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公开(公告)号：US4554364A
公开(公告)日：1985-11-19
申请号：US683547
申请日：1984-12-19
IPC分类号： C07D317/20 , C07D317/00
CPC分类号： C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of tert-butyl hydroperoxide and a cobalt initiator, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes and only minimal amounts of the undesired methyl formate by-product. 2-Hydroxymethyl-1,3-dioxolane is hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译： 根据本发明令人惊奇地发现，当1,3-二氧戊环与甲醛在叔丁基过氧化氢和钴引发剂的存在下反应时，反应优先包括向2-亚甲基基团加入甲醛 的1,3-二氧戊环，与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1,3-二氧戊环，仅含有 最少量的不需要的甲酸甲酯副产物。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基甲基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。
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2.发明授权Production of 2-substituted-1,3-dioxolanes from 1,3-dioxolane and formaldehyde 失效由1,3-二氧戊环和甲醛生产2-取代-1,3-二氧戊环
公开(公告)号：US4628108A
公开(公告)日：1986-12-09
申请号：US683548
申请日：1984-12-19
IPC分类号： C07D317/20 , C07D317/22 , C07D317/00
CPC分类号： C07D317/22 , C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of an organic peroxide and an ionizable, at least sparingly soluble metal salt, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes. 2-Hydroxyalkyl-1,3-dioxolanes are hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译： 根据本发明令人惊奇地发现，当1,3-二氧戊环与有机过氧化物和可电离的至少微溶的金属盐存在下，甲醛反应时，反应优先包括将甲醛加入到 1,3-二氧戊环的2-亚甲基与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1， 3-二氧戊环。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基烷基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。
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公开(公告)号：US4602102A
公开(公告)日：1986-07-22
申请号：US683546
申请日：1984-12-19
IPC分类号： C07C69/675
CPC分类号： C07C69/675
摘要： It has been surprisingly discovered in accordance with the present invention that when dimethoxymethane is reacted with formaldehyde in the presence of an organic peroxide, the reaction preferentially involves an addition of the formaldehyde to the dimethoxymethane to provide a reaction product containing alkyl glycolates such as methyl glycolate and ethyl glycolate as principle products of the reaction. The alkyl glycolates are useful as raw materials for the manufacture of ethylene glycol.
摘要翻译： 根据本发明令人惊奇地发现，当二甲氧基甲烷在有机过氧化物的存在下与甲醛反应时，反应优先包括向二甲氧基甲烷中加入甲醛，以提供含有乙醇酸烷基酯如乙醇酸甲酯的反应产物 和乙醇酸乙酯作为反应的主要产物。 乙醇酸烷基酯可用作制备乙二醇的原料。
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公开(公告)号：US4550184A
公开(公告)日：1985-10-29
申请号：US683441
申请日：1984-12-19
IPC分类号： C07D317/20 , C07D317/00
CPC分类号： C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of an organic peroxide, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxymethyl-1,3-dioxolane. 2-Hydroxymethyl-1,3-dioxolane is hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译： 根据本发明已经令人惊奇地发现，当1,3-二氧戊环与甲醛在有机过氧化物存在下反应时，反应优先包括将甲醛加入到1,3-二氧戊环的2-亚甲基中 二氧杂环戊烷与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟甲基-1,3-二氧戊环。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基甲基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。
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公开(公告)号：US4579978A
公开(公告)日：1986-04-01
申请号：US670102
申请日：1984-11-13
申请人： Jiang-Jen Lin , John R. Sanderson
发明人： Jiang-Jen Lin , John R. Sanderson
IPC分类号： C07C409/08 , C07D301/19 , C07C179/035
CPC分类号： C07D301/19 , C07C407/00 , C07C409/08
摘要： Substantially quantitative yields of bibenzyl hydroperoxide and bibenzyl dihydroperoxide can be obtained when oxygen is reacted with bibenzyl (1,2-diphenylethane) in the presence of a minor amount of sodium bicarbonate at a temperature within the range of about 100.degree. to about 160.degree. C. to provide an oxidation product wherein the bibenzyl is substantially selectively converted to the bibenzyl hydroperoxides. The bibenzyl hydroperoxides can be used as raw materials for the production of propylene oxide by reacting the bibenzyl hydroperoxides with propylene.
摘要翻译： 在少量碳酸氢钠存在下，在约100至约160℃的温度范围内，当与二苄基（1,2-二苯基乙烷）反应时，可以获得过氧化二苄苯基和联苄基二氢过氧化物的基本定量产率 以提供氧化产物，其中联苄基本上选择性地转化为联苯氢过氧化物。 苄基氢过氧化物可以用作通过使苄基氢过氧化物与丙烯反应生产环氧丙烷的原料。
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6.发明授权Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a copper-boron-silver catalyst 失效在铜 - 硼 - 银催化剂存在下通过共氧化同时制备环氧化物和羧酸
公开(公告)号：US4483998A
公开(公告)日：1984-11-20
申请号：US484058
申请日：1983-04-11
IPC分类号： B01J23/89 , C07C51/235 , C07D301/06 , C07D303/04
CPC分类号： B01J23/8926 , C07C51/235 , C07D301/06 , C07D303/04
摘要： A process for simultaneously producing an epoxide and a carboxylic acid from an olefin and an aldehyde, respectively, by co-oxidation over a catalyst in the presence of oxygen is described. The catalyst is made by precipitating silver oxide in the presence of copper(II) oxide, copper(II) borate or a mixture thereof. These novel heterogeneous catalysts provide higher selectivities to the epoxide than those obtainable with commercial catalysts.
摘要翻译： 描述了通过在氧气存在下通过催化剂共氧化同时由烯烃和醛生成环氧化物和羧酸的方法。 催化剂通过在氧化铜（II），硼酸铜（II）或其混合物的存在下沉淀氧化银来制备。 这些新型的非均相催化剂提供了比用商业催化剂获得的更高的选择性。
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7.发明授权
公开(公告)号：US4803305A
公开(公告)日：1989-02-07
申请号：US125965
申请日：1987-11-27
IPC分类号： B01J31/04 , B01J31/22 , C07C29/50 , C07C45/33 , C07C409/04 , C07C179/025 , C07C31/12
CPC分类号： C07C409/04 , B01J31/2226 , C07C29/50 , C07C407/00 , C07C45/33 , B01J2231/70 , B01J2531/0216 , B01J2531/842 , Y02P20/52
摘要： The oxidation of isobutane in the presence of a novel, soluble catalyst of the formula Fe.sub.3 O(Pivalate).sub.6 (MeOH).sub.3 Cl is disclosed. Tertiary-Butyl alcohol, tertiary-butyl hydroperoxide, and acetone are produced. A significant increase in isobutane conversion is obtained without a large decrease in selectivity to tertiary-butyl alcohol and tertiary-butyl hydroperoxide using a small amount of catalyst. Tertiary-butyl alcohol is useful as a gasoline additive and tertiary-butyl hydroperoxide is used for the production of propylene oxide. Acetone has a variety of uses as well.
摘要翻译： 公开了在式Fe 3 O（新戊酸酯）6（MeOH）3Cl）的新型可溶性催化剂存在下异丁烷的氧化。 制备叔丁醇，叔丁基过氧化氢和丙酮。 在使用少量催化剂的叔丁醇和叔丁基过氧化氢的选择性没有大的降低的情况下，异丁烷转化率显着增加。 叔丁醇可用作汽油添加剂，叔丁基过氧化氢用于生产环氧丙烷。 丙酮也有各种用途。
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8.发明授权Synthesis of substituted dioxolanes by direct oxidation of olefins over molybdenum 8-hydroxyquinoline 失效通过在钼上羟基喹啉直接氧化烯烃来合成取代的二氧戊环
公开(公告)号：US4526992A
公开(公告)日：1985-07-02
申请号：US662316
申请日：1984-10-18
申请人： Jiang-Jen Lin , John R. Sanderson
发明人： Jiang-Jen Lin , John R. Sanderson
IPC分类号： C07D215/30 , C07D317/12 , C07F11/00 , C07D317/00
CPC分类号： C07D215/30 , C07D317/12 , C07F11/005
摘要： The synthesis of substituted dioxolanes by direct oxidation of olefins over a molybdenum 8-hydroxyquinoline catalyst in the presence of water is described. An organic solvent such as chlorobenzene may also be employed. Water is essential to the reaction to make the dioxolanes, otherwise olefin oxides are produced. Hence, 4-methyl-1,3-dioxolane and 2,4-dimethyl-1,3-dioxolane were prepared from propylene oxidation, and three isomers of 2,4,5-trimethyl-1,3-dioxolane were prepared from 2-butene oxidation.
摘要翻译： 描述了通过在水存在下在钼8-羟基喹啉催化剂上直接氧化烯烃的取代的二氧戊环的合成。 还可以使用有机溶剂如氯苯。 水是制备二氧戊环的反应所必需的，否则产生烯烃氧化物。 因此，由丙烯氧化制备4-甲基-1,3-二氧戊环和2,4-二甲基-1,3-二氧戊环，由2,5-二甲基-1,3-二氧戊环制备2,4,5-三甲基-1,3-二氧戊环的三种异构体 丁烯氧化。
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公开(公告)号：US20170191651A1
公开(公告)日：2017-07-06
申请号：US15353700
申请日：2016-11-16
CPC分类号： F21V31/005 , F21V3/06 , F21V9/30 , F21V15/00 , F21V15/01 , F21V19/005 , F21V23/001 , F21V29/85 , F21Y2115/10
摘要： Lighting devices using selectively permeable barrier elements, graphite sheet materials, and/or browning agent destroyers/sequestering agents are disclosed. In one embodiment a lighting device may include a body or housing with a selectively permeable barrier element, such as a silicone membrane or o-ring to allow diffusion of contaminants from one or more interior volumes to the exterior environment. Contaminants may be mitigated through use of a sequestering agent/browning agent destroyer. Heat conduction between elements of the housing, such as to aid removal of heat generated from a lighting element such as an LED, may be improved through use of graphite materials, such as PGS sheets between housing elements.
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公开(公告)号：US07954913B2
公开(公告)日：2011-06-07
申请号：US11822940
申请日：2007-07-11
申请人： Kory A. Gunnerson , Kristen K. Hedstrom , Mark E. Palm , John R. Sanderson , Rodney M. Welch , Kurt W. Wight
发明人： Kory A. Gunnerson , Kristen K. Hedstrom , Mark E. Palm , John R. Sanderson , Rodney M. Welch , Kurt W. Wight
CPC分类号： A47L15/4251 , A47L15/0084
摘要： A support frame for a drawer-type dishwasher includes a top section and opposing side sections formed from a plurality of support members which define an open lattice work and establish a cavity for a slidable dishwasher drawer. The support frame also includes first and second rail supports that are provided on respective ones of the opposing side sections. The first and second rail supports are designed to support corresponding first and second extensible rails which, in turn, support the wash tub for movement relative to the frame. In addition, the support frame includes lid support elements for a mechanism that provides shifting of a lid member relative to the wash tub.
摘要翻译： 用于抽屉式洗碗机的支撑框架包括顶部部分和由多个支撑部件形成的相对的侧部部分，所述多个支撑部件限定开放的格栅工作并建立用于可滑动洗碗机抽屉的空腔。 支撑框架还包括设置在相对侧面部分中的相应侧面上的第一和第二轨道支撑件。 第一和第二轨道支撑件被设计成支撑相应的第一和第二可伸展轨道，而这些轨道又支撑洗涤桶以相对于框架移动。 此外，支撑框架包括用于提供盖构件相对于洗涤桶的移位的机构的盖支撑元件。
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