Composition and process for treating steel
    61.
    发明授权
    Composition and process for treating steel 失效
    钢的处理及组成

    公开(公告)号:US4486241A

    公开(公告)日:1984-12-04

    申请号:US410566

    申请日:1982-08-26

    申请人: John J. Donofrio

    发明人: John J. Donofrio

    摘要: Aqueous compositions and low temperature processes for treating clean steel and galvanized steel to provide a coating suitable for the application of paint thereto. The aqueous treating compositions contain:______________________________________ Ingredient Quantity ______________________________________ zinc ion from about 0.9 to about 2.5 g/l; nickel ion from about 0.6 to about 2.0 g/l; orthophosphoric acid from about 15 to about 45 g/l; nitrate ion from about 1.0 to about 10.0 g/l. ______________________________________ The pH of the composition is adjusted to 3.0-3.5 by addition of alkali metal hydroxide. The above composition is used on clean galvanized steel. For clean ungalvanized steel, from about 0.10 to about 0.65 g/l of nitrite ion is included in the composition. Optional ingredients in the above compositions include chlorate ion, ferric ion, and a fluoride compound.The invention also relates to a metal activating composition comprising an aqueous colloidal solution of manganese ion and a titanium compound.

    摘要翻译: 用于处理清洁钢和镀锌钢的水性组合物和低温方法以提供适用于涂料的涂层。 含水处理组合物含有: - 约0.9至约2.5g / l的成分量 - 锌离子; 从约0.6至约2.0g / l的镍离子; - 普磷酸约15至约45g / l; 硝酸根离子为约1.0至约10.0g / l。 - 通过加入碱金属氢氧化物将组合物的pH调节至3.0-3.5。 上述组合物用于清洁镀锌钢板上。 对于清洁的非镀锌钢,组合物中包括约0.10至约0.65g / l的亚硝酸根离子。 上述组合物中的任选成分包括氯酸根离子,三价铁离子和氟化合物。 本发明还涉及包含锰离子的水性胶体溶液和钛化合物的金属活化组合物。

    Method of treating metal surfaces prior to phosphatization
    62.
    发明授权
    Method of treating metal surfaces prior to phosphatization 失效
    在磷化之前处理金属表面的方法

    公开(公告)号:US4384900A

    公开(公告)日:1983-05-24

    申请号:US219245

    申请日:1980-12-22

    CPC分类号: C23C22/78 C23C22/80

    摘要: This invention is directed to a method for treating metal surfaces. More particularly, this invention is directed to an improved method for cleaning, scouring, and activating metal surfaces prior to phosphatization, which comprises contacting said metal surfaces with an aqueous solution comprising primary and/or secondary alkali metal or ammonium salts of orthophosphates and conventional metal cleaning components, the solution having a pH value of from about 6.3 to 8.2, said pH being lower than the pH value of solutions of the corresponding secondary orthophosphates alone having the same concentration; and containing optionally condensed phosphates in an amount corresponding to the amount necessary to soften the water hardness of the water used.

    摘要翻译: 本发明涉及一种处理金属表面的方法。 更具体地,本发明涉及一种用于在磷酸化之前清洁,冲洗和活化金属表面的改进方法,其包括使所述金属表面与包含正磷酸盐和常规金属的伯和/或次级碱金属或铵盐的水溶液接触 所述溶液的pH值为约6.3至8.2,所述pH低于单独具有相同浓度的相应的次级正磷酸盐的溶液的pH值; 并含有相当于软化所用水的水硬度所需的量的任选缩合的磷酸盐。

    Method of preparing titanium-containing phosphate conditioner for metal
surfaces
    63.
    发明授权
    Method of preparing titanium-containing phosphate conditioner for metal surfaces 失效
    制备金属表面的含钛磷酸盐调理剂的方法

    公开(公告)号:US4152176A

    公开(公告)日:1979-05-01

    申请号:US931373

    申请日:1978-08-07

    申请人: Donald J. Guhde

    发明人: Donald J. Guhde

    IPC分类号: C23C22/80 C23F7/08

    CPC分类号: C23C22/80

    摘要: The present invention relates to an improved method of preparing titanium-containing phosphate conditioners useful in cleaning and activating the surface of ferrous, zinc or aluminum metal and alloys thereof for subsequent reaction with phosphate coating solutions. The method comprises the steps of(a) preparing a mixture consisting essentially of water, sodium tripolyphosphate, disodium phosphate and a titanium-containing compound and(b) adding said mixture to solid disodium phosphate with mixing whereby a solid titanium phosphate composition is obtained.The invention provides a method for forming a dry activating composition which does not require the application of any energy such as heat to the material. When the solid titanium phosphate compound is dissolved in water to form pretreatment solutions it can be employed successfully for activating metal surfaces in preparation for reaction with phosphate coating solutions.

    摘要翻译: 本发明涉及一种制备含钛磷酸盐调理剂的改进方法,其用于清洗和活化含铁,锌或铝金属的表面及其合金,用于随后与磷酸盐涂层溶液的反应。 该方法包括以下步骤:(A)制备水性,三磷酸钠,磷酸二氢钠和含钛化合物的混合物的混合物,(B)将固体磷酸二氢钾与混合物溶解,得到固体磷酸氢钙组合物。

    Cleaning of metals with compositions containing alkali metal silicate and chloride
    64.
    发明授权
    Cleaning of metals with compositions containing alkali metal silicate and chloride 失效
    含有碱金属硅酸盐和氯化物的组合物的金属清洁

    公开(公告)号:US3847663A

    公开(公告)日:1974-11-12

    申请号:US27325372

    申请日:1972-07-19

    申请人: LUBRIZOL CORP

    发明人: SHUMAKER G

    IPC分类号: C23C22/80 C23G1/14

    CPC分类号: C23C22/80 C23G1/14

    摘要: Metal surfaces are cleaned, prior to phosphating or the like, with compositions containing alkali metal (especially sodium) silicates and chlorides, and preferably also containing surfactants and chelating agents. These compositions have cleaning power comparable to phosphate-containing cleaners and cause less water pollution upon discharge into natural waterways.

    摘要翻译: 金属表面在磷化等之前用包含碱金属(特别是钠)硅酸盐和氯化物的组合物进行清洁,并且优选还含有表面活性剂和螯合剂。 这些组合物具有与含磷酸盐清洁剂相当的清洁能力,并且在排入自然水路时引起较少的水污染。

    Systems and methods for maintaining pretreatment baths

    公开(公告)号:US11566330B2

    公开(公告)日:2023-01-31

    申请号:US16385173

    申请日:2019-04-16

    IPC分类号: C23C22/80 B32B15/01 C23C22/05

    摘要: Disclosed is a system for maintaining a pretreatment bath containing a pretreatment comprising a Group IVB metal. The system comprises an aqueous reducing agent comprising a metal cation and a latent source of sulfate which, upon reaction with a contaminant in the pretreatment bath, forms a metal sulfate. The contaminant comprises a nitrite source. The metal sulfate salt has a pKsp of 4.5 to 11 at a temperature of 25° C. Also disclosed is a method for maintaining a pretreatment bath containing a pretreatment composition comprising a Group IVB metal. The method comprises supplying the reducing agent to the pretreatment bath in an amount sufficient to reduce a pollution ratio of the pretreatment bath to less than 1:1. Also disclosed are substrates with a pretreatment bath maintained according to the system and method.