摘要:
The present invention relates to a compound of formula 1 and an organic electronic device comprising an organic semiconductor layer, wherein at least one organic semiconductor layer comprises a compound of formula (1), wherein L1 has the formula (2) and L2 has the formula (3), wherein L1 and L2 are bonded at “*” via a single bond independently to the same or different arylene groups or heteroarylenes group of Ar1; and wherein X1, X2 are independently selected from O, S and Se; Ar1 is selected from substituted or unsubstituted C20 to C52 arylene or C14 to C64 heteroarylene, wherein the substituent of the substituted C20 to C52 arylene or C14 to C64 heteroarylene are independently selected from C1 to C12 alkyl, C1 to C12 alkoxy, CN, halogen, OH, C6 to C25 aryl and C2 to C21 heteroaryl; R1, R2 are independently selected from substituted or unsubstituted C1 to C16 alkyl, wherein the substituent of substituted C1 to C16 alkyl is selected from C6 to C18 arylene or C2 to C12 heteroarylene; R3, R4 are independently selected from substituted or unsubstituted C1 to C16 alkyl, substituted or unsubstituted C6 to C18 arylene, C2 to C20 heteroarylene, wherein the substituent of substituted C1 to C16 alkyl, the substituent of the substituted C6 to C18 arylene, C2 to C20 heteroarylene are independently selected from C6 to C18 arylene or C2 to C12 heteroarylene; n is selected from 1 to 5, wherein n is an integer number.
摘要:
The present invention relates to a metallic layer adjacent to a semiconducting layer comprising a substantially covalent matrix material, the metallic layer comprising at least one first metal and at least one second metal, wherein a) the first metal is selected from the group consisting of Li, Na, K, Rb, Cs; and b) the second metal is selected from the group consisting of Zn, Hg, Cd, Te, electronic devices comprising such materials and process for preparing the same.
摘要:
The present invention relates to an organic electronic device, comprising a first electrode, a second electrode, and a substantially organic layer comprising a compound according to formula (I) between the first and the second electrode: wherein M is a metal ion, each of A1-A4 is independently selected from H, substituted or unsubstituted C6-C20 aryl and substituted or unsubstituted C2-C20 heteroaryl and n is valency of the metal ion.
摘要:
The present invention relates to an organic electronic device, comprising a first electrode, a second electrode, and a substantially organic layer comprising a compound according to formula (I) between the first and the second electrode: wherein M is a metal ion, each of A1-A4 is independently selected from H, substituted or unsubstituted C6-C20 aryl and substituted or unsubstituted C2-C20 heteroaryl and n is valency of the metal ion.
摘要:
The present invention relates to a an organic light-emitting diode (OLED) (100) comprising an emission layer and an electron transport layer stack of at least two electron transport layers (160/161), wherein a first electron transport layer (161) and a second electron transport layer (162) comprises at least one matrix compound and in addition, —the first electron transport layer (161) comprises a first lithium halide or a first lithium organic complex; and —the second electron transport layer (162) comprises a second lithium halide or a second lithium organic complex, wherein the first lithium organic complex is not the same as the second lithium organic complex; and wherein the first lithium halide is not the same as the second lithium halide.
摘要:
The invention relates to Organic light emitting diode comprising at least one emission layer, an electron injection layer and at least one cathode electrode, wherein: the electron injection layer comprises an organic phosphine compound, wherein the electron injection layer is free of a metal, metal salt, metal complex and metal organic compound; the cathode electrode comprises at least a first cathode electrode layer, wherein the first cathode electrode layer comprises a first zero-valent metal selected from the group comprising alkali metal, alkaline earth metal, rare earth metal and/or a group 3 transition metal; and the electron injection layer is arranged in direct contact to the first cathode electrode layer.
摘要:
The present invention relates to an electronic device comprising at least one light emitting layer between an anode and a cathode, the device further comprising between the cathode and the anode at least one mixed layer comprising (i) in substantially elemental form, an electropositive element selected from Li, Na, K, Be, Sc, Y, La, Lu, Ti and V, and (ii) at least one substantially covalent electron transport matrix compound comprising at least one polar group selected from a phosphine oxide group, wherein the reduction potential of the substantially covalent electron transport matrix compound, if measured by cyclic voltammetry under the same conditions, has the value which is more negative than the value obtained for 4,7-diphenyl-1, 10-phenanthroline, preferably more negative than for (9-phenyI-9II-carbazole-2,7-diyl)bis(diphenylphosphine oxide), more preferably more negative than for (9,9-dihexyI-9H-fluorene-2,7-diyl)bis(diphenylphosphine oxide), highly preferably more negative than for 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene, even more preferably more negative than for 3-phenyl-3H-benzo[b]dinaphto[2,1-d; 1 2′-fj]phosphepine-3-oxide, most preferably more negative than for pyrene and still preferably more negative than for [1,1′-binaphthalen]-2,2′-diylbis(diphenylphosphine oxide) or a diazole group, wherein the reduction potential of the substantially covalent electron transport matrix compound, if measured by cyclic voltammetry under the same conditions, has the value which is more negative than the value obtained for 4,7-diphenyl-1, 10-phenanthroline, preferably more negative than for (9-phenyl-9H-carbazole-2,7-diyl)bis(diphenylphosphine oxide), more preferably more negative than for (9,9-dihexyl-9H-fluorene-2,7-diyl)bis(diphenylphosphine oxide), highly preferably more negative than for 1,3,5-tris(1-phenyl-1 II-benzimidazol-2-yl)benzene, even more preferably more negative than for 3-phenyl-3H-benzo[b]dinaphto[2,1-d:1′,2′-fj]phosphepine-3-oxide, most preferably more negative than for pyrene and still preferably more negative than for [1,1′-binaphthalen]-2,2′-diylbis(diphenylphosphine oxide), a process for manufacturing the same and a compound comprised therein.
摘要:
The present invention relates to an electrically doped semiconducting material comprising at least one metallic element as n-dopant and at least one electron transport matrix compound comprising at least one phosphine oxide group, a process for its preparation, and an electronic device comprising the electrically doped semiconducting material.
摘要:
The disclosure refers to a semiconducting material comprising a phosphorous-containing compound and at least one lithium complexAlso provided are electronic devices comprising a cathode, an anode and the semiconducting material comprising a phosphorous-containing compound arranged between the cathode and the anode. Furthermore, a compound and an electronic device are disclosed.
摘要:
The present invention relates to an organic electronic device, comprising a first electrode, a second electrode, and a substantially organic layer comprising a compound according to formula (I) between the first and the second electrode: wherein A1 is a C6-C20 arylene and each of A2-A3 is independently selected from a C6-C20 aryl, wherein the aryl or arylene may be unsubstituted or substituted with groups comprising C and H or with a further LiO group, provided that the given C count in an aryl or arylene group includes also all substituents present on the said group.