摘要:
A flexible electrophotographic imaging member comprising a substrate and at least one imaging layer comprising a first charge transport material, free of long chain alkyl ester groups or long chain alkyl carboxyl groups, and a small amount of a different second charge transporting material containing only one long chain alkyl ester group dissolved or molecularly dispersed in a film forming binder, the at least one imaging layer having been formed by drying a coating comprising a solution of the first transporting material and second charge transporting material and the film forming polymer binder in a mixture of a low volatility solvent and a high volatility solvent. A method for fabricating this imaging member is also disclosed.
摘要:
A donor member, useful in ionographic or electrophotographic apparatuses and preferably useful in hybrid scavengeless development units, has a substrate and an oxidized transport coating thereover. The oxidized transport coating includes a polymer binder, charge transporting molecules and one or more oxidizing agents. The polymer binder of the donor roll coating preferably includes one of (1) a crosslinked polymer with charge transporting molecules dispersed therein, or (2) a crosslinked polyamide binder with hydroxy charge transport molecules dispersed therein. The donor roll is preferably included in a printing machine that develops latent images formed on a photoconductive member.
摘要:
A flexible electrostatographic imaging member including at least one photographic imaging layer, a support layer, and an anticurl back layer having an exposed surface including a cross linked polyamide at the exposed surface, the polyamide being, formed from a solution selected from the group including a first solution including crosslinkable alcohol soluble polyamide containing methoxy methyl groups attached to amide nitrogen atoms, an acid having a pKa less than about 3, a cross linking agent selected from the group including a formaldehyde generating cross linking agent, an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof, and a liquid selected from the group including alcohol solvents, diluent and mixtures thereof, a second solution including crosslinkable alcohol soluble polyamide free of methoxy methyl groups attached to amide nitrogen atoms, an acid having a pKa less than about 3, a cross linking agent selected from the group including a an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof, and a liquid selected from the group including alcohol solvents, diluent and mixtures thereof.
摘要:
An allyloxymethylatedpolyamide composition is disclosed, the allyloxymethylatedpolyamide being represented by Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andbetween 1 and 99 percent of the R.sub.2 sites are --H, and the remainder of the R.sub.2 sites is between 25 percent and 99 percent --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2, whereinw is 1, 2 or 3,between 1 and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5, andR.sub.5 is an alkyl unit containing 1 to 4 carbon atoms, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.3 and R.sub.4 sites are --H, and between 25 percent and 99 percent of the remainder of the R.sub.3 and R.sub.4 sites are --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2,whereinw is 1, 2 or 3, andbetween 1 percent and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5wherein R.sub.5 is an alkyl unit containing 1 to 4 carbon atoms.The allyloxymethylatedpolyamide may be synthesized by reacting an alcohol soluble polyamide with formaldehyde and an allylalcohol.The allyloxymethylatedpolyamide may be cross linked by a process selected from the group consisting of(a) heating an allyloxymethylatedpolyamide in the presence of a free radical catalyst, and(b) hydrosilation of the double bond of the allyloxy group of the allyloxymethylatedpolyamide with a silicon hydride reactant having at least 2 reactive sites.A preferred article includesa substrate,at least one photoconductive layer, andan overcoat layer comprisinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, anda cross linked allyloxymethylatedpolyamide film forming binder.A stabilizer may be added to the overcoat.
摘要:
An electrophotographic imaging member includinga substrate,a charge generating layer,a charge transport layer, andan overcoat layer includinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups,bis-(2-methyl-4-diethylaminophenyl)-phenylmethane anda cross linked polyamide film forming binder.A process for forming an overcoated imaging member is also disclosed.
摘要:
An electrophotographic imaging member including a substrate, a charge generating layer, and a charge transport layer including a hole transport host material, a trace amount of a shallow trap dopant having a shallow trap electrochemical oxidation potential between about 0.02 volt and about 1.5 volts lower than that of the hole transport host and a film forming binder.
摘要:
An electrophotographic imaging member comprising a substrate having an electrically conductive metal oxide surface, a hole blocking layer and at least one electrophotographic imaging layer, the hole blocking layer comprising a reaction product of(a) a material selected from the group consisting of a hydrolyzed organozirconium compound, a hydrolyzed organotitanium compound and mixtures thereof,(b) a hydroxyalkylcellulose,(c) a hydrolyzed organoaminosilane, and(d) the metal oxide surface.
摘要:
A composition is provided for coating a photoreceptor having a charge generating layer and a charge transport layer. The composition includes a hole transport material, a cross-linkable film forming binder having at least one functional group that is reactive with isocyanate, a blocked isocyanate cross-linking agent and a solvent having a boiling point equal to or below the deblocking temperature. The blocked isocyanate cross-linking agent is the reaction product of an isocyanate and a blocking agent, wherein the blocking agent has a boiling point temperature equal to or below a selected deblocking temperature to allow the isocyanate to form cross-links. The invention also provides an electrophotographic imaging member with an overcoat layer comprising a cross-linked film forming binder, an isocyanate compound, a hole transport material, and optionally a surface energy reducing agent. Processes for making the imaging members are also provided.
摘要:
An imaging member having a substrate, a charge transport layer having charge transport materials dispersed therein, and thereover, an overcoat layer comprising a deletion control agent.