公开(公告)号：US11518960B2

公开(公告)日：2022-12-06

申请号：US15685241

申请日：2017-08-24

申请人： PPG Industries Ohio, Inc.

发明人： Mark W. McMillen ,  Steven J. Lemon ,  Kevin T. Sylvester ,  Justin J. Martin ,  Michel Sudour

IPC分类号： C11D9/06 ,  C11D3/06 ,  C23G1/14 ,  C23C22/80 ,  C23C22/36 ,  C23C22/73 ,  C23C22/83 ,  C23C22/60 ,  C23C22/34 ,  C23C22/18 ,  C23C22/78 ,  C23G1/20 ,  C11D3/00 ,  C25D5/34

摘要： The present invention is directed towards an aqueous alkaline cleaner composition comprising: an iron cation, a molybdenum cation, a cobalt cation, or combinations thereof; and an alkaline component; wherein the pH of the aqueous alkaline composition is at least 10, and the aqueous alkaline composition includes no more than 50 ppm of phosphate. Also disclosed are treatment systems comprising an aqueous alkaline composition for treating at least a portion of a substrate, and a pretreatment composition for treating at least a portion of a substrate. Also disclosed are substrates treated according to the disclosed treatment systems.

公开(公告)号：US11441226B2

公开(公告)日：2022-09-13

申请号：US16312908

申请日：2017-06-21

申请人： CHEMETALL GMBH

发明人： Stefan Birkenheuer ,  Carina Hecker ,  Oliver Sauer ,  Daniel Schatz

IPC分类号： C23C22/34 ,  C23C22/80 ,  C23C22/78

摘要： Described herein is an improved process for an anticorrosion pretreatment of a metallic surface including steel, galvanized steel, aluminum, magnesium and/or a zinc-magnesium alloy, wherein the metallic surface is brought into contact with an aqueous composition A including a) from 0.01 to 0.5 g/l of a copolymer and the metallic surface is brought into contact with an acidic aqueous composition B including b1) a compound selected from the group consisting of titanium, zirconium and hafnium compounds, wherein the metallic surface is brought into contact i) firstly with the composition A and then with the composition B, ii) firstly with the composition B and then with the composition A and/or iii) simultaneously with the composition A and the composition B.
Also described herein is a corresponding aqueous composition A, an aqueous concentrate for producing this composition, a correspondingly coated metallic surface and a method of using a correspondingly coated metallic substrate.

公开(公告)号：US20200332420A1

公开(公告)日：2020-10-22

申请号：US16385173

申请日：2019-04-16

申请人： PPG Industries Ohio, Inc.

发明人： Kevin T. Sylvester ,  Nathan J. Silvernail

IPC分类号： C23C22/80 ,  B32B15/01

摘要： Disclosed is a system for maintaining a pretreatment bath containing a pretreatment comprising a Group IVB metal. The system comprises an aqueous reducing agent comprising a metal cation and a latent source of sulfate which, upon reaction with a contaminant in the pretreatment bath, forms a metal sulfate. The contaminant comprises a nitrite source. The metal sulfate salt has a pKsp of 4.5 to 11 at a temperature of 25° C. Also disclosed is a method for maintaining a pretreatment bath containing a pretreatment composition comprising a Group IVB metal. The method comprises supplying the reducing agent to the pretreatment bath in an amount sufficient to reduce a pollution ratio of the pretreatment bath to less than 1:1. Also disclosed are substrates with a pretreatment bath maintained according to the system and method.

公开(公告)号：US10378120B2

公开(公告)日：2019-08-13

申请号：US14353164

申请日：2012-10-23

申请人： Chemetall GmbH

发明人： Thomas Kolberg ,  Peter Schubach ,  Manfred Walter ,  Carola Komp ,  Michael Dröge

IPC分类号： C25D5/34 ,  C25D5/36 ,  C25D5/44 ,  C25D13/20 ,  C23C22/78 ,  C23C22/80 ,  C23C22/34 ,  C23C22/83 ,  C23C18/12

摘要： A method for coating metallic surfaces with aqueous compositions, wherein a silane-based aqueous composition containing at least one silane and/or a related silicon-containing compound and optionally additional components is treated further, for example, at temperatures above 70° C., in a pretreatment step without drying the coating, by using at least one aqueous rinse step after this pretreatment step and then performing an electrodeposition coating, in which at least one surfactant is added at least in the last rinse step of the aqueous rinse steps. Coated metallic surfaces are also described.

公开(公告)号：US10113070B2

公开(公告)日：2018-10-30

申请号：US14931913

申请日：2015-11-04

申请人： PPG Industries Ohio, Inc.

发明人： Adam Kolcun ,  Richard M. Vargas ,  Kevin T. Sylvester ,  Nathan J. Silvernail ,  John F. McIntyre

IPC分类号： C09D5/10 ,  C23C22/80

摘要： Disclosed is a pretreatment composition containing (a) a Group IIIB metal, a Group IVB metal, or combinations thereof; and (b) a compound containing at least six phosphorus-containing acid groups or salts thereof; wherein the molar ratio of (a) to (b) is at least 3:1. Also disclosed are methods of treating a substrate with the pretreatment composition and substrates treated with the pretreatment composition.

公开(公告)号：US09515316B2

公开(公告)日：2016-12-06

申请号：US14396128

申请日：2013-04-22

申请人： SHOWA DENKO K.K.

发明人： Hitoshi Yokouchi ,  Masahiro Ohmori ,  Chiaki Sotowa ,  Masayuki Sanbayashi

IPC分类号： H01M4/36 ,  H01M4/485 ,  C23C22/82 ,  C23C22/23 ,  C23C22/80 ,  C23C22/77 ,  H01M4/131 ,  H01M4/04 ,  H01M4/1391 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/58 ,  H01M4/66 ,  H01M10/0525 ,  H01M4/02

CPC分类号： H01M4/366 ,  C23C22/23 ,  C23C22/77 ,  C23C22/80 ,  C23C22/82 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/5825 ,  H01M4/661 ,  H01M10/0525 ,  H01M2004/027 ,  Y02E60/122 ,  Y02P70/54

摘要： This method for producing an anode active material for a secondary battery is provided with a step for forming titanium dioxide by means of hydrolysis by adding a titanium-containing compound to an acidic aqueous solution, and furthermore, by means of adding a compound containing an alkaline earth metal and a condensed phosphate, the surface of the titanium dioxide is covered by the condensed phosphate containing the alkaline earth metal in a manner so that the amount of elemental phosphorus atoms and the amount of alkaline earth metal are each in the range of 0.1 to 10 mass % with respect to the mass of titanium dioxide, thus synthesizing the anode active material (12).

摘要翻译： 该二次电池用负极活性物质的制造方法具有通过向酸性水溶液中添加含钛化合物而进行水解而形成二氧化钛的工序，此外，通过添加含有碱的化合物 土金属和缩合磷酸盐，二氧化钛的表面被含有碱土金属的缩合磷酸盐覆盖，使得元素磷原子的量和碱土金属的量各自在0.1〜 相对于二氧化钛的质量为10质量％，从而合成阳极活性物质（12）。

公开(公告)号：US20100243465A1

公开(公告)日：2010-09-30

申请号：US12679048

申请日：2008-09-26

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C23C22/80 ,  B05D3/10

CPC分类号： C23C22/361 ,  C09D5/4488 ,  C23C22/34 ,  C23C22/83 ,  C23C2222/20 ,  C25D13/04

摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.

摘要翻译： 一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对所述金属材料 已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

公开(公告)号：US5776265A

公开(公告)日：1998-07-07

申请号：US624623

申请日：1996-04-26

申请人： Linda S. Kramer ,  Robin M. Dunn ,  Terrence R. Giles ,  Robert W. Miller

发明人： Linda S. Kramer ,  Robin M. Dunn ,  Terrence R. Giles ,  Robert W. Miller

IPC分类号： C23C22/80

CPC分类号： C23C22/80

摘要： The invention is a process for applying a phosphate coating to a metal substrate in which the metal substrate is contacted with an aqueous activating bath before the phosphate coating is applied. The improved process is obtained by applying ultrasonic vibration energy to the aqueous activating bath. The ultrasonic energy can be applied to the aqueous activating bath when the aqueous activating bath is in contact with the metal substrate or when the metal substrate is not in contact with the aqueous activating bath.

摘要翻译： PCT No.PCT / US93 / 10243 Sec。 371日期：1996年4月26日 102（e）日期1996年4月26日PCT提交1993年10月26日PCT公布。 出版物WO95 / 12011 日期1995年5月4日本发明是在施加磷酸盐涂层之前将磷酸盐涂层施加到金属基底上的方法，其中金属基底与水性活化浴接触。 通过将超声波振动能量施加到水性活化浴来获得改进的方法。 当水性活化浴与金属基底接触时或当金属基底不与水性活化浴接触时，超声能量可以施加到水性活化浴。

公开(公告)号：US5326408A

公开(公告)日：1994-07-05

申请号：US77473

申请日：1993-06-15

申请人： Gerald J. Cormier

发明人： Gerald J. Cormier

IPC分类号： C23C22/80 ,  C23G1/14 ,  C23C22/05 ,  C23C22/78

CPC分类号： C23C22/80

摘要： An otherwise conventional Jernstedt salt dispersion for activating metal surfaces to improve the quality of subsequently deposited phosphate conversion coatings on the activated metal surface is stabilized against deterioration in storage for at least six months by utilizing in the dispersion a mixture of sodium and potassium salts, preferably condensed phosphate salts, in such amounts that the ratio of potassium to titanium is within the range from 8.0:1.0 to 40:1.0 and the ratio of potassium to sodium is within the range from 0.9:1.0 to about 2.5:1.0.

摘要翻译： 用于活化金属表面以改善随后沉积的磷酸盐转化涂层在活化金属表面上的质量的另外常规的杰恩斯台德盐分散体通过在分散体中使用钠盐和钾盐的混合物而优选地储存至少六个月，以防止其劣化 缩合磷酸盐，其量使得钾与钛的比率在8.0:1.0至40:1.0的范围内，并且钾与钠的比率在0.9:1.0至约2.5:1.0的范围内。

公开(公告)号：US5112395A

公开(公告)日：1992-05-12

申请号：US674260

申请日：1991-03-25

申请人： Toan M. Ngo

发明人： Toan M. Ngo

IPC分类号： C23C22/80

CPC分类号： C23C22/80

摘要： Compositions and process for activating metal surfaces prior to coating with zinc phosphate are disclosed. A Jernstedt salt concentrate is provided which can be employed to prepare Jernstedt salt baths of the type desired by combining the concentrate with additional alkali metal phosphate. Improved activation of metal surfaces are achieved by incorporating a chloride ion producing compound in the activating bath.

摘要翻译： 公开了在用磷酸锌包被之前活化金属表面的组合物和方法。 提供了一种Jernstedt盐浓缩物，其可用于通过将浓缩物与另外的碱金属磷酸盐组合来制备所需类型的Jernstedt盐浴。 通过在活化浴中加入氯化物离子产生化合物来实现金属表面的活化。