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    Method for preparing β-phosphorus nitroxide radicals
    62.
    发明授权
    Method for preparing β-phosphorus nitroxide radicals 有权
    制备β-磷氮氧自由基的方法

    公开(公告)号：US07126021B2

    公开(公告)日：2006-10-24

    申请号：US10450128

    申请日：2001-12-07

    申请人： Olivier Guerret ,  Jean-Luc Couturier ,  Christophe Le Mercier

    发明人： Olivier Guerret ,  Jean-Luc Couturier ,  Christophe Le Mercier

    IPC分类号： C07F9/02

    CPC分类号： C07F9/4006

    摘要： The present invention relates to a process for the preparation of β-phosphorated nitroxide radicals which consist in preparing, in a first step, an aminophosphonate by reaction of a carbonyl compound, of a primary amine and of a phosphorous compound in the presence of a Lewis acid and then, in a second step, in oxidizing the said crude aminophosphonate using nonhalogenated organic peracids in a water/organic solvent two-phase medium with an aqueous phase buffered at a pH ranging from 5 to 12.

    摘要翻译： 本发明涉及一种制备β-磷酸化氮氧自由基的方法，其包括在第一步中通过羰基化合物，伯胺和磷化合物在Lewis的存在下反应制备氨基膦酸酯 然后在第二步中，使用非卤代有机过酸在水/有机溶剂两相介质中氧化所述粗氨基膦酸酯，其中水相在pH为5至12的范围内缓冲。

    Water-soluble or water-dispersible acrylic dispersants obtained by controlled radical polymerization
    63.
    发明申请
    Water-soluble or water-dispersible acrylic dispersants obtained by controlled radical polymerization 失效
    通过控制自由基聚合获得的水溶性或水分散性丙烯酸分散剂

    公开(公告)号：US20060111479A1

    公开(公告)日：2006-05-25

    申请号：US11270751

    申请日：2005-11-09

    申请人： Manuel Hidalgo ,  Stephanie Magnet ,  Olivier Guerret

    发明人： Manuel Hidalgo ,  Stephanie Magnet ,  Olivier Guerret

    IPC分类号： C04B24/26

    CPC分类号： C08F220/32 ,  C04B24/2647 ,  C04B24/2694 ,  C04B2103/0045 ,  C04B2103/408 ,  C08F2/16 ,  C08F2/38 ,  C08F220/06

    摘要： The present invention relates to a process for the preparation in aqueous solution of water-soluble acrylic polymers or for the preparation in aqueous dispersion of water-dispersible acrylic co-polymers, polymerised from, being 100 mol %: a) 5 to 70 mol % of one or more monomer(s) (A) which are (alkoxy)polyalkylene glycol (meth)acrylates and/or ((alkoxy)polyalkylene glycol)(meth)acrylamides; b) 5 to 95 mol % of one or more unsaturated carboxylic monomer(s) (B); and c) 0 to 85 mol % of one or more hydrophobic monomer(s) (C) which are water insoluble, in the absence of a chain-transfer agent, and in the presence of a sufficient amount of a water-soluble alkoxyamine, until a conversion of at least 90% by weight of the monomers (A), (B) and (C) is obtained. The polymer has a polydispersity index {overscore (Mw)}/{overscore (Mn)} advantageously 50%) is converted by the alkoxyamine and the polymerization is completed by a conventional radical initiator. The polymer obtained has a polydispersity index {overscore (Mw)}/{overscore (Mn)}

    摘要翻译： 本发明涉及一种在水溶性丙烯酸类聚合物的水溶液中制备或在水分散性丙烯酸共聚物的水分散体中制备方法，聚合度为100摩尔％：a）5-70摩尔％ （甲氧基）聚亚烷基二醇（甲基）丙烯酸酯和/或（（烷氧基）聚亚烷基二醇）（甲基）丙烯酰胺的一种或多种单体（A） b）5〜95摩尔％的一种或多种不饱和羧酸单体（B）; 和c）在不存在链转移剂的情况下，在足够量的水溶性烷氧基胺存在下，0至85mol％的一种或多种水不溶性疏水单体（C） 直到得到至少90重量％的单体（A），（B）和（C）的转化率。 聚合物具有多分散性指数（超核（Mw / {超芯（Mn有利地<2）和（超核（Mn在10,000至50,000之间）。或者，仅一些单体（> 50％）由烷氧基胺转化， 所获得的聚合物具有多分散性指数（超核（Mw / {超晶核（Mn <6，有利地<5，优选<4），并且（超晶核（Mw在10,000至500000 有利地在3万到15万之间。

    Thermoset materials with improved impact resistance
    67.
    发明授权
    Thermoset materials with improved impact resistance 有权
    具有改善耐冲击性的热固性材料

    公开(公告)号：US07767757B2

    公开(公告)日：2010-08-03

    申请号：US11813799

    申请日：2006-01-18

    申请人： Olivier Guerret ,  Pierre Gerard ,  Jean-Pierre Pascault ,  Anthony Bonnet

    发明人： Olivier Guerret ,  Pierre Gerard ,  Jean-Pierre Pascault ,  Anthony Bonnet

    IPC分类号： C08L53/00 ,  C08L63/00 ,  C08F297/00 ,  C08F293/00

    CPC分类号： C08L53/00 ,  C08L101/00 ,  C08L2666/14 ,  C08L2666/02 ,  C08L2666/04

    摘要： The present invention relates to a thermoset material with improved impact resistance comprising, by weight: •99 to 20% of a thermoset resin, •1 to 80% of an impact modifier comprising at least one copolymer chosen from copolymers comprising A-B-C and A-B blocks, in which: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, A is a copolymer of methyl methacrylate and of at least one water-soluble monomer, C is either (i) a PMMA (homopolymer or copolymer) this PMMA comprising optionally a water-soluble monomer or (ii) a polymer based on vinyl monomers or mixture of vinyl monomers, B is incompatible or partially compatible with the thermoset resin and incompatible with the A block and the optional C block and its glass transition temperature Tg is less than the operating temperature of the thermoset material. The invention also relates to the use of these impact modifiers in thermosets.

    摘要翻译： 本发明涉及具有改进的抗冲击性的热固性材料，其包含重量百分比：99至20％的热固性树脂，1至80％的抗冲改性剂，其包含至少一种选自包含ABC和AB嵌段的共聚物的共聚物， 其中：每个嵌段通过共价键或通过共价键连接到其中一个嵌段的中间分子连接，另一个通过另一个共价键连接到另一个嵌段，A是甲基丙烯酸甲酯和 至少一种水溶性单体C是（i）PMMA（均聚物或共聚物），该PMMA包含任选的水溶性单体或（ii）基于乙烯基单体或乙烯基单体混合物的聚合物，B是不相容的或 与热固性树脂部分相容并且与A嵌段和任选的C嵌段不相容，并且其玻璃化转变温度Tg小于热固性材料的操作温度。 本发明还涉及这些抗冲改性剂在热固性材料中的应用。

    Novel Method for the Synthesis/Production of Acrylic Films
    69.
    发明申请
    Novel Method for the Synthesis/Production of Acrylic Films 审中-公开
    丙烯酸薄膜的合成/生产的新方法

    公开(公告)号：US20080050572A1

    公开(公告)日：2008-02-28

    申请号：US10550808

    申请日：2004-03-23

    申请人： Olivier Guerret ,  Gerard Pierre

    发明人： Olivier Guerret ,  Gerard Pierre

    IPC分类号： B32B27/36 ,  C08L33/04

    CPC分类号： C08J5/18 ,  C08F293/005 ,  C08F2438/02 ,  C08J2353/00

    摘要： The invention relates to the use of block copolymers, obtained by controlled radical polymerization in the presence of alkoxyamine derivatives of substituted nitroxides, for the production of perfectly transparent acrylic films with the mechanical properties required for the applications envisaged, whereby the transparency thereof remains under mechanical stress and a wide temperature range. The total thickness is between 40 and 300 microns, preferably 70 to 90 microns. The film has a haze of less than 2 and elongation at breakage of more than 90%.

    摘要翻译： 本发明涉及通过在取代的氮氧化物的烷氧基胺衍生物的存在下通过受控自由基聚合获得的嵌段共聚物的用途，用于制备具有所设想的应用所需的机械性能的完全透明的丙烯酸膜，由此其透明度保持在机械 压力和较宽的温度范围。 总厚度为40至300微米，优选为70至90微米。 该膜的雾度小于2，断裂伸长率大于90％。