Method for the processing of silver halide color photographic material
    61.
    发明授权
    Method for the processing of silver halide color photographic material 失效
    用于处理卤化银彩色照相材料的方法

    公开(公告)号:US5814436A

    公开(公告)日:1998-09-29

    申请号:US863931

    申请日:1997-05-27

    摘要: The present invention provides a processing method which allows a silver halide color photographic material to be sufficiently desilvered and minimizes the rise in the formation of bleaching fog or stain even when it is processed in a short period of time. A novel process for the processing of a silver halide color photographic material comprising at least silver halide emulsion layer on a support which comprises subjecting the silver halide color photographic material to color development, and then processing the silver halide color photographic material with a processing solution having a bleaching capacity is provided, characterized in that said emulsion layer comprises tabular silver halide grains having �100! major faces and a silver chloride content of 50 to 100 mol % and said processing solution having a bleaching capacity contains at least one ferric complex salt of a compound represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represent a hydrogen atom, aliphatic group, aromatic group or hydroxyl group; and W represents a divalent bridging group containing carbon atoms; and M.sub.1, M.sub.2, M.sub.3 and M.sub.4 each represent a hydrogen atom or cation. The total coated amount of silver in the silver halide color photographic material is in the range of 2.0 to 8.0 g/m.sup.2 per m.sup.2 of light-sensitive material. The compound represented by the general formula (I) comprises an �S,S! optical isomer as determined about the carbon atoms to which R.sub.1 and R.sub.4 are bonded in a proportion of not less than 70%.

    摘要翻译: 本发明提供一种能够使卤化银彩色照相材料充分脱壳并且即使在短时间内进行处理也能最大限度地减少漂白雾或污渍形成的上升的处理方法。 一种用于处理卤化银彩色照相材料的新方法,其至少包含在载体上的卤化银乳剂层,其包括使卤化银彩色照相材料经受着色显影,然后用具有 提供了漂白能力,其特征在于所述乳剂层包括具有[100]主面和氯化银含量为50-100mol%的片状卤化银颗粒,并且所述具有漂白能力的处理溶液含有至少一种铁配合盐 由以下通式(I)表示的化合物:ach表示氢原子,脂族基,芳基或羟基; W表示含有碳原子的二价桥基; 而M1,M2,M3和M4各自表示氢原子或阳离子。 卤化银彩色照相材料中银的总涂布量在每平方米感光材料2.0至8.0g / m2的范围内。 由通式(I)表示的化合物包含按照不少于70%的比例键合R1和R4的碳原子测定的[S,S]旋光异构体。

    Developing machine and developing method for color photography
    62.
    发明授权
    Developing machine and developing method for color photography 失效
    开发机器和彩色摄影的开发方法

    公开(公告)号:US5660973A

    公开(公告)日:1997-08-26

    申请号:US404584

    申请日:1995-03-15

    摘要: A developing machine having a high durability at a high temperature even in the presence of a high concentration of the developing agent is provided. The developing machine has means for keeping the temperature of a color developer having a concentration of an aromatic primary amine developing agent of 0.15 to 0.50 mol/l in the range of 40.degree. to 50.degree. C., and the material for at least one of the developing tanks and the racks is a resin selected from the group consisting of polyphenylene sulfide resin, polyphenylene oxide resin, polymethylpentene resin, polyether ether ketone resin, polyalkylene terephthalate resin, polyether imide resin, polyether sulfone resin and polysulfone resin.

    摘要翻译: 提供即使在高浓度的显影剂的存在下也能在高温下具有高耐久性的显影机。 显影机具有使具有浓度为0.15〜0.50mol / l的芳族伯胺显影剂的显色剂的温度保持在40〜50℃的范围的装置,并且将至少一种 显影槽和支架是选自聚苯硫醚树脂,聚苯醚树脂,聚甲基戊烯树脂,聚醚醚酮树脂,聚对苯二甲酸亚烷基酯树脂,聚醚酰亚胺树脂,聚醚砜树脂和聚砜树脂中的树脂。

    Color developer and processing method using the same
    63.
    发明授权
    Color developer and processing method using the same 失效
    彩色显影剂和加工方法使用相同

    公开(公告)号:US5607819A

    公开(公告)日:1997-03-04

    申请号:US321863

    申请日:1994-10-14

    摘要: There is disclosed a color developer and a method for processing a silver halide color photographic material using said color developer. The color developer comprises a thiourea compound represented by the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted cycloalkylene group, provided that two or more of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each do not represent a hydrogen atom at the same time; at least one pair of R.sub.1 and R.sub.3, and R.sub.2 and R.sub.4, together may bond to form a nitrogen-containing heterocyclic ring; or at least one pair of R.sub.1 and R.sub.2, and R.sub.3 and R.sub.4, together may bond to form a ring.

    摘要翻译: 公开了一种彩色显影剂和使用所述彩色显影剂处理卤化银彩色照相材料的方法。 彩色显影剂包括由式(I)表示的硫脲化合物:其中R 1,R 2,R 3和R 4各自表示氢原子,取代或未取代的烷基,取代或未取代的芳基 或者取代或未取代的亚环烷基,条件是R 1,R 2,R 3和R 4中的两个或多个各自不同时表示氢原子; 至少一对R 1和R 3以及R 2和R 4可以结合形成含氮杂环; 或至少一对R 1和R 2以及R 3和R 4可以结合形成环。

    Method for processing silver halide color photographic materials
    64.
    发明授权
    Method for processing silver halide color photographic materials 失效
    卤化银彩色照相材料的处理方法

    公开(公告)号:US5534394A

    公开(公告)日:1996-07-09

    申请号:US331876

    申请日:1994-11-01

    IPC分类号: G03C7/42

    CPC分类号: G03C7/421

    摘要: A method for processing a silver halide color photographic material with which edge staining and the occurrence of staining on aging after processing can be prevented, and with which the stability of the bleach-fixer can be improved, comprising color developing and bleach-fixing the photographic material, wherein the bleach-fixer contains (1) thiosulfate, (2) at least one type of compound selected from among the group of compounds represented by formulae (I) and (II): ##STR1## wherein Ra, Rb, R.sup.1 through R.sup.4, X.sup.1 and n are as defined in the specification, and (3) an adduct of bisulfite with at least one type of compound selected from among the group of compounds represented by formulae (A), (B), (C) and (D): ##STR2## wherein R.sub.1 through R.sub.11, X, Y, Z, m and n are as defined in the specification.

    摘要翻译: 一种用于处理卤化银彩色照相材料的方法,可以防止边缘染色和加工后的老化现象的发生,并且可以改善漂白定影剂的稳定性,包括彩色显影和漂白固定摄影 材料,其中漂白剂定影剂含有(1)硫代硫酸盐,(2)选自由式(I)和(II)表示的化合物组中的至少一种类型的化合物:(I)< IMAGE> II)其中Ra,Rb,R1至R4,X1和n如说明书中所定义,和(3)亚硫酸氢盐与至少一种选自式(A), (B),(C)和(D):其中R1至R11,X,Y,Z,m和n如说明书中所定义。

    Method of processing silver halide photographic material
    65.
    发明授权
    Method of processing silver halide photographic material 失效
    卤化银照相材料的处理方法

    公开(公告)号:US5466563A

    公开(公告)日:1995-11-14

    申请号:US798135

    申请日:1991-11-26

    IPC分类号: G03C5/395 G03C7/44 G03C5/31

    CPC分类号: G03C5/3958 G03C7/44

    摘要: A method of processing silver halide photographic material comprises the steps of passing a belt for conveying an imagewise exposed silver halide photographic material through the processing tanks, carrying the silver halide photographic material on the belt and processing the silver halide photographic material conveyed by the belt in the processing tanks while replenishing the tanks with constant amounts of replenishing solutions respectively, wherein the method comprises detecting a level of developing solution in development tank and supplying the development tank with an additional fresh developing tank solution or overflow solution from the development tank when said level of developing solution in the tank falls to a predetermined level. This method makes it possible to reduce an amount of the processing solution waste to be drained from the processing machine.

    摘要翻译: 一种处理卤化银照相材料的方法包括以下步骤:使用于传送成像曝光的卤化银照相材料的带通过处理槽,在该带上携带卤化银照相材料并处理由带传送的卤化银照相材料 处理罐,同时分别以恒定量的补充溶液补充罐,其中所述方法包括检测显影槽中的显影溶液的水平,并在显影槽中从所述显影槽向所述显影槽提供另外的新鲜显影槽溶液或溢出溶液时, 在罐中的显影溶液下降到预定水平。 该方法使得可以减少从处理机排出的处理溶液废物的量。

    Processing of silver halide color photographic material
    66.
    发明授权
    Processing of silver halide color photographic material 失效
    卤化银彩色照相材料的加工

    公开(公告)号:US5234801A

    公开(公告)日:1993-08-10

    申请号:US840585

    申请日:1992-02-26

    IPC分类号: G03C5/395 G03C7/44

    CPC分类号: G03C7/44 G03C5/3958

    摘要: A method for continuously processing an image-wise exposed silver halide color photographic material comprising the steps of color developing, bleach-fixing and at least one of washing with water and stabilizing. A replenisher is supplied to the bleach-fix bath to result in an overflow of from 30 to 500 ml/m.sup.2 of the photographic material processed. The bleach-fixing step further comprises collecting the bleach-fix overflow, regenerating the collected bleach-fix bath overflow by adding thereto a regenerant to produce a regenerated bleach-fix bath, and reusing the regenerated bleach-fix bath as a replenisher to the bleach-fix bath. The regeneration rate defined as the amount of bleach-fix overflow used for regeneration divided by the total amount of overflow multiplied by 100% is more than 80%. The photographic layers of the silver halide color photographic material have a degree of swelling of from about 2.5 to 4.0. The silver halide color photographic material further has a silver coverage of less than about 0.8 g/m.sup.2. The above described method solves problems of poor desilvering, inadequate color reproduction and undesirable cyan thermal discoloration which generally accompany reuse of the bleach-fixing bath.

    摘要翻译: 一种用于连续处理图像曝光的卤化银彩色照相材料的方法,包括彩色显影,漂白固定和至少一种用水洗涤和稳定化的步骤。 补充液被提供给漂白固定液,导致处理的照相材料溢出30至500ml / m 2。 漂白固定步骤还包括收集漂白剂固定溢流液,通过向其中加入再生剂再生所述收集的漂白固定液溢流,以产生再生漂白剂 - 固定浴,以及将再生漂白剂固定浴作为补充剂再次用于漂白剂 混合浴。 再生率定义为用于再生的漂白固定溢流量除以总溢出量乘以100%,超过80%。 卤化银彩色照相材料的照相层具有约2.5至4.0的溶胀度。 卤化银彩色照相材料还具有小于约0.8g / m 2的银覆盖。 上述方法解决了脱色不良,颜色再现不足和不期望的青色热变色的问题,通常伴随着漂白剂固定浴的再利用。

    Silicon substrate having porous oxidized silicon layers and its
production method
    67.
    发明授权
    Silicon substrate having porous oxidized silicon layers and its production method 失效
    具有多孔氧化硅层的硅衬底及其生产方法

    公开(公告)号:US5091061A

    公开(公告)日:1992-02-25

    申请号:US629857

    申请日:1990-12-18

    摘要: In the silicon substrate having porous oxidized silicon layers of this invention, which consists of a silicon substrate the one surface of which is dotted with porous oxidized silicon layers, the residual internal stress (compression stress) is dispersedly distributed in the porous oxidized silicon layers. Therefore, the entire silicon substrate having porous oxidized silicon layers of this invention is only minimally warped.Adopting a method for producing the silicon substrate of this invention which consists of covering with a mask the surface of a silicon substrate except its dotting areas to be treated, subjecting the silicon substrate to anodic formation in an aqueous hydrofluoric acid solution to form porous silicon layers in the areas to be treated and not covered with the mask and then oxidizing the formed porous silicon layers enables secured production of a silicon substrate dotted with porous oxidized silicon layers.

    摘要翻译: 在本发明的具有多孔氧化硅层的硅衬底中,其由一个表面以多孔氧化硅层为点的硅衬底组成,残留的内部应力(压缩应力)分散分布在多孔氧化硅层中。 因此,具有本发明的多孔氧化硅层的整个硅衬底仅被最小程度地翘曲。 采用本发明的硅基板的制造方法,该方法由掩模覆盖硅基板​​的除了其待处理区域之外的表面,使硅基板在氢氟酸水溶液中阳极形成以形成多孔硅层 在待处理的区域中并未被掩模覆盖,然后氧化所形成的多孔硅层,从而可以有效地生产以多孔氧化硅层为中心的硅衬底。

    Process for processing silver halide color photographic materials
    68.
    发明授权
    Process for processing silver halide color photographic materials 失效
    卤化银彩色照相材料加工工艺

    公开(公告)号:US5006438A

    公开(公告)日:1991-04-09

    申请号:US518266

    申请日:1990-05-03

    CPC分类号: G03C7/39208 G03C7/413

    摘要: A process for processing a silver halide color photographic material is disclosed which comprises processing a silver halide color photographic material containing at least one compound represented by formula (I) or (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, or a heterocyclic group; A represents a group forming a chemical bond by reaction with an aromatic primary amine color developing agent; n represents 0 or 1; X represents a group released on reaction with an aromatic primary amine color developing agent; B represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, or a sulfonyl group; and Y represents a group accelerating the addition of an aromatic primary amine color developing agent to the compound of formula (II), and said R.sub.1 and X or said Y and R.sub.2 or B may combine with each other to form a ring, with a color developer prepared by diluting a concentrated color developer composition containing from 90 ml/liter to 600 ml/liter of benzyl alcohol and from 0.07 mol/liter to 0.5 mol/liter of an aromatic primary amine color developing agent.

    Method for processing a silver halide photosensitive material for color
photography
    69.
    发明授权
    Method for processing a silver halide photosensitive material for color photography 失效
    用于处理用于彩色摄影的卤化银感光材料的方法

    公开(公告)号:US5004675A

    公开(公告)日:1991-04-02

    申请号:US416797

    申请日:1989-10-03

    摘要: A method for processing a silver halide color photosensitive material is disclosed.The process step comprises developing a color photographic light-sensitive material composed of a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide containing at least 80 mol % silver chloride; at least one emulsion layer thereof containing a dispersion of a mixture of (i) at least one oil-soluble non-diffusible cyan coupler capable of forming a substantially non-diffusible cyan dye by coupling with the oxidized form of a developing agent, and (ii) a water-insoluble polymer;in a color developer solution comprising a primary amine color developing agent, and having a chloride ion concentration of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l, and a bromide ion concentration of from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l.When used in rapid processing methods, the method according to the invention prevents pressure-sensitization fogging, and provides high maximum density and low minimum density images.

    摘要翻译: 公开了一种处理卤化银色感光材料的方法。 工艺步骤包括显影由其上具有至少一种含有至少80mol%氯化银的卤化银的感光卤化银乳剂层的载体组成的彩色照相感光材料; 其至少一个乳剂层含有(i)至少一种能够通过与显影剂的氧化形式偶联形成基本上不可扩散的青色染料的油溶性非扩散性青色成色剂的混合物的分散体,和 ii)水不溶性聚合物; 在包含伯胺显色剂的显色剂溶液中,并且氯离子浓度为3.5×10 -2至1.5×10 -1 mol / l,溴离子浓度为3.0×10-5至1.0×10-3 mol / l。 当用于快速加工方法时,根据本发明的方法防止增压雾化,并提供高的最大密度和低的最小密度的图像。

    Method for forming a direct positive color image
    70.
    发明授权
    Method for forming a direct positive color image 失效
    用于形成直接正彩色图像的方法

    公开(公告)号:US4956267A

    公开(公告)日:1990-09-11

    申请号:US200268

    申请日:1988-05-31

    IPC分类号: G03C1/485 G03C7/413

    CPC分类号: G03C7/413 G03C1/48538

    摘要: A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.