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    PROCESS FOR PREPARING DIARYL CARBONATES AND POLYCARBONATES
    51.
    发明申请
    PROCESS FOR PREPARING DIARYL CARBONATES AND POLYCARBONATES 有权
    制备二元碳酸酯和聚碳酸酯的方法

    公开(公告)号：US20110278174A1

    公开(公告)日：2011-11-17

    申请号：US13074433

    申请日：2011-03-29

    申请人： Pieter Ooms ,  Andreas Bulan

    发明人： Pieter Ooms ,  Andreas Bulan

    IPC分类号： C25B15/00 ,  C25B1/00

    CPC分类号： C07C68/02 ,  C08G64/307 ,  C25B1/26 ,  Y02P20/127 ,  C07C69/96

    摘要： The present invention relates to a process for the continuous preparation of diaryl carbonates from phosgene and at least one monohydroxy compound (monophenol) in the presence of catalysts, and also the use thereof for preparing polycarbonates. The hydrogen chloride formed in the reaction is converted by electrochemical oxidation into chlorine, with the chlorine being recirculated to the preparation of phosgene. In particular, the process comprises utilization of the hydrogen chloride formed for the process for preparing diphenyl carbonate (DPC process).

    摘要翻译： 本发明涉及在催化剂存在下从光气和至少一种单羟基化合物（单酚）连续制备碳酸二芳酯的方法，以及其用于制备聚碳酸酯的方法。 在反应中形成的氯化氢通过电化学氧化转化成氯，氯被再循环到光气的制备中。 特别地，该方法包括利用形成的用于制备碳酸二苯酯的方法中的氯化氢（DPC工艺）。

    Processes for preparing diaryl and/or alkylaryl carbonates from dialkyl carbonates
    52.
    发明授权
    Processes for preparing diaryl and/or alkylaryl carbonates from dialkyl carbonates 有权
    由碳酸二烷基酯制备二芳基和/或烷基芳基碳酸酯的方法

    公开(公告)号：US08039659B2

    公开(公告)日：2011-10-18

    申请号：US12210279

    申请日：2008-09-15

    申请人： Andre Düx ,  Pieter Ooms ,  Johann Rechner ,  Matthias Böhm ,  Kaspar Hallenberger ,  Georg Ronge ,  Johan Vanden Eynde

    发明人： Andre Düx ,  Pieter Ooms ,  Johann Rechner ,  Matthias Böhm ,  Kaspar Hallenberger ,  Georg Ronge ,  Johan Vanden Eynde

    IPC分类号： C07C69/96

    CPC分类号： C07C68/06 ,  C07C69/96

    摘要： Processes comprising: reacting a dialkyl carbonate and an aromatic hydroxy compound in the presence of a transesterification catalyst in a first reaction column, the first reaction column comprising a top section, a bottom section, a rectifying section in an upper portion of the column and a reaction zone below the rectifying section; feeding a bottom product from the first reaction column to a further reaction column; the bottom product comprising a diaryl carbonate, an alkylaryl carbonate, or both, and residual unreacted dialkyl carbonate and aromatic hydroxy compound; the further reaction column comprising a top section, a rectifying section in an upper portion of the column and a reaction zone below the rectifying section; and reacting the residual unreacted dialkyl carbonate and aromatic hydroxy compound in the further reaction column; feeding a process stream to a distillation column, the process stream comprising a mixture of unreacted dialkyl carbonate and one or more reaction-product alcohols drawn from the first reaction column, the further reaction column, or both, such that the unreacted dialkyl carbonate is separated from the one or more reaction-product alcohols; and recycling the separated, unreacted dialkyl carbonate to the first reaction column; wherein the further reaction column comprises one or more condensers, and heat of condensation from the one or more condensers is fed back into the process.

    摘要翻译： 方法包括：在第一反应塔中的酯交换催化剂存在下使碳酸二烷基酯和芳族羟基化合物反应，所述第一反应塔包括塔的上部的顶部，底部，精馏段和 整流段下方的反应区; 将底部产物从第一反应塔进料至另一反应塔; 底部产物包含碳酸二芳基酯，碳酸二烷基酯或二者，和残留的未反应的碳酸二烷基酯和芳族羟基化合物; 所述另外的反应塔包括顶部，所述塔的上部的精馏部和所述精馏部下方的反应区; 并使残留的未反应的碳酸二烷基碳酸酯和芳族羟基化合物在另外的反应塔中反应; 将工艺流输送到蒸馏塔，所述工艺流包含未反应的碳酸二烷基酯和从第一反应塔，进一步的反应塔或两者中抽出的一种或多种反应产物醇的混合物，使得未反应的碳酸二烷基酯被分离 由一种或多种反应产物醇; 并将分离的未反应的碳酸二烷基酯再循环到第一反应塔中; 其中所述另外的反应塔包括一个或多个冷凝器，并且将来自所述一个或多个冷凝器的冷凝热反馈到所述方法中。

    PROCESSES FOR PURIFYING DIARYL CARBONATES
    55.
    发明申请
    PROCESSES FOR PURIFYING DIARYL CARBONATES 有权
    纯化二氧化碳的方法

    公开(公告)号：US20090137832A1

    公开(公告)日：2009-05-28

    申请号：US12274776

    申请日：2008-11-20

    申请人： Pieter Ooms ,  Johann Rechner ,  Matthias Bohm ,  Andre Dux ,  Kaspar Hallenberger ,  Georg Ronge ,  Johan Vanden Eynde

    发明人： Pieter Ooms ,  Johann Rechner ,  Matthias Bohm ,  Andre Dux ,  Kaspar Hallenberger ,  Georg Ronge ,  Johan Vanden Eynde

    IPC分类号： C07C68/06

    CPC分类号： C07C68/08 ,  B01D3/14 ,  B01D3/141 ,  Y02P20/57 ,  C07C69/96

    摘要： Processes comprising: transesterifying a dialkyl carbonate and an aromatic hydroxyl compound in the presence of a transesterification catalyst to provide a diaryl carbonate product comprising the transesterification catalyst as an impurity; subjecting the diaryl carbonate product to distillation in a first distillation column having an upper part and a lower part, wherein the upper part comprises a rectifying section and the lower part comprises a stripping section; and withdrawing a first sidestream from the first distillation column, wherein the first sidestream comprises a purified diaryl carbonate.

    摘要翻译： 方法包括：在酯交换催化剂存在下酯交换碳酸二烷基酯和芳族羟基化合物，得到包含酯交换催化剂作为杂质的碳酸二芳酯产物; 在具有上部和下部的第一蒸馏塔中对碳酸二芳基酯进行蒸馏，其中上部包括精馏段，下部包含汽提段; 以及从所述第一蒸馏塔排出第一侧流，其中所述第一侧流包含纯化的碳酸二芳基酯。

    Double metal cyanide catalysts for producing polyether polyols
    56.
    发明授权
    Double metal cyanide catalysts for producing polyether polyols 有权
    用于生产聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US07008900B1

    公开(公告)日：2006-03-07

    申请号：US09890889

    申请日：2000-01-31

    申请人： Jörg Hofmann ,  Pieter Ooms ,  Pramod Gupta ,  Walter Schäfer ,  John Lohrenz

    发明人： Jörg Hofmann ,  Pieter Ooms ,  Pramod Gupta ,  Walter Schäfer ,  John Lohrenz

    IPC分类号： B01J27/26

    CPC分类号： B01J27/26 ,  C07F15/065 ,  C08G65/2663

    摘要： The invention provides new double metal cyanide (DMC) catalysts for preparing polyetherpolyols by the polyaddition of alkylene oxides to starter compounds which contain active hydrogen atoms, wherein the catalyst comprises a) double metal cyanide compounds, b) bile acids or their salts, esters or amides and c) organic complex ligands. The catalysts according to the invention show greatly increased activity during preparation of a polyetherpolyol.

    摘要翻译： 本发明提供了新的双金属氰化物（DMC）催化剂，用于通过将环氧烷烃加成到含有活性氢原子的起始化合物中制备聚醚多元醇，其中催化剂包含a）双金属氰化物化合物，b）胆汁酸或其盐，酯或 酰胺和c）有机络合物配体。 根据本发明的催化剂在制备聚醚多元醇期间显示出极大增加的活性。

    Double-metal cyanide catalysts for producing polyether polyols
    59.
    发明授权
    Double-metal cyanide catalysts for producing polyether polyols 失效
    用于生产聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US06608231B1

    公开(公告)日：2003-08-19

    申请号：US09787130

    申请日：2001-03-13

    申请人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    发明人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    IPC分类号： C07C4311

    CPC分类号： C08G65/2663 ,  B01J27/26 ,  B01J31/2213 ,  B01J2231/14 ,  B01J2531/26 ,  B01J2531/845 ,  C08G65/2642

    摘要： The invention relates to novel double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides to starter compounds containing active hydrogen atoms, wherein the catalyst contains a) double metal cyanide compounds, b) organic complex ligands other than c), and c) carboxylic acid ester of polyhydric alcohols. The catalysts according to the invention have greatly increased activity in the preparation of polyether polyols.

    摘要翻译： 本发明涉及用于制备聚醚多元醇的新型双金属氰化物（DMC）催化剂，其通过将环氧烷加成到含有活性氢原子的起始化合物中，其中催化剂含有a）双金属氰化物化合物，b）除c以外的有机络合物配体 ）和c）多元醇的羧酸酯。 根据本发明的催化剂在制备聚醚多元醇中的活性大大增加。

    Double metal cyanide catalysts for the preparation of polyether polyols
    60.
    发明授权
    Double metal cyanide catalysts for the preparation of polyether polyols 有权
    用于制备聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US06468939B1

    公开(公告)日：2002-10-22

    申请号：US09525882

    申请日：2000-03-15

    申请人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    发明人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    IPC分类号： B01J2726

    CPC分类号： C08G65/2663 ,  B01J31/0212 ,  B01J31/0235 ,  B01J31/0259 ,  B01J31/0261 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/24 ,  B01J2231/34 ,  B01J2531/26 ,  B01J2531/845

    摘要： This invention relates to new double metal cyanide (DMC) catalysts, a process for the preparation of these DMC catalysts, and to a process for the production of polyether polyols by the polyaddition of alkylene oxides to starter compounds which comprise active hydrogen atoms, wherein the catalyst comprises a) one or more double metal cyanide compounds, b) one or more organic complexing ligands, and c) one or more organic phosphates, organic phosphites, organic phosphonates, organic phosphonites, organic phosphinates or organic phosphinites. The catalysts according to the invention exhibit a considerably increased activity for polyether polyol production.

    摘要翻译： 本发明涉及新的双金属氰化物（DMC）催化剂，制备这些DMC催化剂的方法，以及通过将环氧烷烃加成到起始化合物（其包含活性氢原子）中加成聚醚多元醇的方法，其中 催化剂包括a）一种或多种双金属氰化物，b）一种或多种有机络合配体，和c）一种或多种有机磷酸盐，有机亚磷酸盐，有机膦酸盐，有机亚膦酸盐，有机次膦酸盐或有机亚磷酸盐。 根据本发明的催化剂对于聚醚多元醇的生产显示出显着提高的活性。