公开(公告)号：US06949326B2

公开(公告)日：2005-09-27

申请号：US10217486

申请日：2002-08-14

Applicant: Tomoyoshi Mitsumoto ,  Noriaki Watanabe ,  Kazuo Maemoto

Inventor： Tomoyoshi Mitsumoto ,  Noriaki Watanabe ,  Kazuo Maemoto

IPC: G03F7/033 ,  B41C1/10 ,  B41N1/14 ,  G03F7/00 ,  G03F7/11 ,  B41C1/055 ,  G03F7/004 ,  G03F7/038

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/145 ,  Y10S430/146

Abstract: A lithographic printing plate for infrared laser is provided which shows an excellent coated surface state and an excellent stability with time against scratch, and which has a heat-sensitive layer containing the following (A) to (D): (A) a substance which absorbs a light to generate heat; (B) an alkaline aqueous solution-soluble resin having phenolic hydroxyl groups; (C) a polymer containing as a polymerizable component (meth)acrylate monomer having within the molecule 2 or 3 perfluoroalkyl groups containing 3 to 20 carbon atoms; and (D) a fluorine-containing polymer containing at lease a specific monomer as a copolymerizable component.

Abstract translation: 提供了一种用于红外激光的平版印刷版，其具有优异的涂覆表面状态和优异的耐刮擦时间的稳定性，并且具有包含以下（A）至（D）的热敏层：（A） 吸收光线产生热量; （B）具有酚羟基的碱性水溶液可溶性树脂; （C）含有在分子内含有3〜20个碳原子的全氟烷基的分子内的聚合性成分（甲基）丙烯酸酯单体的聚合物; 和（D）含有至少一种特定单体作为可共聚组分的含氟聚合物。

公开(公告)号：US20050142484A1

公开(公告)日：2005-06-30

申请号：US11018259

申请日：2004-12-22

Applicant: Kotaro Watanabe ,  Kazuto Kunita ,  Kunihiko Kodama

Inventor： Kotaro Watanabe ,  Kazuto Kunita ,  Kunihiko Kodama

IPC: G03F7/004 ,  B41C1/10 ,  B41M5/36 ,  G03F7/00 ,  G03F7/11 ,  G03C1/76

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  G03F7/0045 ,  Y10S430/106 ,  Y10S430/11 ,  Y10S430/111 ,  Y10S430/165

Abstract: A positive image recording material applicable to infrared laser comprising a support whereon is formed a photosensitive/heatsensitive layer containing (A) an alkali-soluble resin, (B) a photothermal conversion substance, and (C) at least one compound selected from a group of compounds defined by the formulae (I), (II), (III), and (IV) exhibiting improved solubility to an alkaline developer following exposure with an infrared laser wherein the substituent groups of the formulae (I) to (IV) are specified in the specification for this invention.

Abstract translation: 适用于红外线激光器的正性图像记录材料包括其上形成有包含（A）碱溶性树脂，（B）光热转换物质）和（C）至少一种选自下组的化合物的光敏/感热层： 由式（I），（II），（III）和（IV）定义的化合物在用红外激光曝光后显示出对碱性显影剂的溶解度的改善，其中式（I）至（IV）的取代基是 在本发明的说明书中指定。

公开(公告)号：US20050112496A1

公开(公告)日：2005-05-26

申请号：US10973918

申请日：2004-10-27

Applicant: Hiroyuki Nagase

Inventor： Hiroyuki Nagase

IPC: B41C1/10 ,  G03F7/30 ,  G03F7/32 ,  G03C1/76

CPC classification number: G03F7/322 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/3028

Abstract: The present invention relates to a method for forming images which comprises imagewise exposing a photopolymerizable image-forming material comprising a substrate provided thereon with an image-recording layer which comprises a specific photopolymerization initiator system, a polymerizable compound carrying at least one ethylenically unsaturated group and a binder polymer and then developing the imagewise exposed material with a developer containing at least one carbonate and at least one hydrogen carbonate and a specific surfactant in an amount ranging from 1.0 to 10% by weight, and having a specific pH and a specific electrical conductivity. The image-forming method permits the achievement of a sufficient developing ability even at a relatively low pH at which the image-forming material is not damaged so much and the preparation of a printing plate having good printing durability.

Abstract translation: 本发明涉及一种用于形成图像的方法，该方法包括将包含其上设置有基材的基材的可光聚合成像材料成像曝光，所述图像记录层包含特定光聚合引发剂体系，携带至少一个烯键式不饱和基团的可聚合化合物和 粘合剂聚合物，然后用含有至少一种碳酸酯和至少一种碳酸氢盐和特定表面活性剂的显影剂显影成像曝光的材料，其量为1.0至10重量％，并且具有特定的pH和比电导率 。 图像形成方法即使在图像形成材料没有被损坏太多的相对低的pH下也能够获得足够的显影能力，并且制备具有良好印刷耐久性的印刷版。

公开(公告)号：US06893795B2

公开(公告)日：2005-05-17

申请号：US10190545

申请日：2002-07-09

Applicant: Ikuo Kawauchi ,  Akio Oda ,  Hideo Miyake

Inventor： Ikuo Kawauchi ,  Akio Oda ,  Hideo Miyake

IPC: B41C1/10 ,  G03F7/038 ,  G03F7/11 ,  G03F7/30 ,  G03F7/32

CPC classification number: B41C1/1016 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/107 ,  Y10S430/109 ,  Y10S430/113 ,  Y10S430/115 ,  Y10S430/145 ,  Y10S430/146

Abstract: A positive working lithographic printing plate precursor comprising a lower layer containing a water-insoluble and alkali-soluble resin, and an upper heat-sensitive layer containing a water-insoluble and alkali-soluble resin and an infrared absorbing dye and increasing the solubility in an alkaline aqueous solution by heating, provided in this order on a hydrophilic support, and (a) the upper heat-sensitive layer containing at least two kinds of surface active agents, or (b) the lower layer and upper heat-sensitive layer each containing a surface active agent different from each other.

Abstract translation: 包含含有水不溶性和碱溶性树脂的下层和含有水不溶性和碱溶性树脂和红外线吸收染料的上部热敏层的正性工作平版印刷版原版，并增加其在 碱性水溶液按照此顺序提供在亲水性载体上，和（a）含有至少两种表面活性剂的上部热敏层，或（b）下层和上部热敏层，每层包含 表面活性剂彼此不同。

公开(公告)号：US20050064330A1

公开(公告)日：2005-03-24

申请号：US10945926

申请日：2004-09-22

Applicant: Keisuke Arimura ,  Takahiro Goto

Inventor： Keisuke Arimura ,  Takahiro Goto

IPC: G03F7/09 ,  B41C1/10 ,  B41N3/03 ,  G03F7/00 ,  G03F7/004 ,  G03F7/033 ,  G03F7/11 ,  G03C1/76

CPC classification number: B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24

Abstract: A lithographic printing plate precursor comprising, in this order, a support, an undercoat layer and a photosensitive layer containing an infrared absorber, a polymerization initiator, a polymerizable compound and a binder polymer, wherein the undercoat layer contains a polymer compound having an acid group, and Ra, ΔS and a45 of a surface of the support are satisfied with the following conditions (i) to (iii), respectively: (i) Ra: 0.2 to 0.40 μm, (ii) AS: 35 to 85%, (iii) a45: 25 to 55%, in which Ra, ΔS (%) and a45 are defined herein.

Abstract translation: 平版印刷版原版，依次包含载体，底涂层和含有红外线吸收剂，聚合引发剂，聚合性化合物和粘合剂聚合物的感光层，其中底涂层含有具有酸基的高分子化合物 ，和载体表面的Ra，DeltaS和a45分别满足以下条件（i）至（iii）：（i）Ra：0.2〜0.40μm，（ii）AS：35〜85％，（ iii）a45：25-55％，其中本文定义了Ra，DeltaS（％）和a45。

公开(公告)号：US20050058936A1

公开(公告)日：2005-03-17

申请号：US10934731

申请日：2004-09-07

Applicant: Ikuo Kawauchi ,  Masako Imai ,  Miki Takahashi

Inventor： Ikuo Kawauchi ,  Masako Imai ,  Miki Takahashi

IPC: B41C1/10 ,  B41M5/36 ,  B41M5/46 ,  G03F7/00 ,  G03F7/004 ,  G03F7/11 ,  G03F7/40 ,  G03C1/76

CPC classification number: B41C1/1016 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  G03F7/11

Abstract: The present invention provides an image recording material comprising a substrate, an intermediate layer, and a photosensitive layer containing a novolac phenol resin and a light to heat conversion agent and being recordable with an infrared laser. The intermediate layer and photosensitive layer are sequentially provided on the substrate. The intermediate layer contains a polymer having an acidic group and being capable of interacting with the novolac phenol resin contained in the photosensitive layer. A planographic printing plate excellent in chemical resistance and printing durability is obtained by heat-treating the image recording material at 150 to 300° C. after effecting image-wise exposure with an infrared laser and development.

Abstract translation: 本发明提供一种图像记录材料，其包括基材，中间层和含有酚醛清漆酚树脂和光热转换剂的感光层，并且可以用红外激光进行记录。 中间层和感光层依次设置在基板上。 中间层含有具有酸性基团并且能够与感光层中所含的酚醛清漆酚树脂相互作用的聚合物。 通过在用红外线激光进行图像曝光和显影之后，在150〜300℃下对图像记录材料进行热处理，获得耐化学性和印刷耐久性优异的平版印刷版。

公开(公告)号：US20050043173A1

公开(公告)日：2005-02-24

申请号：US10921860

申请日：2004-08-20

Applicant: Tomotaka Tsuchimura

Inventor： Tomotaka Tsuchimura

IPC: G03F7/004 ,  B41C1/10 ,  B41M5/20 ,  G03F7/00

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262

Abstract: The heat mode image recording material of the present invention comprises an infrared absorbent (A), and a polymer (B) comprising a polyfunctional monomer component. The material can be exposed to an infrared laser, whereby an image can be formed thereon. The heat mode image recording material of the invention has superior film-formability and superior film strength, and is useful for a the recording layer of a planographic printing plate precursor having wide development latitude and excellent scratch resistance.

Abstract translation: 本发明的热模式图像记录材料包括红外线吸收剂（A）和包含多官能单体组分的聚合物（B）。 该材料可以暴露于红外激光器，从而可以在其上形成图像。 本发明的热模式图像记录材料具有优异的成膜性和优异的膜强度，并且可用于具有宽显影宽度和优异的耐刮擦性的平版印刷版原版的记录层。

公开(公告)号：US20050028697A1

公开(公告)日：2005-02-10

申请号：US10902161

申请日：2004-07-30

Applicant: Naonori Makino ,  Ryuki Kakino ,  Sumiaki Yamasaki ,  Yasuhito Oshima

Inventor： Naonori Makino ,  Ryuki Kakino ,  Sumiaki Yamasaki ,  Yasuhito Oshima

IPC: G03F7/004 ,  B41C1/055 ,  B41C1/10 ,  B41N1/14 ,  G03F7/00 ,  B41F1/18

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262

Abstract: A lithographic printing process which comprises the steps of: imagewise exposing to infrared light a presensitized lithographic plate which comprises a hydrophilic support and a removable image-forming layer containing an infrared absorbing agent having the absorption maximum within an infrared region and a visible dye having the absorption maximum within a visible region to shift the absorption maximum of the visible dye within the exposed area with a change of at least 50 nm in the wavelength and a change of at least 15 in color in terms of ΔE, and to make the image-forming layer irremovable within the exposed area; removing the image-forming layer within the unexposed area of the lithographic plate mounted on a cylinder of a printing press; and then printing an image with the lithographic plate mounted on the cylinder of the printing press. The other processes are also disclosed.

Abstract translation: 一种平版印刷方法，其包括以下步骤：将具有亲水性载体和含有在红外区域内具有最大吸收的红外线吸收剂的可除去图像形成层的预定平版印刷版成像曝光于红外光， 在可见区域内的吸收最大值，以使透射区域中的可见染料的吸收最大值在波长上具有至少50nm的变化，并且以DeltaE为单位改变至少15个颜色， 在暴露区域内不可移动的成膜层; 去除安装在印刷机的滚筒上的平版印刷板的未曝光区域内的图像形成层; 然后用安装在印刷机滚筒上的平版印刷机印刷图像。 还公开了其他方法。

公开(公告)号：US20050016402A1

公开(公告)日：2005-01-27

申请号：US10858374

申请日：2004-06-02

Applicant: Yasuhito Oshima ,  Toshifumi Inno ,  Tomoyoshi Mitsumoto ,  Kazuhiro Fujimaki ,  Kazuto Shimada ,  Naonori Makino

Inventor： Yasuhito Oshima ,  Toshifumi Inno ,  Tomoyoshi Mitsumoto ,  Kazuhiro Fujimaki ,  Kazuto Shimada ,  Naonori Makino

IPC: B41C1/10 ,  B41N3/00

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24

Abstract: A lithographic printing process comprises the steps of: imagewise exposing to infrared light a presensitized lithographic plate which comprises a hydrophilic support and an image-forming layer containing an infrared absorbing agent, a polymerization initiator and a binder polymer to polymerize the polymerizable compound within the exposed area; removing the image-forming layer within the unexposed area while mounting the lithographic plate on a cylinder of a printing press; and then printing with the lithographic plate while mounting the lithographic plate on the cylinder of the printing press. The polymerization initiator is a salt of an anion with a sulfonium ion. According to the present invention, a specific anion or a specific sulfonium ion is used in the polymerization initiator.

Abstract translation: 平版印刷方法包括以下步骤：将包含亲水性支持物和包含红外线吸收剂的图像形成层，聚合引发剂和粘合剂聚合物的预定平版印刷板成像曝光于红外光，以使曝光的聚合化合物聚合 区; 在将平版印刷版安装在印刷机的滚筒上的同时，将未曝光区域内的图像形成层移除; 然后在将平版印刷版安装在印刷机的滚筒上的同时用平版印刷机进行印刷。 聚合引发剂是具有锍离子的阴离子的盐。 根据本发明，在聚合引发剂中使用特定的阴离子或特定的锍离子。

公开(公告)号：US20040229163A1

公开(公告)日：2004-11-18

申请号：US10844454

申请日：2004-05-13

Inventor： Koji Sonokawa ,  Tatsuya Nomura

IPC: G03C001/76

CPC classification number: B41C1/1016 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2210/02 ,  B41C2210/08 ,  B41C2210/16 ,  B41N1/003

Abstract: A lithographic printing plate precursor requiring no fountain solution, comprising, in this order: a back layer containing a particle having an average particle size of 0.2 to 4.0 nullm; a support; a light-to-heat conversion layer; and a silicone rubber layer, wherein a dynamic friction coefficient between a surface of the back layer and a surface of a plate cylinder of a press on which the lithographic printing plate precursor is to be loaded is from 0.17 to 0.26.

Abstract translation: 不需要润版液的平版印刷版原版，其顺序为：含有平均粒径为0.2〜4.0μm的颗粒的背层; 一个支持 光热转换层; 以及硅橡胶层，其中背层的表面与印刷版的印版滚筒的表面之间的动摩擦系数为0.17至0.26。