N-(2-nitrophenyl)-5-aminopyrimidine derivatives and useful for
controlling harmful micro-organisms
    51.
    发明授权
    N-(2-nitrophenyl)-5-aminopyrimidine derivatives and useful for controlling harmful micro-organisms 失效
    N-(2-硝基苯基)-5-氨基嘧啶衍生物,可用于控制有害微生物

    公开(公告)号:US4840662A

    公开(公告)日:1989-06-20

    申请号:US631272

    申请日:1984-07-16

    摘要: The invention discloses novel N-(2-nitrophenyl)-5-aminopyrimidine derivatives of the general formula ##STR1## wherein R.sub.1 and R.sub.2 are each independently NO.sub.2 or CF.sub.3, or one of R.sub.1 and R.sub.2 is hydrogen,R.sub.3 is hydrogen or halogen,R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio,R.sub.5, R.sub.6 and R.sub.7 are each independently hydrogen, halogen, nitro, cyano, thiocyano, mercapto, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkoxy which is substituted by halogen, nitro, cyano, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio and/or N(C.sub.1 -C.sub.4 alkyl).sub.2 ; or are C.sub.3 -C.sub.6 cycloalkoxy, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.1 -C.sub.6 alkylthio, C.sub.3 -C.sub.6 alkenylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl or the N(C.sub.1 -C.sub.4 alkyl).sub.2 group, and R.sub.5 may additionally be a phenyl or benzyl group which is unsubstituted or substituted by one to three identical or different members selected from halogen, nitro, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl, N--(C.sub.1 -C.sub.3 alkyl).sub. 2, and/or C.sub.1 -C.sub.3 alkoxy.The preparation of these compounds and their use in agriculture are also disclosed.

    摘要翻译: 本发明公开了通式(I)的新型N-(2-硝基苯基)-5-氨基嘧啶衍生物,其中R 1和R 2各自独立地为NO 2或CF 3,或者R 1和R 2中的一个为氢,R 3为氢或 卤素,R 4是氢或-C(O)R'基团,其中R'是未被取代或被卤素取代的C 1 -C 4烷基,C 1 -C 3烷氧基或C 1 -C 3烷硫基,R 5,R 6和R 7各自独立地为氢, 卤素,硝基,氰基,硫氰基,巯基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷氧基,被卤素,硝基,氰基,C1-C3烷氧基,C1-C3烷硫基和/或N(C1-C4烷基) )2; 或者是C 3 -C 6环烷氧基,C 3 -C 6烯氧基,C 3 -C 6炔氧基,C 1 -C 6烷硫基,C 3 -C 6烯基硫基,C 1 -C 6烷基磺酰基,C 1 -C 6烷基亚磺酰基,C 3 -C 6烯基,C 3 -C 6卤代烯基,C 3 -C 6炔基,C 3 -C 6卤代炔基或N -C 1-4烷基)2基团,并且R 5可另外为未取代的或被一至三个相同或不同的选自卤素,硝基,氰基,C 1 -C 4烷基,C 1 -C 3卤代烷基,N-(C 1 -C 4烷基) C3烷基)2和/或C1-C3烷氧基。 还公开了这些化合物的制备及其在农业中的应用。

    Use of quinoline derivatives for the protection of cultivated plants
    53.
    发明授权
    Use of quinoline derivatives for the protection of cultivated plants 失效
    使用喹啉衍生物保护栽培植物

    公开(公告)号:US4758264A

    公开(公告)日:1988-07-19

    申请号:US895569

    申请日:1986-08-11

    申请人: Adolf Hubele

    发明人: Adolf Hubele

    摘要: A process for the protection of cultivated plants against harmful effects of aggressive cultural chemicals by the use of compounds of the formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 indpendently of one another are each hydrogen, halogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, nitro or cyano,R.sub.4, R.sub.5 and R.sub.6 independently of one another are each hydrogen, halogen or C.sub.1 -C.sub.3 -alkyl,A is any one of the groups --CH.sub.2 --, --CH.sub.2 --CH.sub.2 -- or --CH(CH.sub.3)--, andZ is cyano, or amidoxime which can be acylated on the oxygen atom,including acid addition salts and metal complexes thereof.

    摘要翻译: 通过使用其中R 1,R 2和R 3彼此独立的式I(I)的化合物各自为氢,卤素,C 1 -C 3 - 烷基的化合物,保护栽培植物免受侵蚀性文化化学物质的有害影响的方法, 烷基,C 1 -C 3 - 烷氧基,硝基或氰基,R 4,R 5和R 6彼此独立地各自为氢,卤素或C 1 -C 3 - 烷基,A为-CH 2 - , - CH 2 -CH 2 - 或 - -CH(CH 3)+13,Z为氰基或可在氧原子上酰化的偕胺肟,包括其酸加成盐和金属络合物。

    Pesticidal compositions
    54.
    发明授权
    Pesticidal compositions 失效
    杀虫剂组合物

    公开(公告)号:US4694009A

    公开(公告)日:1987-09-15

    申请号:US746432

    申请日:1985-06-19

    摘要: The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2 ;R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio;R.sub.5, R.sub.6 and R.sub.7 are each independently halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, or are unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms, or are the Q--(E).sub.n --(X).sub.m group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur, and R.sub.6 and/or one of the radicals R.sub.5 or R.sub.7 can also be hydrogen.Also disclosed are methods of preparing these compounds, and agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or compositions containing them, in agriculture and related fields.

    摘要翻译: 本发明公开了通式I(I)的新型N-(2-硝基苯基)-2-氨基嘧啶衍生物,其中R 1和R 2是氢,NO 2或CF 3,条件是只有R 1或R 2可以是NO 2; R 4是氢或-C(O)R'基团,其中R'是未被取代或被卤素,C 1 -C 3烷氧基或C 1 -C 3烷硫基取代的C 1 -C 4烷基; R5,R6和R7各自独立地为卤素,硝基,氰基,氰基,C1-C12烷基,C3-C8环烷基,C1-C8烷硫基,C1-C6烷基磺酰基,C1-C6烷基亚磺酰基,C3-C6链烯基,C3-C6卤代烯基,C3-C6炔基, C 6卤代炔基,C 3 -C 6烯氧基,C 3 -C 6卤代烯氧基,C 3 -C 6烯基硫基,C 3 -C 6炔氧基,C 3 -C 6卤代炔氧基,被卤素,氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基,或未取代的C 1 -C 8烷氧基或卤素取代的C 1 C 1-8烷氧基,其烷基部分可被一个或多个单个氧原子间隔,或是Q-(E)n-(X)m基团,其中n为0或1,m为0或1,Q 是未取代的或被卤素,硝基,C 1 -C 3烷基,CF 3和/或C 1 -C 3烷氧基取代的苯基,或是含有一个或多个杂原子的饱和或不饱和杂环基,E是C 1 -C 3亚烷基桥,X是 氧或硫,R6和/或基团R5或R7之一也可以是氢。 还公开了制备这些化合物的方法和含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中使用含有它们的新化合物或组合物。

    8-hydroxy-quinoline derivatives for the protection of cultivated plants
    55.
    发明授权
    8-hydroxy-quinoline derivatives for the protection of cultivated plants 失效
    8-羟基喹啉衍生物,用于保护栽培植物

    公开(公告)号:US4623727A

    公开(公告)日:1986-11-18

    申请号:US465740

    申请日:1983-02-11

    申请人: Adolf Hubele

    发明人: Adolf Hubele

    摘要: A process for the protection of cultivated plants against harmful effects of aggressive agricultural chemicals by the use of compounds of the formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, nitro or cyano,R.sub.4, R.sub.5 and R.sub.6 independently of one another are each hydrogen, halogen or C.sub.1 -C.sub.3 -alkyl,A is any one of the groups --CH.sub.2 --, --CH.sub.2 --CH.sub.2 -- or --CH(CH.sub.3)--, andZ is cyano, or amidoxime which can be acylated on the oxygen atom, including acid addition salts and metal complexes thereof.

    摘要翻译: 通过使用式I(I)的化合物来保护栽培植物免受侵蚀性农药的有害影响的方法,其中R 1,R 2和R 3彼此独立地为氢,卤素,C 1 -C 3 - 烷基,C 1 -C 3 - 烷氧基,硝基或氰基,R 4,R 5和R 6彼此独立地各自为氢,卤素或C 1 -C 3 - 烷基,A为-CH 2 - , - CH 2 -CH 2 - 或 - -CH(CH 3) - ,Z为氰基或可在氧原子上酰化的偕胺肟,包括其酸加成盐和金属络合物。

    Imidazolidine-2,4-dione derivatives and their use as pesticides
    57.
    发明授权
    Imidazolidine-2,4-dione derivatives and their use as pesticides 失效
    咪唑烷-2,4-二酮衍生物及其作为农药的用途

    公开(公告)号:US4000303A

    公开(公告)日:1976-12-28

    申请号:US666731

    申请日:1976-03-15

    申请人: Adolf Hubele

    发明人: Adolf Hubele

    IPC分类号: C07D233/80 A01N9/22

    CPC分类号: C07D233/80

    摘要: Imidazolidine-2,4-dione derivatives of formula I ##STR1## wherein R.sub.1 and R.sub.2 each independently represent hydrogen, halogen, C.sub.1 -C.sub.3 -alkyl, nitro, C.sub.1 -C.sub.3 -haloalkyl or C.sub.1 -C.sub.3 -alkoxy,R.sub.3 represents hydrogen, halogen or methyl, andR.sub.4 and R.sub.5 each independently represent hydrogen or C.sub.1 -C.sub.3 -alkyl, whereby if one of the symbols R.sub.1, R.sub.2 or R.sub.3 is hydrogen the two others cannot simultaneously be halogen atoms in the meta-position with respect to the amino group which are useful as pesticides.

    摘要翻译: 式I的咪唑烷-2,4-二酮衍生物其中R 1和R 2各自独立地表示氢,卤素,C 1 -C 3 - 烷基,硝基,C 1 -C 3 - 卤代烷基或C 1 -C 3 - 烷氧基,R 3表示 氢,卤素或甲基,R 4和R 5各自独立地表示氢或C 1 -C 3 - 烷基,其中如果符号R 1,R 2或R 3中的一个为氢,则其中两个不能同时为相对于 用作农药的氨基。

    Imidazolidine-2,4-dione derivatives and their use as pesticides
    58.
    发明授权
    Imidazolidine-2,4-dione derivatives and their use as pesticides 失效
    咪唑烷-2,4-二酮衍生物及其作为农药的用途

    公开(公告)号:US3960883A

    公开(公告)日:1976-06-01

    申请号:US500983

    申请日:1974-08-27

    申请人: Adolf Hubele

    发明人: Adolf Hubele

    CPC分类号: C07D233/80

    摘要: Imidazolidine-2,4-dione derivatives of formula I ##EQU1## wherein R.sub.1 and R.sub.2 each independently represent hydrogen, halogen, C.sub.1 -C.sub.3 -alkyl, nitro, C.sub.1 -C.sub.3 -haloalkyl or C.sub.1 -C.sub.3 -alkoxy,R.sub.3 represents hydrogen, halogen or methyl, andR.sub.4 and R.sub.5 each independently represent hydrogen or C.sub.1 -C.sub.3 -alkyl, whereby if one of the symbols R.sub.1, R.sub.2 or R.sub.3 is hydrogen the two others cannot simultaneously be halogen atoms in the meta-position with respect to the amino group which are usful as pesticides.

    摘要翻译: 式I OR4的咪唑烷-2,4-二酮衍生物PARALLEL | CC-R5 | N ANGLE |(I)| CN-SCCl2F PARALLEL 0其中R1和R2各自独立地表示氢,卤素,C1-C3-烷基,硝基,C1 -C 3 - 卤代烷基或C 1 -C 3 - 烷氧基,R 3表示氢,卤素或甲基,R 4和R 5各自独立地表示氢或C 1 -C 3 - 烷基,其中如果R1,R2或R3之一是氢, 不能同时成为相对于作为农药有用的氨基的间位的卤素原子。

    Microbicides
    59.
    发明授权
    Microbicides 失效
    杀菌剂

    公开(公告)号:US5663176A

    公开(公告)日:1997-09-02

    申请号:US642232

    申请日:1996-05-02

    CPC分类号: A01N43/653

    摘要: Mixtures of certain triazole fungicides (component I) and 4,6-dimethyl-N-phenyl-2-pyrimidinamine (component II) achieve synergistically enhanced activity against fungus infestation. Components I and II can also be applied to plant crops individually, one immediately after the other.

    摘要翻译: 某些三唑类杀真菌剂(组分I)和4,6-二甲基-N-苯基-2-嘧啶胺(组分II)的混合物达到协同增强的针对真菌侵袭的活性。 组分I和II也可以单独应用于种植作物,一个接一个地应用于植物作物。