mCH═CH2 [Ib], wherein n is an integer of 0 to 5, and m is an integer of 0 to 6, is obtained as a mixture fraction of products [Ia] and [Ib] by reacting a polyfluoroalkyl iodide represented by the general formula: CF3(CF2)n+1CH2(CF2)m+1(CH2CH2)I [II], with an organic basic compound. The polyfluoroalkadiene mixture is compounds having a perfluoroalkyl group in which the number of successive CF2 groups is 5 or less, and is effectively used as a copolymerizable monomer in the production of resinous or elastomeric fluorine-containing copolymers, which are used as active ingredients of surface-treating agents, such as water- and oil-repellents and mold-release agents.
摘要翻译： 由通式CF 3（CF 2）n CF = CH（CF 2）m + 1 CH = CH 2 [Ia]和CF 3（CF 2）n + 1 CH = CF（CF 2）m CH = CH 2 [Ib]表示的多氟代二烯的混合物，其中n 通过使由通式CF 3（CF 2）n +表示的多氟烷基碘反应得到作为产物[Ia]和[Ib]的混合分数的0〜5的整数，m为0〜6的整数， 1CH2（CF2）m + 1（CH2CH2）I [II]与有机碱性化合物反应。 多氟二烯混合物是具有连续CF 2基团数为5以下的全氟烷基的化合物，在生产含有树脂或弹性体的含氟共聚物中有效地用作可共聚单体，其用作表面活性成分 去油剂，如拒水拒油剂和脱模剂。
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6.发明申请公开(公告)号：US20110315050A1
公开(公告)日：2011-12-29
申请号：US13255332
申请日：2010-03-09
CPC分类号： B29C33/62 , C07F9/3808 , C07F9/4006
摘要： Disclosed is a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2, wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, or a salt thereof, which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and being usable as an active ingredient of a mold-releasing agent. The polyfluoroalkylphosphonic acid is produced by hydrolyzing a polyfluoroalkylphosphonic acid diester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP (O)(OR)2, wherein R is a C1-C4 alkyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3.
摘要翻译： 公开了由以下通式表示的多氟烷基膦酸：C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2，其中n为1至6的整数，a为整数1 至4，b为1〜3的整数，c为1〜3的整数，或其具有碳原子数6以下的全氟烷基的化合物的盐，其生物蓄积电位低 ，可用作脱模剂的活性成分。 多氟烷基膦酸通过水解由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OR）2表示的多氟烷基膦酸二酯制备，其中R是C 1 -C 4烷基， n为1〜6的整数，a为1〜4的整数，b为1〜3的整数，c为1〜3的整数。
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公开(公告)号：US20110077435A1
公开(公告)日：2011-03-31
申请号：US12993564
申请日：2009-06-12
IPC分类号： C07C21/18
摘要： A polyfluoro-1-alkene represented by the general formula: CF3(CF2)nCH2(CF2)mCH═CH2[I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyfluoroalkyl iodide represented by the general formula: CF3(CF2)nCH2(CF2)m(CH2CH2)I [II], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, with an inorganic basic compound in the presence of a phase transfer catalyst. Alternatively, the polyfluoro-1-alkene is produced by reacting the polyfluoroalkyl iodide [II] with a nitrogen-containing organic basic compound, and is obtained product [I] as one fraction thereof. By the copolymerization of the polyfluoro-1-alkene with other fluorinated olefin monomers, a fluorine-containing copolymer having excellent light transmittance in the visible light range is formed.
摘要翻译： 由通式CF 3（CF 2）n CH 2（CF 2）m CH = CH 2 [I]表示的多氟-1-烯烃，其中n为0〜5的整数，m为1〜7的整数，由 使由通式CF 3（CF 2）n CH 2（CF 2）m（CH 2 CH 2）I [II]表示的多氟烷基碘反应，其中n为0〜5的整数，m为1〜7的整数，与无机 在相转移催化剂存在下的碱性化合物。 或者，通过使多氟烷基碘化物[II]与含氮有机碱性化合物反应来制造多氟-1-烯烃，得到作为其一部分的产物[I]。 通过多氟-1-烯烃与其它氟化烯烃单体的共聚，形成在可见光范围内具有优异的透光率的含氟共聚物。
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公开(公告)号：US20100261869A1
公开(公告)日：2010-10-14
申请号：US12677579
申请日：2008-08-29
IPC分类号： C08G61/12
CPC分类号： C08F114/18 , C07C17/278 , C07C19/16 , C08F14/18 , C08F214/18 , C08F2/00
摘要： Provided is a terminally iodized polyfluoroalkane represented by the general formula: CnF2n+1(CHXCFY)s+p(CF2CF2)t+rI [I] (in the formula, X and Y are each a hydrogen atom or a fluorine atom, wherein when Y is a fluorine atom, X is also a fluorine atom; n is an integer of 1 to 6; s+p is an integer of 1 to 5 and denotes the number of CHXCFY group; and t+r is 0 or an integer of 1 to 6 and denotes the number of tetrafluoroethylene skeleton). The terminally iodized polyfluoroalkane is produced by telomerizing a fluorine-containing olefin CHX═CFY and tetrafluoroethylene, successively, to CnF2n+1I in the presence of a peroxide initiator.
摘要翻译： 提供由以下通式表示的末端碘化多氟烷烃：CnF2n + 1（CHXCFY）s + p（CF2CF2）t + rI [I]（在该式中，X和Y各自为氢原子或氟原子，其中当 Y为氟原子，X为氟原子，n为1〜6的整数，s + p为1〜5的整数，表示CHXCFY基的数，t + r为0或整数 1〜6，表示四氟乙烯骨架的数量）。 末端碘化的多氟烷烃是通过在含有过氧化物引发剂的存在下将含氟烯烃CHX = CFY和四氟乙烯连续地调节至C n F 2n + 1 I来制备的。
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公开(公告)号：US08313573B2
公开(公告)日：2012-11-20
申请号：US13395189
申请日：2010-09-08
IPC分类号： B29C33/60 , B28B7/38 , C08L71/02 , C10M105/74 , C10M145/26 , C10N30/00 , C10N40/36
CPC分类号： B29C33/62 , C08G65/3353 , C08G65/337 , C08K5/5317 , C08K5/5337 , C10M173/02 , C10M2207/021 , C10M2213/06 , C10M2215/04 , C10M2223/04 , C10M2225/00 , C10N2240/58
摘要： Disclosed is a mold-releasing agent comprising, as active ingredients, a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (n: an integer of 1 to 6, a: an integer of 1 to 4, b: an integer of 1 to 3, c: an integer of 1 to 3), or a salt thereof and a polyfluoroalkylphosphonic acid oxyalkylene ester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)[O(RO)mR′]d(OH)2−d (RO: a C2-C6 linear or branched oxyalkylene group, R′: a hydrogen atom, a C1-C20 alkyl group, or aralkyl group, n: an integer of 1 to 6, a: an integer of 1 to 4, b: an integer of 1 to 3, c: an integer of 1 to 3, d: an integer of 1 or 2, m: an integer of 1 to 100). This mold-releasing agent comprises, as an active ingredient, a polyfluoroalkylphosphonic acid oxyalkylene ester having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, but exhibits mold release performance equivalent to that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.
摘要翻译： 公开了一种脱模剂，其包含作为活性成分的由以下通式表示的多氟烷基膦酸：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）（OH）2（n： 1至6，a：1至4的整数，b：1至3的整数，c：1至3的整数）或其盐和由以下通式表示的多氟烷基膦酸氧化烯：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）[O（RO）mR'] d（OH）2-d（RO：C2-C6直链或支链氧化烯基，R' ，C 1〜C 20的烷基或芳烷基，n：1〜6的整数，a：1〜4的整数，b：1〜3的整数，c：1〜3的整数，d： 1或2的整数，m：1〜100的整数）。 该脱模剂含有具有6个以下碳原子的全氟烷基的多氟烷基膦酸氧化烯作为活性成分，其被认为具有低的生物累积潜力，但是具有与脱模剂相当的脱模性能 包含具有8个以上碳原子的全氟烷基的化合物作为活性成分的药剂。
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公开(公告)号：US08278361B2
公开(公告)日：2012-10-02
申请号：US12863464
申请日：2009-01-20
CPC分类号： C07C33/423 , C07C29/09
摘要： Disclosed is a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH [Ia] and CF3(CF2)n-1(CF═CH)aCF2(CF2CF2)b(CH2CH2)cOH [Ib], wherein n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3. This fluoroalkyl alcohol mixture is produced by the reaction of a fluoroalkyl iodide represented by the general formula: CF3(CF2)n(CH2CF2)a(CF2CF2)b(CH2CH2)cI [II], with N-methylformamide, followed by hydrolysis in the presence of a basic compound.
摘要翻译： 公开了由以下通式表示的氟烷基醇的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）cOH [Ia]和CF 3（CF 2）n-1（CF = CH）aCF 2 CF 2 CF 2）b（CH 2 CH 2）c OH [Ib]，其中n为1〜5的整数，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数。 氟烷基醇混合物通过由通式CF 3（CF 2）n（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）c I [II]表示的氟代烷基碘与N-甲基甲酰胺反应制备，然后在存在下水解 的基本化合物。
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