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61.发明授权Process for co-reacting poly(isobutylene) and linear olefins to prepare synthetic lubricant base stocks having improved properties 失效合成聚（异丁烯）和线性烯烃的方法来制备具有改进性能的合成润滑剂基料
公开(公告)号：US5180869A
公开(公告)日：1993-01-19
申请号：US699533
申请日：1991-05-14
IPC分类号： C10M107/02 , C07C2/08 , C10M107/08 , C10M107/10 , C10M169/04 , C10N30/02 , C10N30/08 , C10N30/10 , C10N60/02 , C10N70/00
CPC分类号： C10M169/041 , C07C2/08 , C10M107/10 , C07C2521/16 , C10M2205/026 , C10M2205/0285 , C10M2219/04
摘要： A process is disclosed for preparing synthetic lubricant base stocks having improved properties. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic montmorillonite clay catalysts. When a mixture of poly(isobutylene) and long-chain linear olefin, in which up to about 10 wt. % of the mixture is poly(isobutylene), is co-reacted in the presence of these catalysts, a synthetic lubricant base stock having a high viscosity and a high viscosity index is prepared.
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62.发明授权Oxidation of primary alcohols to aldehydes using transition metal phthalocyanines as catalysts 失效使用过渡金属酞菁作为催化剂将伯醇氧化成醛
公开(公告)号：US5132465A
公开(公告)日：1992-07-21
申请号：US689569
申请日：1991-04-23
摘要： Primary alcohols may be oxidized to the corresponding aldehydes using non-toxic oxidizing agents such as tert-butyl hydroperoxide (TBHP) in the presence of a transition metal phthalocyanine catalyst. Representative catalysts include ferrous phthalocyanine and chloroferric phthalocyanine. Under some conditions, 1,1-dialkoxyalkanes may be co-produced with the aldehydes. 1,1-Dialkoxyalkanes are protected aldehydes and find utility in solvents.
摘要翻译： 在过渡金属酞菁催化剂存在下，可以使用无毒氧化剂如叔丁基过氧化氢（TBHP）将伯醇氧化成相应的醛。 代表性的催化剂包括亚铁酞菁和氯铁酞菁。 在一些条件下，可以与醛共同生产1,1-二烷氧基烷烃。 1,1-Dialkoxyalkanes是受保护的醛类，可用于溶剂中。
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63.发明授权Catalytic process for the production of diketone derivatives of polyoxypropylene glycols 失效用于生产聚氧丙烯二醇的二酮衍生物的催化方法
公开(公告)号：US5099073A
公开(公告)日：1992-03-24
申请号：US653220
申请日：1991-02-11
申请人： John R. Sanderson , John M. Larkin
发明人： John R. Sanderson , John M. Larkin
CPC分类号： C08G65/321 , C07C45/002
摘要： A process for the conversion of a polyoxypropylene glycol to the corresponding diketone derivative by dehydrogenation in the presence of an unsupported nickel, copper, chromia catalyst or a Raney nickel catalyst.
摘要翻译： 在非负载的镍，铜，氧化铬催化剂或阮内镍催化剂存在下，通过脱氢将聚氧丙烯二醇转化为相应的二酮衍生物的方法。
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公开(公告)号：US5072050A
公开(公告)日：1991-12-10
申请号：US594464
申请日：1990-10-09
IPC分类号： C07C45/30 , C07C49/175
CPC分类号： C07C49/175 , C07C45/30
摘要： Mono-, di- and tri-ketones of polyoxyalkylene compounds prepared by a method whereby the terminal hydroxyl groups of polyoxyalkylene compounds are oxidized to ketone groups with an alkali metal or an alkaline earth metal hypochlorite oxidant in the presence of acetic acid are disclosed. These compounds are useful for preparing surface active agents or they may be reacted with amines to provide fuel additives.
摘要翻译： 公开了通过使聚氧化烯化合物的末端羟基在乙酸存在下用碱金属或碱土金属次氯酸盐氧化剂氧化成酮基的方法制备的聚氧化烯化合物的单 - ，二 - 和三 - 酮。 这些化合物可用于制备表面活性剂，或者它们可与胺反应以提供燃料添加剂。
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公开(公告)号：US4992566A
公开(公告)日：1991-02-12
申请号：US401381
申请日：1989-08-31
IPC分类号： C07D301/14 , B01J23/28 , B01J23/92 , B01J31/22 , B01J38/00 , C07B61/00 , C07C27/28 , C07C29/03 , C07C29/80 , C07C31/12 , C07C407/00 , C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , C07C29/80 , C07C407/003
摘要： Tertiary butyl hydroperoxide and tertiary butyl alcohol are recovered from the reaction product formed by reacting excess propylene with tertiary butyl hydroperoxide in solution in tertiary butyl alcohol in the presence of a soluble molybdenum catalyst, by fractionating the reaction produce to provide distillate propylene, propylene oxide, and tertiary butyl alcohol fractions and a heavy distillation fraction comprising tertiary butyl hydroperoxide, tertiary butyl alcohol and impurities, including dissolved molybdenum catalyst, the tertiary butyl hydroperoxide and tertiary butyl alcohol being recovered from the heavy distillation fraction by vacuum evaporation under evaporation conditions including a temperature of about 25.degree. to about 160.degree. C. and a pressure of about 2 to about 200 mm Hg. in order to provide a lighter condensate fraction comprising about 60 to about 95 wt. % of the heavy distillation fraction and containing from about 70 to about 95 wt. % of tertiary butyl alcohol, about 1 to about 20 wt. % of the tertiary butyl hydroperoxide and from about 15 to about 3 wt. % of impurities and also into a clear liquid heavier residue fraction comprising tertiary butyl alcohol, tertiary butyl hydroperoxide and substantially all of the soluble molybdenum catalyst originally contained in the heavy liquid fraction.
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66.发明授权Dicyano bis-(1,10-phenanthrolene)iron(II) catalyst useful for detergent range alcohols and ketones 失效可用于洗涤剂范围的醇和酮的二氰基双 - （1,10-菲咯啉）铁（II）催化剂
公开(公告)号：US4970346A
公开(公告)日：1990-11-13
申请号：US428701
申请日：1989-10-30
IPC分类号： C07C29/48 , C07C45/28 , C07C409/10
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of dicyano bis-(1,10-phenanthrolene)iron(II) is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide.
摘要翻译： 描述了在二氰基双 - （1,10-菲咯啉）铁（II）存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。
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公开(公告)号：US4960948A
公开(公告)日：1990-10-02
申请号：US456891
申请日：1989-12-26
IPC分类号： C08G65/32 , C07C45/30 , C07C49/175 , C08F8/06 , C08G65/324
CPC分类号： C08G65/324 , C07C45/30 , C07C49/175
摘要： Polyoxypropylene diketones are prepared by initially adding predetermined amounts of glacial acetic acid, a polyoxypropylene glycol and, optionally, water, to a reaction zone and thereafter adding an aqueous solution of an alkali metal or an alkaline earth metal hypochlorite oxidant to the reaction zone with agitation under reaction conditions including a temperature of about 10.degree. to about 50.degree. C., a pressure of about 0 to 1,000 psig. and a total reaction time of about 0.5 to 20 hours, whereby said polyoxypropylene glycol will be substantially selectively converted to the said corresponding diketone, and recovering said diketone.
摘要翻译： 通过首先向反应区中加入预定量的冰醋酸，聚氧丙烯二醇和任选的水，然后在搅拌下向反应区中加入碱金属或碱土金属次氯酸盐氧化剂的水溶液来制备聚氧丙烯二酮 在包括约10℃至约50℃的温度，约0-1000psig压力的反应条件下进行。 并且总反应时间为约0.5至20小时，由此所述聚氧丙烯二醇将基本上选择性地转化为所述相应的二酮，并回收所述二酮。
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公开(公告)号：US4654427A
公开(公告)日：1987-03-31
申请号：US804132
申请日：1985-12-06
IPC分类号： B01J31/22 , C07D301/19 , C07F11/00
CPC分类号： C07D301/19 , B01J31/2208 , B01J31/2226 , B01J2231/72 , B01J2531/64
摘要： Storage stable solutions of molybdenum/alkanol complexes in the alkanol are prepared by reacting a molybdenum oxide and ammonium hydroxide and an amount of a straight chain or branched chain C.sub.6 -C.sub.13 alkanol, within the range of about 10 to about 55 moles of alkanol per gram atom of molybdenum sufficient to form a storage stable molybdenum/alkanol complex. The complex-forming reaction is initiated in the presence of about 1 to about 4 moles of water per gram atom of molybdenum and about 0.5 to about 10 moles of ammonia per gram atom of molybdenum, the water and ammonia preferably being added in the form of concentrated ammonium hydroxide. The reaction is conducted at a temperature of about 120.degree. to about 190.degree. C. for a period of time, normally about 3 to about 8 hours, sufficient to substantially completely remove ammonia and water to provide a liquid reaction product comprising said solution of molybdenum/alkanol complex dissolved in unreacted alkanol and containing about 0.001 to about 0.1 wt. % of water. The reaction product is filtered to provide a clarified storage stable solution of the molybdenum/alkanol complex having a dissolved molybdenum content of about 3 to about 10.5 wt. %.
摘要翻译： 钼/烷醇配合物在烷醇中的储存稳定溶液是通过使氧化钼和氢氧化铵与一定量的直链或支链C 6 -C 13烷醇在约10-约55摩尔的链烷醇/克 足以形成储存稳定的钼/烷醇络合物的钼原子。 在约1至约4摩尔水/克原子钼和约0.5至约10摩尔氨/克原子钼的存在下引发络合物形成反应，优选以水和氨的形式加入水和氨 浓氢氧化铵。 反应在约120℃至约190℃的温度下进行一段时间，通常约3至约8小时，足以基本上完全除去氨和水，以提供包含所述钼溶液的液体反应产物 /链烷醇络合物溶解在未反应的链烷醇中并含有约0.001至约0.1wt。 ％的水。 将反应产物过滤以提供溶解的钼含量为约3至约10.5重量％的钼/烷醇络合物的澄清储存稳定溶液。 ％。
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公开(公告)号：US4556730A
公开(公告)日：1985-12-03
申请号：US423413
申请日：1982-09-24
CPC分类号： C07C69/16 , C07C69/013 , C07C2102/42
摘要： Novel compounds made from the reaction of 5-vinyl-2-norbornene with carboxylic acid anhydrides in the presence of oxygen are described. The process to make these novel esters is preferably conducted at a temperature in the range from about 50.degree. to 150.degree. C. and in the presence of a catalyst. A transition metal borate catalyst is preferred. Such ester compounds are potentially useful plasticizers, lubricants, solvents and fuel additives.
摘要翻译： 描述了在氧存在下由5-乙烯基-2-降冰片烯与羧酸酐反应制备的新型化合物。 制备这些新型酯的方法优选在约50-150℃的温度和催化剂存在下进行。 过渡金属硼酸盐催化剂是优选的。 这种酯化合物是潜在有用的增塑剂，润滑剂，溶剂和燃料添加剂。
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公开(公告)号：US4554364A
公开(公告)日：1985-11-19
申请号：US683547
申请日：1984-12-19
IPC分类号： C07D317/20 , C07D317/00
CPC分类号： C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of tert-butyl hydroperoxide and a cobalt initiator, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes and only minimal amounts of the undesired methyl formate by-product. 2-Hydroxymethyl-1,3-dioxolane is hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译： 根据本发明令人惊奇地发现，当1,3-二氧戊环与甲醛在叔丁基过氧化氢和钴引发剂的存在下反应时，反应优先包括向2-亚甲基基团加入甲醛 的1,3-二氧戊环，与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1,3-二氧戊环，仅含有 最少量的不需要的甲酸甲酯副产物。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基甲基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。
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