公开(公告)号：US4211880A

公开(公告)日：1980-07-08

申请号：US965829

申请日：1978-12-04

申请人： Werner O. Haag ,  Darrell D. Whitehurst

发明人： Werner O. Haag ,  Darrell D. Whitehurst

IPC分类号： B01J31/08 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  B01J31/40 ,  C07C5/25 ,  C07C51/58 ,  C07C67/055 ,  C07C67/38 ,  C08F8/42 ,  C07C67/05 ,  B01J31/12

CPC分类号： C08F8/42 ,  B01J31/08 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/226 ,  B01J31/2404 ,  C07C5/2568 ,  C07C51/58 ,  C07C67/055 ,  C07C67/38 ,  B01J2231/12 ,  B01J2231/321 ,  B01J2231/52 ,  B01J2231/645 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/825 ,  B01J2531/845 ,  B01J2531/847 ,  B01J31/1895 ,  B01J31/4023 ,  Y02P20/584

摘要： This specification discloses an insoluble resin-metal compound complex, the method for its preparation, and its use in carrying out a catalyzed reaction. The complex is a weak base anion exchange resin which has been contacted with a solution of a coordination compound having at least two ligands connected to at least one central metal atom to bond chemically the resin to the metal atom by replacement of at least one of the ligands of the coordination compound by a functional group of the weak base anion exchange resin. The complex can be used as a catalyst for hydrogenation, carbon monoxide insertion, polymerization, isomerization, vinyl ester exchange, and ethylene oxidation reactions, among others.

摘要翻译： 该说明书公开了不溶性树脂 - 金属化合物络合物，其制备方法及其在进行催化反应中的用途。 络合物是弱碱阴离子交换树脂，其与具有至少两个与至少一个中心金属原子连接的配体的配位化合物的溶液接触，以通过将至少一种 通过弱碱阴离子交换树脂的官能团配位化合物的配位体。 该络合物可用作氢化，一氧化碳插入，聚合，异构化，乙烯基酯交换和乙烯氧化反应等的催化剂。

公开(公告)号：US4145486A

公开(公告)日：1979-03-20

申请号：US858228

申请日：1977-12-07

申请人： Werner O. Haag ,  Darrell D. Whitehurst

发明人： Werner O. Haag ,  Darrell D. Whitehurst

IPC分类号： B01J31/08 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  B01J31/40 ,  C08F4/00 ,  C08F4/06 ,  B01J31/06

CPC分类号： C08F4/00 ,  B01J31/08 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/226 ,  B01J31/2404 ,  B01J2231/12 ,  B01J2231/321 ,  B01J2231/645 ,  B01J2531/62 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/825 ,  B01J2531/847 ,  B01J31/1895 ,  B01J31/4023 ,  Y02P20/584

摘要： This specification discloses an insoluble resin-metal compound complex, the method for its preparation, and its use in carrying out a catalyzed reaction. The complex is a weak base anion exchange resin which has been contacted with a solution of a coordination compound having at least two ligands connected to at least one central metal atom to bond chemically the resin to the metal atom by replacement of at least one of the ligands of the coordination compound by a functional group of the weak base anion exchange resin. The complex can be used as a catalyst for hydrogenation, carbon monoxide insertion, polymerization, isomerization, vinyl ester exchange, and ethylene oxidation reactions, among others.

摘要翻译： 该说明书公开了不溶性树脂 - 金属化合物络合物，其制备方法及其在进行催化反应中的用途。 络合物是弱碱阴离子交换树脂，其与具有至少两个与至少一个中心金属原子连接的配体的配位化合物的溶液接触，以通过将至少一种 通过弱碱阴离子交换树脂的官能团配位化合物的配位体。 该络合物可用作氢化，一氧化碳插入，聚合，异构化，乙烯基酯交换和乙烯氧化反应等的催化剂。

公开(公告)号：US4098727A

公开(公告)日：1978-07-04

申请号：US107863

申请日：1971-01-19

申请人： Werner O. Haag ,  Darrell Duayne Whitehurst

发明人： Werner O. Haag ,  Darrell Duayne Whitehurst

IPC分类号： B01J31/08 ,  B01J31/10 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07C41/01 ,  C07C45/50 ,  C08F8/42 ,  C08F12/36

CPC分类号： B01J31/08 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/2404 ,  C07C29/16 ,  C07C45/50 ,  C08F8/42 ,  B01J2231/321 ,  B01J2531/822

摘要： This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a catalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table. The metal can be, for example, rhodium, cobalt, or ruthenium. The olefin can contain more than one carbon-to-carbon double bond, may be an open chain or a cyclic olefin, and may be substituted. Further, the olefin may be contained in a refinery stream such as a cracked gasoline. The reaction may be carried out in the presence of a polar solvent.

摘要翻译： 本说明书公开了一种通过使烯烃与氢和一氧化碳在作为催化剂的存在下，含有可以是胺的官能团的不溶性聚合物的反应来制备含氧化合物，更具体地说是醛和醇的方法， 硫醇，膦或胂基，化学键合元素周期表第VIII族金属。 金属可以是例如铑，钴或钌。 烯烃可以含有多于一个碳 - 碳双键，可以是开链或环烯烃，并且可以被取代。 此外，烯烃可以包含在炼油厂流中，例如裂化汽油。 该反应可以在极性溶剂的存在下进行。