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61.发明授权
公开(公告)号：US4525294A
公开(公告)日：1985-06-25
申请号：US484943
申请日：1983-04-14
申请人： Guido Sartori , Warren A. Thaler
发明人： Guido Sartori , Warren A. Thaler
摘要： The present invention relates to the preparation of mixtures of sterically hindered substituted N-secondary amino acids or their alkali metal salts by a one-step reductive condensation of an amino acid or its alkali metal salt containing a primary amino group and a ketone to thereby form a mono-substituted amino acid or alkali metal salt thereof, followed by preparing the corresponding sterically hindered tertiary amino acids or alkali metal salt thereof by reacting the mono-substituted amino acids or alkali metal salt thereof with an unhindered aldehyde under reducing conditions in the presence of a hydrogenating catalyst. The novel mixtures of the sterically hindered mono-substituted amino acids and the tertiary amino acids and their alkali metal salts are useful promoters for alkaline salts in "hot pot" acid gas scrubbing processes.
摘要翻译： 本发明涉及通过氨基酸或其含有伯氨基和酮的碱金属盐的一步还原缩合制备空间位阻取代的N-仲氨基酸或其碱金属盐的混合物，从而形成 单取代的氨基酸或其碱金属盐，然后在还原条件下使单取代的氨基酸或其碱金属盐与不受阻碍的醛反应制备相应的空间位阻叔氨基酸或其碱金属盐， 的氢化催化剂。 空间位阻单取代氨基酸和叔氨基酸及其碱金属盐的新型混合物是“火锅”酸性气体洗涤方法中碱性盐的有用促进剂。
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62.发明授权Process for removing acid gases using a basic salt activated with a non-sterically hindered diamine 失效用非位阻二胺活化的碱性盐除去酸性气体的方法
公开(公告)号：US4376101A
公开(公告)日：1983-03-08
申请号：US321059
申请日：1981-11-13
CPC分类号： B01D53/1493 , Y02C10/06
摘要： Acidic gases containing carbon dioxide are removed from a normally gaseous mixture by absorbing CO.sub.2 from the gaseous mixture with an aqueous solution comprising a basic alkali metal salt or hydroxide and an activator or promoter system for the salt or hydroxide which contains (i) at least one non-sterically hindered diamine defined as having both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, and (ii) an amino acid, and desorbing at least partially the absorbed CO.sub.2 from the aqueous solution.
摘要翻译： 通过用包含碱性碱金属盐或氢氧化物的水溶液和用于盐或氢氧化物的活化剂或助催化剂体系的水溶液从气态混合物中吸收二氧化碳，从常规气体混合物中除去含二氧化碳的酸性气体，其含有（i）至少一种 定义为具有伯氨基和叔氨基部分的非位阻二胺，其中伯氨基部分连接到伯碳原子上，和（ii）氨基酸，并且至少部分地从水溶液中解吸所吸收的CO 2。
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63.发明授权1-Secondary or 1-tertiary alkyl or cycloalkyl-hexahydro-2-pyrimidinones and 1-secondary or 1-tertiary alkyl or 1-cycloalkyl-2-imidazolidinones and their use as antifoaming agents 失效1-仲烷基或1-叔烷基或环烷基 - 六氢-2-嘧啶酮和1-仲或1-叔烷基或1-环烷基-2-咪唑啉酮及其作为消泡剂的用途
公开(公告)号：US4343716A
公开(公告)日：1982-08-10
申请号：US51873
申请日：1979-06-25
CPC分类号： B01D53/1493 , Y02C10/06
摘要： Antifoaming agents for use in acid gas scrubbing processes comprising 1-secondary or 1-tertiary alkyl- or 1-cycloalkyl-hexahydro-2-pyrimidinones and 1-secondary or 1-tertiary alkyl- or 1-cycloalkyl-2-imidazolidinones are disclosed.
摘要翻译： 公开了用于酸性气体洗涤方法的消泡剂，其包含1-仲或1-叔烷基 - 或1-环烷基 - 六氢-2-嘧啶酮和1-仲或1-叔烷基 - 或1-环烷基-2-咪唑啉酮。
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64.发明授权Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures 失效用于从气体混合物中除去酸性气体的工艺和胺 - 溶剂吸收剂
公开(公告)号：US4240922A
公开(公告)日：1980-12-23
申请号：US835811
申请日：1977-09-22
申请人： Guido Sartori , David W. Savage
发明人： Guido Sartori , David W. Savage
CPC分类号： B01D53/1493 , B01D53/526
摘要： Acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an amine-solvent liquid absorbent comprising (i) an amine mixture comprised of at least about 50 mol % of a sterically hindered amine and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amine contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom, and (ii) a solvent for said amine mixture which is also a physical absorbent for said acidic gases. The liquid absorbent may also include up to about 35 weight percent water. The coaction of the sterically hindered amine and the tertiary amino alcohol in conjunction with the solvent provides an increase in the amount of CO.sub.2 containing acidic gases absorbed compared to the use of the same sterically hindered amines alone and lowers the heat of reaction.
摘要翻译： 酸性气体通过包括将常规气态混合物与胺溶剂液体吸收剂接触的方法基本上从常规气体混合物中除去，该胺溶剂液体吸收剂包含（i）由至少约50mol％空间位阻胺和至少约 10摩尔％的叔氨基醇，其中所述空间位阻胺含有至少一个作为环的一部分的仲氨基并连接到连接到叔碳原子上的仲或叔碳原子或伯氨基上， 和（ii）所述胺混合物的溶剂，其也是所述酸性气体的物理吸收剂。 液体吸收剂还可包含至多约35重量％的水。 与单独使用相同的空间位阻胺相比，空间位阻胺和叔氨基醇与溶剂的共同作用与吸收的含CO 2的量相比增加了，降低了反应热。
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65.发明授权Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures 失效用于从气体混合物中除去酸性气体的工艺和胺 - 溶剂吸收剂
公开(公告)号：US4112051A
公开(公告)日：1978-09-05
申请号：US862195
申请日：1977-12-19
申请人： Guido Sartori , Frederic Leder
发明人： Guido Sartori , Frederic Leder
CPC分类号： B01D53/1475 , B01D53/1493 , Y02C10/04 , Y02C10/06
摘要： Acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an amine-solvent liquid absorbent comprising (i) an amine comprised of at least about 50 mol % of a sterically hindered amine, and (ii) a solvent for said amine mixture which is also a physical absorbent for said acidic gases. The liquid absorbent may also include up to about 35 weight percent water.
摘要翻译： 通过包括使常规气态混合物与胺溶剂液体吸收剂接触的方法基本上从酸性气体除去酸性气体，所述胺溶剂液体吸收剂包括（i）由至少约50mol％空间位阻胺组成的胺，和（ii） 所述胺混合物的溶剂也是所述酸性气体的物理吸收剂。 液体吸收剂还可包含至多约35重量％的水。
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公开(公告)号：US4100128A
公开(公告)日：1978-07-11
申请号：US787367
申请日：1977-04-14
申请人： Guido Sartori , Robert D. Lundberg
发明人： Guido Sartori , Robert D. Lundberg
摘要： The instant invention relates to compositions comprising a copolymer of sulfur dioxide and one or more olefins in combination with a hydrocarbon oil which is a mixture of paraffinic, aromatic and naphthenic hydrocarbons having a solubility parameter of about 7 to about 8.5. The olefins are alpha olefins, at least one having a carbon number of 20 or more, more preferably a carbon number of from 20 to 40. The copolymers useful in preparing the compositions of the instant invention are crystalline solids, which are combined with a sufficient amount, preferably from about 5 to 24 pph, of the hydrocarbon oil to yield flexible materials. The above compositions are useful as coatings.
摘要翻译： 本发明涉及包含二氧化硫和一种或多种烯烃与烃油的共聚物的组合物，烃油是溶解度参数为约7至约8.5的链烷烃，芳族烃和环烷烃的混合物。 烯烃是α-烯烃，至少一种碳原子数为20以上，更优选碳原子数为20〜40。可用于制备本发明组合物的共聚物是结晶固体，它们与足够的 量，优选约5至24pph的烃油，以产生柔性材料。 上述组合物可用作涂层。
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67.发明授权Block copolymers containing olefin sulfur dioxide segments and process for their preparation 失效含有烯烃二氧化硫段的嵌段共聚物及其制备方法
公开(公告)号：US3932369A
公开(公告)日：1976-01-13
申请号：US521454
申请日：1974-11-06
申请人： Guido Sartori , Robert D. Lundberg
发明人： Guido Sartori , Robert D. Lundberg
IPC分类号： C08F293/00 , C08G75/22 , C08F28/00
CPC分类号： C08G75/22 , C08F293/00
摘要： The instant invention relates to novel block copolymers containing olefin sulfur-dioxide segments and a process for their preparation. The olefin of choice is a "strained" olefin thus capable of reaction with SO.sub.2 in the presence of radicals at very high rates. Examples of strained olefins include cyclopropene, cyclobutene, norbornene, and the derivatives thereof. The novel block copolymers are prepared by contacting the olefin and the sulfur dioxide with a polymer under conditions of shearing degradation whereby said polymer is broken down into radical-containing segments which subsequently combine with the olefin and sulfur dioxide to form the novel copolymers described above. The polymer may be selected from the group consisting of polyisobutylene, poly(ethylene oxide), ethylene-propylene copolymers, poly(propylene oxide), polybutadiene, polyisoprene, etc. A novel block polymer formed by this preferred process shows improved properties as compared to physical mixtures of said polymer and olefin-sulfur dioxide copolymers. For example, the novel polymers formed by the preferred process of the instant invention show higher moduli and may be plasticized to higher levels while retaining good physical properties.
摘要翻译： 本发明涉及含有烯烃二氧化硫段的新型嵌段共聚物及其制备方法。 所选择的烯烃是一种“应变”烯烃，因此能够在极性存在自由基的情况下与SO2反应。 应变烯烃的实例包括环丙烯，环丁烯，降冰片烯及其衍生物。 通过在剪切降解的条件下使烯烃和二氧化硫与聚合物接触来制备新的嵌段共聚物，其中所述聚合物被分解成含自由基的链段，其随后与烯烃和二氧化硫结合以形成上述新的共聚物。 聚合物可以选自聚异丁烯，聚（环氧乙烷），乙烯 - 丙烯共聚物，聚（环氧丙烷），聚丁二烯，聚异戊二烯等。通过该优选方法形成的新的嵌段聚合物显示出与 所述聚合物和烯烃 - 二氧化硫共聚物的物理混合物。 例如，通过本发明优选方法形成的新型聚合物显示更高的模量，并且可以塑化至更高的水平，同时保持良好的物理性能。
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公开(公告)号：US06767452B1
公开(公告)日：2004-07-27
申请号：US09958436
申请日：2001-10-09
IPC分类号： C10G4500
CPC分类号： C10G29/22
摘要： The invention is a process for decreasing the acidity of an organic acid containing petroleum oil, comprising contacting said petroleum oil containing organic acids with an effective amount of an alcohol and an effective trace amount of a base selected from Group IA and IIA metal carbonates, hydroxides, phosphates, biphosphates and mixtures of a hydroxide and phosphate and/or biphosphates at a temperature and under conditions sufficient to form the corresponding ester of said alcohol.
摘要翻译： 本发明是降低含有机酸的石油的酸度的方法，包括将含有机酸的石油与有效量的醇和有效微量的选自IAA和IIA族金属碳酸盐的碱，氢氧化物 ，磷酸盐，二磷酸盐以及氢氧化物和磷酸盐和/或二磷酸盐的混合物，在足以形成所述醇的相应酯的温度和条件下。
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公开(公告)号：US06190541B1
公开(公告)日：2001-02-20
申请号：US09309941
申请日：1999-05-11
IPC分类号： C10G4500
CPC分类号： C10G29/22
摘要： The invention is a process for decreasing the acidity of an organic acid containing petroleum oil, comprising contacting said petroleum oil containing organic acids with an effective amount of an alcohol and an effective trace amount of a base selected from Group IA and IIA metal carbonates, hydroxides, phosphates, and mixtures of a hydroxide and phosphate at a temperature and under conditions sufficient to form the corresponding ester of said alcohol.
摘要翻译： 本发明是降低含有机酸的石油的酸度的方法，包括将含有机酸的石油与有效量的醇和有效微量的选自IAA和IIA族金属碳酸盐的碱，氢氧化物 ，磷酸盐，以及氢氧化物和磷酸盐的混合物在足以形成所述醇的相应酯的温度和条件下进行。
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公开(公告)号：US06030524A
公开(公告)日：2000-02-29
申请号：US167153
申请日：1998-10-06
申请人： David W. Savage , Guido Sartori
发明人： David W. Savage , Guido Sartori
摘要： In an atmospheric pipestill stripping process where steam is utilized as the stripping gas to strip bottoms and side stream products, the improvement comprising utilizing methanol or a methanol and steam mixture as said stripping gas. In a refinery atmospheric pipestill stripping process utilizing a stripping gas, said process comprising utilizing a gas selected from the group consisting of methanol and a mixture of methanol and steam as said stripping gas.
摘要翻译： 在其中使用蒸汽作为汽提气体来剥离塔底馏分物和副产物的大气管道蒸馏过程中，改进包括利用甲醇或甲醇和蒸汽混合物作为所述汽提气体。 在利用汽提气体的炼油大气管道汽提过程中，所述方法包括利用选自甲醇和甲醇和蒸汽混合物的气体作为所述汽提气体。
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