摘要:
A window comprising at least one thermochromic layer and a film comprising multiple layers of polymer with alternating refractive index (MLARI). The thermochromic layer has a reversible change in absorbance of electromagnetic radiation such that the absorbance increases as the temperature of the thermochromic layer increases and the absorbance decreases as the temperature of the thermochromic layer decreases. Particularly useful thermochromic materials are ligand exchange thermochromic materials. In various embodiments, the window may have multiple panes and may incorporate a low-e layer.
摘要:
An energy efficient, thermochromic device that may be used to allow sunlight or solar radiation into a building or structure when sunlight is absent or at high sun angles and substantially blocks solar radiation when sunlight is directly on the window.
摘要:
An electrochromic variable reflectance mirror for a vehicle includes a front element having a rear surface with a first layer of electrically conductive material disposed thereon, and a rear element having a front surface with a second layer of electrically conductive material disposed thereon. An electrical conductor may be provided to electrically couple a portion of the first conductive layer with a portion of the second conductive layer. At least one of the first and second conductive layers may be separated into a first portion and a second portion that is electrically isolated from the first portion and is in electrical contact with an electrochromic material disposed between the elements. A seal is provided to sealably bond the elements together in a spaced-apart relationship. The seal may have at least one electrically conductive region.
摘要:
Electrochromic windows and panels are provided which have first and second spaced elements that are optically transparent to visible light. The first and second elements each have first and second sides, and the windows and panels define a sealed chamber disposed between the second side of the first element and the first side of the second element. The sealed chamber is filled with an electrochromic medium, and the transmission of visible light through the electrochromic medium is variable when an electrical potential is applied to electrically conductive coatings that are provided on the second side of the first element and the first side of the second element. A layer partially transmissive of visible light and partially reflective of visible light is provided on one of the sides of the first or second elements so that the application of electrical potential to the electrochromic medium causes variations in the visible light transmitted through the partially visible light transmissive and partially visible light reflective layer and through the electrochromic medium whereby privacy and changes in visible color of the electrochromic medium may be either enhanced in one embodiment of the invention or hidden in another embodiment of the invention.
摘要:
Single-compartment, self-erasing, solution-phase electrochromic devices, solutions of electrochromic compounds for use as media of variable transmittance in such devices, and electrochromic compounds for such solutions are provided. The devices of the invention are surprisingly stable to cycling between light and dark states, have continuously variable transmittance to light as a function of electrical potential applied across the solution in a device, and have transmittance that can be varied over more than a factor of 10, from clear to dark or from dark to clear, in several seconds. Thus, the devices are especially suitable as variable transmittance components of variable transmission light filters, including windows, and variable reflectance mirrors, including anti-glare rearview mirrors in automobiles. Also provided are improved variable reflectance mirrors, wherein transmittance of reflected light is varied by thermochromic, photochromic or electro-optic means and wherein the reduction in transmittance which is required to eliminate perceptible reflection of an object to the eyes of an observer is reduced by disposing the plane of the highly reflective surface of the mirror at an angle with respect to the plane of the surface through which light from the object enters the mirror.
摘要:
Electrochromic compounds capable of reversibly attenuating the transmittance of the near infrared portion of the electromagnetic spectrum are provided. These compounds exhibit an energy difference between the singly occupied molecular orbital (SOMO) energy and the highest doubly occupied molecular orbital (HDOMO) energy (ESOMO−EHDOMO) of less than about 3.6 eV. In addition, these compounds have a transition moment of the configuration made up of the HDOMO and SOMO that is “long axis polarized”.
摘要:
An electrochromic mirror is disclosed for use in a vehicle rearview mirror assembly having a light source positioned behind the electrochromic mirror for selectively projecting light through the mirror. The electrochromic mirror includes front and rear spaced elements each having front and rear surfaces and being sealably bonded together in a spaced-apart relationship to define a chamber, a layer of transparent conductive material disposed on the rear surface of the front element, at least one solution-phase electrochromic material contained within the chamber, and a second electrode overlying the front surface of the rear element in contact with the electrochromic material. The second electrode includes a layer of reflective material and a coating of electrically conductive material that is at least partially transmissive and is disposed over substantially all of the front surface of the rear element. The second electrode further includes a region in front of the light source that is at least partially transmissive. The electrically conductive coating may include a single transparent layer or a plurality of partially reflective and transmissive layers, or an electrically conductive dichroic coating. The light source may be an information display, such as a compass/temperature display as used in an inside rearview mirror, or may be a signal light as used in an outside rearview mirror.
摘要:
Prismatic variable reflectance mirrors are provided. In the mirrors of the invention, transmittance of reflected light is varied by thermochromic, electrochromic, photochromic or electro-optic means and the reduction in transmittance, which is required to eliminate perceptible reflection of an object to the eyes of an observer, is reduced by disposing the plane of the highly reflective surface of the mirror at an angle with respect to the plane of the surface through which light from the object enters the mirror.
摘要:
The present invention provides solutions of certain 4,4'-bipyridinium salts, such as salts of 1,1'- dibenzyl-2,2',6,6'-tetraalkyl-4,4'-bipyridinium cations. The solutions of the invention are employed as solutions of variable transmittance in solution-phase electrochromic devices, including such devices that are single-compartment and self-erasing. In the solutions of the invention in such devices, the bipyridinium salts are cathodic electrochromic compounds, as reduction of a cation of such a salt causes its molar extinction coefficient at at least one wavelength in the visible range to increase markedly. Electrochromic devices, in which solutions of the invention provide variable transmittance, are, in turn, components of variable transmittance in display devices, windows and other types of light filters, and variable reflectance mirrors, such as those that can be used as dimmable rearview mirrors in motor vehicles.
摘要:
The present invention provides variable reflectance mirrors wherein the component of variable transmittance is a single-compartment, self-erasing, solution-phase electrochromic device.