公开(公告)号：US11548266B2

公开(公告)日：2023-01-10

申请号：US16824101

申请日：2020-03-19

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Charlene Marie Smith

IPC: B32B17/06 ,  B32B7/023 ,  C03B17/06 ,  C03C21/00

Abstract: Scratch and damage resistant laminated glass articles are disclosed. According to one aspect, a laminated glass article may include a glass core layer formed from an ion exchangeable core glass composition and includes a core glass elastic modulus EC and at least one glass clad layer fused directly to the glass core layer. The at least one glass clad layer may be formed from an ion exchangeable clad glass composition different than the ion exchangeable core glass composition and includes a clad glass elastic modulus ECL. The laminated glass article may have a total thickness T and the at least one glass clad layer may have a thickness TCL that is less than 30% of the total thickness T. EC may be at least 5% greater than ECL.

公开(公告)号：US20220396522A1

公开(公告)日：2022-12-15

申请号：US17838335

申请日：2022-06-13

Applicant: CORNING INCORPORATED

Inventor： Emily Marie Aaldenberg ,  Timothy Michael Gross

IPC: C03C21/00 ,  C03C17/02 ,  B32B17/06 ,  B32B37/06

Abstract: A method of manufacturing a strengthened glass article includes forming a glass-to-glass laminate by fusing clad and core glasses, where the clad has greater high-temperature coefficient of thermal expansion (HTCTE) than the core but a lesser low-temperature coefficient of thermal expansion (LTCTE). The method includes cooling the laminate to impart stresses through contraction mismatch between the clad and core, where stresses in the laminate from HTCTE differences at least partially offset stresses in the laminate from LTCTE. After the cooling, the method includes modifying geometry of the laminate, then relaxing at least some of the stresses in the glass-to-glass laminate from differences in the HTCTE.

公开(公告)号：US20220340476A1

公开(公告)日：2022-10-27

申请号：US17620809

申请日：2020-06-10

Applicant: Corning Incorporated

Inventor： Timothy Michael Gross ,  Alexandra Lai Ching Kao Andrews Mitchell

IPC: C03C3/078

Abstract: An alkali-free glass including greater than or equal to 65.0 mol % SiO2, mol % RO/mol % Al2O3 less than 0.7 (where RO can include divalent oxides MgO, CaO, SrO, BaO, or combinations thereof), RO less than or equal to 14 mol %, and the absolute value of a slope dE/dTf of a line extending between a first endpoint and a second endpoint less than or equal to 10.0221 GPa/° C. The first endpoint is a Young's modulus at a fictive temperature of the annealing point temperature and the second endpoint is a Young's modulus at a fictive temperature of the strain point temperature, and the slope is a change in Young's modulus (GPa) per 1° C. change in fictive temperature. RO is a total amount of alkali earth metal oxides. A glass article is also disclosed.

公开(公告)号：US20220324202A1

公开(公告)日：2022-10-13

申请号：US17838757

申请日：2022-06-13

Applicant: CORNING INCORPORATED

Inventor： Theresa Chang ,  Polly Wanda Chu ,  Patrick Joseph Cimo ,  Adam James Ellison ,  Timothy Michael Gross ,  Guangli Hu ,  Nicholas James Smith ,  Butchi Reddy Vaddi ,  Natesan Venkataraman

IPC: B32B17/10 ,  C03C21/00 ,  H05K1/02 ,  H05K1/03 ,  C03C17/32 ,  B32B27/36 ,  C03C17/30 ,  C03C15/00 ,  G06F1/16 ,  B32B17/06 ,  C03C3/091 ,  B32B7/12 ,  B32B37/12 ,  B32B37/16 ,  H05K3/46

Abstract: A glass element having a thickness from 25 μm to 125 μm, a first primary surface, a second primary surface, and a compressive stress region extending from the first primary surface to a first depth, the region defined by a compressive stress GI of at least about 100 MPa at the first primary surface. Further, the glass element has a stress profile such that it does not fail when it is subject to 200,000 cycles of bending to a target bend radius of from 1 mm to 20 mm, by the parallel plate method. Still further, the glass element has a puncture resistance of greater than about 1.5 kgf when the first primary surface of the glass element is loaded with a tungsten carbide ball having a diameter of 1.5 mm.

公开(公告)号：US20220298055A1

公开(公告)日：2022-09-22

申请号：US17616727

申请日：2020-06-03

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Alexandra Lai Ching Kao Andrews Mitchell

IPC: C03C3/087 ,  C03C3/097 ,  C03C3/093 ,  C03C3/085

Abstract: A glass composition and substrate are provided. The glass substrate can include about 50 to about 80 mole percent of SiO2; about 1 to about 30 mole percent of Al2O3; 0 to about 30 mole percent of B2O3; about 1.0 to about 10.1 mole percent of P2O5; and about 10.5 to about 15.7 mole percent of SrO, BaO, K2O, or a combination thereof, and wherein the composition includes less than about 5 mole percent of ZnO, MgO, CaO, or a combination thereof. A device incorporating the glass substrate is also provided.

公开(公告)号：US20220250967A1

公开(公告)日：2022-08-11

申请号：US17618644

申请日：2020-06-04

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Alexandra Lai Ching Kao Andrews Mitchell

IPC: C03C3/095

Abstract: A glass substrate includes about 45 mol % to about 70 mol % SiO2, about 15 mol % to about 30 mol % Al2O3, about 7 mol % to about 20 mol % of Y2O3, and optionally 0 mol % to about 9 mol % of La2O3. The glass substrate has high modulus and fracture toughness.

公开(公告)号：US20220240517A1

公开(公告)日：2022-08-04

申请号：US17722688

申请日：2022-04-18

Applicant: CORNING INCORPORATED

Inventor： Dana Craig Bookbinder ,  Gary Stephen Calabrese ,  Timothy Michael Gross ,  Dayue Jiang ,  Jianguo Wang

IPC: A01N59/20 ,  C03C3/091 ,  C03C3/064 ,  A01N59/00 ,  A01N25/00 ,  C03C3/093 ,  C03C4/00 ,  C03B19/10 ,  A01N25/10 ,  C03B37/01 ,  C03C10/00 ,  C03C3/083 ,  C03C3/066 ,  A01N59/06 ,  A01N59/16 ,  A01N59/26 ,  A01N59/14 ,  C03C3/097 ,  C03C3/085 ,  A01N59/08 ,  C03C3/062 ,  C03C12/00 ,  C03C3/089 ,  A01N25/08 ,  A01N25/34 ,  C03C4/02

Abstract: Embodiments of the present invention pertain to antimicrobial glass compositions, glasses and articles. The articles include a glass, which may include a glass phase and a cuprite phase. In other embodiments, the glasses include as plurality of Cu1+ ions, a degradable phase including B2O3, P2O5 and K2O and a durable phase including SiO2. Other embodiments include glasses having a plurality of Cu1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The article may also include a polymer. The glasses and articles disclosed herein exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomomas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

公开(公告)号：US20210380470A1

公开(公告)日：2021-12-09

申请号：US17411464

申请日：2021-08-25

Applicant: CORNING INCORPORATED

Inventor： Dana Craig Bookbinder ,  Timothy Michael Gross ,  Marcel Potuzak

IPC: C03C3/097 ,  C03C3/064 ,  C03C21/00 ,  C03C3/062

Abstract: Glasses comprising SiO2, Al2O3, and P2O5 that are capable of chemical strengthened by ion exchange and having high damage resistance. These phosphate-containing glasses have a structure in which silica (SiO2) is replaced by aluminum phosphate (AlPO4) and/or boron phosphate (BPO4).

公开(公告)号：US20210355023A1

公开(公告)日：2021-11-18

申请号：US17327870

申请日：2021-05-24

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Jingshi Wu

IPC: C03C3/097 ,  C03C21/00 ,  H05K5/00 ,  H05K5/03

Abstract: Glass-based articles that include a compressive stress layer extending from a surface of the glass-based article to a depth of compression are formed by exposing glass-based substrates to water vapor containing environments. The glass-based substrates have compositions selected to be fusion formable, to be steam strengthen able, and to avoid the formation of platinum defects during the forming process. The methods of forming the glass-based articles may include elevated pressures and/or multiple exposures to water vapor containing environments.

公开(公告)号：US11104602B2

公开(公告)日：2021-08-31

申请号：US15191961

申请日：2016-06-24

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross

IPC: C03C3/097 ,  H05K5/00 ,  H05K5/03 ,  C03C4/18 ,  B32B17/06 ,  C03C21/00 ,  B32B9/04 ,  B32B7/12 ,  B32B27/36

Abstract: Embodiments of alkali aluminosilicate glass articles that may be chemically strengthened to achieve a maximum surface compressive stress that exceeds compressive stresses that have been achieved in similar glasses are disclosed. In one or more embodiments, the fictive temperature of these glass articles may be equal to the 1011 poise (P) viscosity temperature of the glass article. In some embodiments, the strengthened alkali aluminosilicate glass articles described herein may exhibit a maximum compressive stress of at least about 400 MPa, 800 MPa, 930 MPa or 1050 MPa. In some embodiments, the strengthened alkali aluminosilicate glass articles described herein may exhibit a compressive stress layer extending to a depth of layer of at least about 40 μm (in samples having a thickness of 1 mm). In still other embodiments, these strengthened alkali aluminosilicate glass articles exhibit a parabolic or near-parabolic tensile stress profile in the central region of the glass articles.