公开(公告)号：US20140155611A1

公开(公告)日：2014-06-05

申请号：US14173323

申请日：2014-02-05

申请人： Nippon Soda Co., Ltd.

发明人： Hidekazu Miyazaki ,  Satoru Yanaka ,  Shiro Tsubokura ,  Tadashi Sugiura ,  Kaoru Noda ,  Kengo Suzuki

IPC分类号： C07D401/12

CPC分类号： C07D213/75 ,  C07D401/12 ,  C07D405/12

摘要： Disclosed is a compound containing a pyridine ring that can be synthesized in an industrially advantageous manner, and is useful as an intermediate for producing tetrazolyloxime derivatives that exhibit fungicidal activity (wherein R0 represents a C1-6 alkoxy group, C1-6 alkoxy-C1-6 alkoxy group or the like, R1 represents a C1-2 alkoxycarbonyl group, acetyl group or the like, Z represents a halogen atom, cyano group or the like, X represents a halogen atom, and n represents an integer of 0 to 3), and industrially advantageous production methods for producing 2-substituted amino-6-halomethylpyridine derivatives and tetrazolyloxime derivatives.

摘要翻译： 公开了含有可以工业上有利的方式合成的吡啶环的化合物，可用作生产具有杀真菌活性的四唑基肟衍生物的中间体（其中R 0表示C1-6烷氧基，C1-6烷氧基C1- 6烷氧基等，R 1表示C 1-2烷氧基羰基，乙酰基等，Z表示卤素原子，氰基等，X表示卤素原子，n表示0〜3的整数） 以及用于生产2-取代的氨基-6-卤甲基吡啶衍生物和四唑基肟衍生物的工业上有利的制备方法。

公开(公告)号：US08697867B2

公开(公告)日：2014-04-15

申请号：US13967872

申请日：2013-08-15

申请人： Isami Hamamoto ,  Jun Takahashi ,  Makio Yano ,  Masahiro Kawaguchi ,  Daisuke Hanai ,  Takao Iwasa

发明人： Isami Hamamoto ,  Jun Takahashi ,  Makio Yano ,  Masahiro Kawaguchi ,  Daisuke Hanai ,  Takao Iwasa

IPC分类号： C07D237/08 ,  C07D241/16 ,  C07D221/22

CPC分类号： C07D221/22 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  A01N43/90 ,  C07D211/54 ,  C07D211/58 ,  C07D221/24 ,  C07D237/08 ,  C07D241/16 ,  C07D401/04 ,  C07D401/12 ,  C07D417/04

摘要： Cyclic amine compounds represented by formula (1) or salts thereof or N-oxides thereof, wherein Cy1 represents an unsubstituted or substituted aromatic ring; X represents oxygen, sulfur, unsubstituted or substituted nitrogen, sulfinyl, or sulfonyl; R1a and R2a, R1a and R4a, R2a and R3a, or R3a and R4a form saturated rings together; R1a, R1b, R2a, R2b, R3a, R3b, R4a, R4b, and R5 which do not form the saturated rings are each independently hydrogen, hydroxyl, halogen, unsubstituted or substituted amino, nitro, or an organic group; Cy2 represents an unsubstituted or substituted aromatic ring with a proviso that Cy2 is an unsubstituted or substituted heteroaromatic ring when R1a and R2a form a saturated ring together and Cy1 is an unsubstituted or substituted phenyl, and Cy2 is a substituted pyridin-2-yl having one or more cyano as a substituent when Cy1 is an unsubstituted or substituted phenyl and Cy2 is a pyridin-2-yl.

摘要翻译： 由式（1）表示的环胺化合物或其盐或其N-氧化物，其中Cy1表示未取代或取代的芳环; X表示氧，硫，未取代或取代的氮，亚磺酰基或磺酰基; R1a和R2a，R1a和R4a，R2a和R3a，或R3a和R4a一起形成饱和环; 不形成饱和环的R1a，R1b，R2a，R2b，R3a，R3b，R4a，R4b和R5各自独立地为氢，羟基，卤素，未取代或取代的氨基，硝基或有机基团; Cy2表示未取代或取代的芳环，条件是当R 1a和R 2a一起形成饱和环时，Cy2为未取代或取代的杂芳环，Cy1为未取代或取代的苯基，Cy2为具有一个取代基的吡啶-2-基 或更多的氰基作为取代基，当Cy1是未取代或取代的苯基时，Cy2是吡啶-2-基。

公开(公告)号：US20140066405A1

公开(公告)日：2014-03-06

申请号：US14115590

申请日：2012-05-08

申请人： Kaoru Nishimura ,  Rieko Nakamura ,  Rie Sakamoto

发明人： Kaoru Nishimura ,  Rieko Nakamura ,  Rie Sakamoto

IPC分类号： A01N55/00 ,  A01N47/40

CPC分类号： A01N55/00 ,  A01N25/30 ,  A01N47/40 ,  A01N2300/00

摘要： A liquid insecticide composition is provided containing a neonicotinoid-based compound, a silicone-based surfactant, and a water-soluble organic solvent. Furthermore, a method is provided for enhancing an insecticidal effect which includes using a silicone-based surfactant in combination with a neonicotinoid-based compound as an insecticidal active ingredient.

摘要翻译： 提供含有新烟碱类化合物，硅氧烷类表面活性剂和水溶性有机溶剂的液体杀虫剂组合物。 此外，提供了一种增强杀虫效果的方法，其包括使用硅氧烷基表面活性剂与新烟碱类化合物组合作为杀虫活性成分。

公开(公告)号：US08609034B2

公开(公告)日：2013-12-17

申请号：US12734066

申请日：2008-10-10

申请人： Ilhyong Ryu ,  Masaaki Sato ,  Takahiro Sagae ,  Kenichi Hayashi

发明人： Ilhyong Ryu ,  Masaaki Sato ,  Takahiro Sagae ,  Kenichi Hayashi

IPC分类号： B01J8/00

CPC分类号： C07C17/275 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/44 ,  B01J35/023 ,  B01J35/026 ,  B01J2219/00835 ,  B01J2219/00891 ,  C07C67/343 ,  C07C205/16 ,  C07C22/04 ,  C07C69/618

摘要： This invention provides a microreactor comprising a microchamber provided with a raw material introduction port and a product discharge port; wherein solid catalysts are aligned in a line in the longitudinal direction of the microchamber to fill the microchamber.

摘要翻译： 本发明提供了一种微反应器，其包括设置有原料引入口和产品排出口的微型室; 其中固体催化剂在微室的纵向方向上一行排列以填充微室。

公开(公告)号：US20130324739A1

公开(公告)日：2013-12-05

申请号：US13985504

申请日：2012-03-19

申请人： Hiroshi Sumiya ,  Junji Ipposhi

发明人： Hiroshi Sumiya ,  Junji Ipposhi

IPC分类号： C07D263/22

CPC分类号： C07D263/22 ,  C07D263/44

摘要： An object of the present invention is to provide crystal polymorphs which have a high bulk density and are excellent in storage stability, among crystal polymorphs of a glutamic acid benzyl ester N-carboxylic anhydride. According to the present invention, the crystal polymorphs of glutamic acid benzyl ester N-carboxylic anhydride that have a bulk density of 0.45 g/cm3 or higher can be obtained by dissolving glutamic acid benzyl ester N-carboxylic anhydride in a solvent which has been heated at a temperature equal to or higher than 40° C. and lower than a boiling point thereof and is in an amount of 0.5 L or more per mol of the glutamic acid benzyl ester N-carboxylic anhydride, adding a poor solvent which is in an amount of 1.4 L or more per mol of the glutamic acid benzyl ester N-carboxylic anhydride at a temperature equal to or higher than 40° C. and lower than a boiling point thereof, precipitating crystals at a temperature equal to or higher than 40° C. and lower than a boiling point thereof, and cooling the crystals.

摘要翻译： 本发明的目的在于提供谷氨酸苄酯N-羧酸酐的结晶多晶型物中，具有高堆积密度，保存稳定性优异的晶体多晶型物。 根据本发明，通过将谷氨酸苄酯N-羧酸酐溶解在加热的溶剂中，可以得到堆积密度为0.45g / cm 3以上的谷氨酸苄酯N-羧酸酐的结晶多晶型物 在等于或高于40℃且低于其沸点的温度下，相对于每摩尔谷氨酸苄酯N-羧酸酐为0.5升以上，加入不良溶剂 在等于或高于40℃并低于其沸点的温度下，每摩尔谷氨酸苄酯N-羧酸酐的量为1.4升以上，在等于或高于40度的温度下析出晶体 并低于其沸点，并冷却晶体。

公开(公告)号：US08592412B1

公开(公告)日：2013-11-26

申请号：US13938896

申请日：2013-07-10

申请人： Nippon Soda Co., Ltd.

发明人： Ichirou Urihara ,  Atsunori Isshiki ,  Hiroyasu Hosokawa ,  Tomoyuki Saiga

IPC分类号： A01N43/713 ,  A01N43/88 ,  A01P3/00 ,  A01P7/04

CPC分类号： A01N43/713 ,  A01N43/88 ,  A01N47/18 ,  A01N37/34 ,  A01N37/46 ,  A01N43/36 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N47/04 ,  A01N47/12 ,  A01N47/34 ,  A01N47/44 ,  A01N51/00 ,  A01N55/00 ,  A01N57/12 ,  A01N59/20

摘要： The present invention provides a plant disease control agent containing at least one of tetrazoyloxime derivatives and salts thereof, and at least one selected from the group consisting of fosetyl, propamocarb, basic copper chloride, chlorothalonil, manzeb, cymoxanil, folpet, iminoctadine, cyazofamid, metalaxyl, fludioxonil, tebuconazole, prothioconazole, thiamethoxam, azoxystrobin and salts thereof.

摘要翻译： 本发明提供了含有四唑基肟衍生物及其盐中的至少一种的植物病害防除剂，以及选自聚西泮酯，丙酰胺，碱性氯化铜，百菌清，马萨诸塞，胞嘧磺隆，淫羊藿苷， 甲霜灵，氟虫腈，戊唑醇，丙硫菌唑，噻虫嗪，嘧菌酯及其盐。

公开(公告)号：US20130225824A1

公开(公告)日：2013-08-29

申请号：US13858586

申请日：2013-04-08

申请人： Takeshi OHKUMA ,  Noriyoshi ARAI ,  Masaya AKASHI ,  Hirohito OOOKA ,  Tsutomu INOUE

发明人： Takeshi OHKUMA ,  Noriyoshi ARAI ,  Masaya AKASHI ,  Hirohito OOOKA ,  Tsutomu INOUE

IPC分类号： C07D453/02

CPC分类号： C07D453/02 ,  B01J31/1805 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/0266 ,  B01J2531/821 ,  C07B53/00

摘要： A process is provided for efficiently producing an optically active 3-quinuclidinol derivative of high optical purity using a readily available ruthenium compound as an asymmetric reduction catalyst. This process is a process for producing an optically active 3-quinuclidinol derivative represented by the following formula (III) comprising asymmetrically hydrogenating a 3-quinuclidinone derivative represented by the following formula (I) in the presence of a ruthenium compound (II) represented by formula (II): Ru(X)(Y)(Px)n[R1R2C*(NR3R4)-A-R5R6C*(NR7R8)] (in the formulas, R represents a hydrogen atom or C7 to C18 aralkyl group and the like, X and Y represent hydrogen atoms or halogen atoms and the like, Px represents a phosphine ligand, n represents 1 or 2, R1 to R8 represent hydrogen atoms or C1 to C20 alkyl groups and the like, * represents an optically active carbon atom and A represents an ethylene group and the like).

摘要翻译： 提供了使用容易获得的钌化合物作为不对称还原催化剂有效地制备高光学纯度的光学活性的3-奎宁环醇衍生物的方法。 该方法是制备由下式（III）表示的光学活性3-奎宁环醇衍生物的方法，包括在下述式（I）表示的钌化合物（II）的存在下，使下式（I）表示的3-奎宁环酮衍生物 式（II）：Ru（X）（Y）（Px）n [R1R2C *（NR3R4）-A-R5R6C *（NR7R8）]（式中，R表示氢原子或C7〜C18芳烷基等 ，X和Y表示氢原子或卤素原子等，Px表示膦配体，n表示1或2，R1〜R8表示氢原子或C1〜C20烷基等，*表示光学活性碳原子， A表示亚乙基等）。

公开(公告)号：US20130158231A1

公开(公告)日：2013-06-20

申请号：US13819853

申请日：2011-09-13

申请人： Naoyuki Kamegaya ,  Kazuo Ono ,  Masato Amaike ,  Tomoya Nomura

发明人： Naoyuki Kamegaya ,  Kazuo Ono ,  Masato Amaike ,  Tomoya Nomura

IPC分类号： C08G65/02 ,  C09J163/00

CPC分类号： C08G65/02 ,  C08G59/42 ,  C08G59/4207 ,  C08G59/5073 ,  C08G59/56 ,  C08G59/62 ,  C09J163/00

摘要： An object of the present invention is to provide a curable epoxy resin composition containing an epoxy resin, wherein the composition is excellent in storage stability and curing characteristics and provides a cured product excellent in characteristics, particularly organic solvent resistance; an adhesive agent consisting of the composition; and an adhesive agent consisting of a curable epoxy resin composition excellent in adhesive strength. The curable epoxy resin composition of the present invention is a liquid curable epoxy resin composition containing the following (A) and (B): (A) an epoxy resin or an epoxy-polyester hybrid resin; and (B) a clathrate containing the following (b1) and (b2): (b1) at least one compound selected from the group consisting of a carboxylic acid compound represented by the formula A(COOH)a (wherein A represents a C1-C6 chain hydrocarbon group optionally having a substituent, a C3-C10 monocyclic hydrocarbon group optionally having a substituent, or a C6-C10 bicyclic hydrocarbon group optionally having a substituent; and a represents 2 or 3) and the like; and (b2) at least one compound selected from the group consisting of a compound represented by formula (II) and 1,8-diazabicyclo[5.4.0]undecene-7.

摘要翻译： 本发明的目的是提供一种含有环氧树脂的可固化环氧树脂组合物，其中所述组合物具有优异的储存稳定性和固化特性，并且提供了特性优异，特别是耐有机溶剂性的固化产物; 由该组合物组成的粘合剂; 以及由粘合强度优异的可固化环氧树脂组合物组成的粘合剂。 本发明的可固化环氧树脂组合物是含有下列（A）和（B）的液体可固化环氧树脂组合物：（A）环氧树脂或环氧 - 聚酯杂化树脂; 和（B）包含以下（b1）和（b2）的包合物：（b1）至少一种选自由式A（COOH）a表示的羧酸化合物的化合物（其中A表示C1- 任选具有取代基的C 6链烃基，任选具有取代基的C 3 -C 10单环烃基，或任选具有取代基的C 6 -C 10双环烃基; a表示2或3）等; 和（b2）选自由式（II）表示的化合物和1,8-二氮杂双环[5.4.0]十一碳烯-7的化合物中的至少一种化合物。

公开(公告)号：US20130131337A1

公开(公告)日：2013-05-23

申请号：US13705506

申请日：2012-12-05

申请人： NIPPON SODA CO., LTD.

发明人： Keiji MARUOKA ,  Yasushi KUBOTA

IPC分类号： B01J31/02

CPC分类号： B01J31/0271 ,  C07B53/00 ,  C07B2200/07 ,  C07C22/04 ,  C07C25/18 ,  C07C33/46 ,  C07C43/225 ,  C07D223/18 ,  C07D487/10

摘要： An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality. An optically active azepine derivative or a racemic azepine derivative represented by formula (3). Methods of producing an optically active quaternary ammonium salt compound represented by formula (8).

摘要翻译： 由式（2）表示的具有轴向手性的光学活性双苄基化合物或外消旋双苄基化合物。 光学活性吖庚因衍生物或由式（3）表示的外消旋吖庚因衍生物。 制备由式（8）表示的光学活性季铵盐化合物的方法。

公开(公告)号：US20130078333A1

公开(公告)日：2013-03-28

申请号：US13702873

申请日：2011-06-21

申请人： Kazuhisa Kumazawa ,  Hiromoto Shibata

发明人： Kazuhisa Kumazawa ,  Hiromoto Shibata

IPC分类号： B29C33/38

CPC分类号： B29C33/3878 ,  B29C35/02 ,  B29C35/0805 ,  B29C59/022 ,  B29C71/04 ,  B29C2035/0827 ,  B29C2059/023 ,  B29K2083/00 ,  B29K2105/243

摘要： The present invention provides a method for producing a replica mold for imprinting use which is inexpensive and has good properties including strength and flexibility. The method for producing a replica mold according to the present invention comprises the steps of: (A) coating a substrate with an organic-inorganic hybrid material; (B) semi-curing the coated surface with heat and/or an electromagnetic ray to produce a substrate for fine raised and depressed pattern formation; (C) pressing a master mold having a predetermined fine raised and depressed pattern formed thereon against the substrate for fine raised and depressed pattern formation by an imprinting method to transfer the fine raised and depressed pattern onto the substrate; and (D) irradiating the substrate for fine raised and depressed pattern formation onto which the fine raised and depressed pattern is transferred with an electromagnetic ray to cure the substrate.

摘要翻译： 本发明提供一种制造用于印刷用途的复制模具的方法，该复制模具便宜并且具有包括强度和柔性在内的良好性能。 根据本发明的复制模具的制造方法包括以下步骤：（A）用有机 - 无机混合材料涂覆基材; （B）用热和/或电磁射线对涂覆表面进行半固化，以产生用于精细的凸起和凹陷图案形成的衬底; （C）通过压印方法将具有形成在其上的预定微细凸起和凹陷图案的母模压在衬底上，用于通过压印方法形成细微的凸起和凹陷图案，以将微细的凸起和凹陷图案转印到衬底上; 和（D）用电磁射线照射基板以进行精细的凸起和凹陷图案形成，细微的凸起和凹陷图案被转印到其上以固化基板。