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    Carboamidoalkyl norbornanes and organoleptic use in detergents
    61.
    发明授权
    Carboamidoalkyl norbornanes and organoleptic use in detergents 失效
    卡波酰胺基烷基降冰片烷和感官用于洗涤剂

    公开(公告)号：US4331550A

    公开(公告)日：1982-05-25

    申请号：US268117

    申请日：1981-05-28

    申请人： Philip T. Klemarczyk ,  Frederick L. Schmitt ,  Edward J. Granda ,  Domenick Luccarelli, Jr.

    发明人： Philip T. Klemarczyk ,  Frederick L. Schmitt ,  Edward J. Granda ,  Domenick Luccarelli, Jr.

    IPC分类号： A24B15/34 ,  C07C45/62 ,  C07C45/69 ,  C07C47/347 ,  C07C47/445 ,  C07C61/13 ,  C11B9/00 ,  C11D3/50 ,  A61K7/46

    CPC分类号： C11D3/50 ,  A24B15/345 ,  C07C45/62 ,  C07C45/69 ,  C07C47/347 ,  C07C47/445 ,  C07C61/13 ,  C11B9/0046

    摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.

    摘要翻译： 描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。 此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体 或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。 还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl- and alkylidene-cycloalkanones
    63.
    发明授权
    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl- and alkylidene-cycloalkanones 失效
    2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基 - 环烷酮

    公开(公告)号：US4173585A

    公开(公告)日：1979-11-06

    申请号：US932677

    申请日：1978-08-10

    申请人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    发明人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    IPC分类号： C07C29/17 ,  C07C29/40 ,  C07C33/12 ,  C07C35/21 ,  C07C45/58 ,  C07C45/74 ,  C07C49/21 ,  C07C49/653 ,  C11B9/00 ,  C07C49/46 ,  C07C49/48

    CPC分类号： C07C29/175 ,  C07C29/17 ,  C07C29/40 ,  C07C33/12 ,  C07C35/21 ,  C07C45/58 ,  C07C45/74 ,  C07C49/21 ,  C07C49/653 ,  C11B9/003 ,  C11B9/0034 ,  C07C2101/08 ,  C07C2101/10 ,  C07C2101/14

    摘要： Described are perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines +++++ is a carbon-carbon double bond and the other of the lines +++++ is a carbon-carbon single bond; wherein X is carbinol having the structure: ##STR2## or carbonyl having the structure ##STR3## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances. Also described is a process for preparing such compounds according to the reaction schemes: ##STR4## wherein the lines +++++ A', B', the dashed lines and n are as defined above wherein M is alkaline metal.

    摘要翻译： 描述了香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香水制品， 其中线+++++之一是碳 - 碳双键，另一条线+++++是碳 - 碳单键; 其中X是具有以下结构的甲醇：具有结构的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿 和土质的香气与树脂的顶部和坚果油的细微差别。 还描述了根据反应方案制备这些化合物的方法：其中线+++++ A'，B'，虚线和n如上所定义，其中 M是碱金属。

    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones, organoleptic uses thereof in perfume compositions, colognes and perfumed articles and process for producing same
    65.
    发明授权
    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones, organoleptic uses thereof in perfume compositions, colognes and perfumed articles and process for producing same 失效
    2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮，在香料组合物，古龙水和香料制品中的感官用途及其制备方法

    公开(公告)号：US4210767A

    公开(公告)日：1980-07-01

    申请号：US23442

    申请日：1979-03-23

    申请人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    发明人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    IPC分类号： C07C29/143 ,  C07C29/17 ,  C07C29/40 ,  C07C35/21 ,  C07C45/74 ,  C07C49/653 ,  C11B9/00 ,  C07C45/00 ,  C07C29/00

    CPC分类号： C11B9/0034 ,  C07C29/143 ,  C07C35/21 ,  C07C45/74 ,  C07C49/653 ,  C11B9/003 ,  C07B2200/09 ,  C07C2101/08 ,  C07C2101/10 ,  C07C2101/14

    摘要： Described are perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines + + + + + is a carbon-carbon double bond and the other of the lines + + + + + is a carbon-carbon single bond; wherein X is carbinol having the structure: ##STR2## or carbonyl having the structure ##STR3## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen,CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances. Also described is a process for preparing such compounds according to the reaction schemes: ##STR4## wherein the lines + + + + + A', B', the dashed lines and n are as defined above wherein M is alkaline metal.

    摘要翻译： 描述了香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香水制品， 其中线+ + + + +之一是碳 - 碳双键，另一条线+ + + + + +是碳 - 碳单键; 其中X是具有以下结构的甲醇：具有结构的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿 和土质的香气与树脂的顶部和坚果油的细微差别。 还描述了根据以下反应方案制备这些化合物的方法：其中线+ + + + + A'，B'，虚线和n如上所定义，其中 M是碱金属。

    2,2,3-Trimethyl-3-cyclopenten-1-yl-alkenyl and alkylidene cycloalkanones
    66.
    发明授权
    2,2,3-Trimethyl-3-cyclopenten-1-yl-alkenyl and alkylidene cycloalkanones 失效
    2,2,3-三甲基-3-环戊烯-1-基 - 链烯基和亚烷基环烷酮

    公开(公告)号：US4206091A

    公开(公告)日：1980-06-03

    申请号：US23385

    申请日：1979-03-23

    申请人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    发明人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    IPC分类号： C07C29/143 ,  C07C29/17 ,  C07C29/40 ,  C07C45/74 ,  C07C49/653 ,  C11B9/00 ,  A61K7/46

    CPC分类号： C07C29/143 ,  C07C45/74 ,  C07C49/653 ,  C11B9/003 ,  C11B9/0034

    摘要： Described are perfume and fragrance compositions and colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines +++++ is a carbon-carbon double bond and the other of the lines +++++ is a carbon-carbon single bond; wherein X is carbonyl having the structure ##STR2## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances.

    摘要翻译： 描述了含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香料和香料组合物和古龙卷，其中一行+++ ++是碳 - 碳双键，另一条线+++++是碳 - 碳单键; 其中X是具有结构“IMAGE”的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿 和土质的香气与树脂的顶部和坚果油的细微差别。

    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones, organoleptic uses thereof in perfume compositions, colognes and perfumed articles and process for producing same
    69.
    发明授权
    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones, organoleptic uses thereof in perfume compositions, colognes and perfumed articles and process for producing same 失效
    2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮，在香料组合物，古龙水和香料制品中的感官用途及其制备方法

    公开(公告)号：US4241228A

    公开(公告)日：1980-12-23

    申请号：US23322

    申请日：1979-03-22

    申请人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    发明人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    IPC分类号： C07C33/12 ,  C07C45/74 ,  C11B9/00 ,  C07C35/21

    CPC分类号： C11B9/0034 ,  C07C33/12 ,  C07C45/74 ,  C11B9/003

    摘要： Described are perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines +++++ is a carbon-carbon double bond and the other of the lines +++++ is a carbon-carbon single bond; wherein X is carbinol having the structure: ##STR2## or carbonyl having the structure ##STR3## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances. Also described is a process for preparing such compounds according to the reaction schemes: ##STR4## wherein the lines +++++ A', B', the dashed lines and n are as defined above wherein M is alkaline metal.

    摘要翻译： 描述了香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香水制品， 其中线+++++之一是碳 - 碳双键，另一条线+++++是碳 - 碳单键; 其中X是具有以下结构的甲醇：具有结构的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿 和土质的香气与树脂的顶部和坚果油的细微差别。 还描述了根据反应方案制备这些化合物的方法：其中线+++++ A'，B'，虚线和n 如上所定义，其中M是碱金属。