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公开(公告)号：US4963112A
公开(公告)日：1990-10-16
申请号：US340003
申请日：1989-04-06
摘要： A method of producing a spark plug for internal combustion engines comprising arranging a metal piece formed of a noble material on an end face of at least one metal electrode of the spark plug and directing laser beams onto an outer surface of the metal piece facing the spark gap to form an alloy zone between the one metal electrode and a wear-resistant layer facing the spark gap, the alloy zone consisting of materials of the metal electrode and the metal piece with the proportion of the material of the metal electrode continuously decreasing from an area abutting the metal electrode and consisting only of the metal electrode material, to an area abutting the wear-resistant layer which consists only of the material of the metal piece.
摘要翻译： PCT No.PCT / DE88 / 00435 Sec。 371日期：1989年4月6日 102（e）日期1989年4月6日PCT Filed 1988年7月14日PCT公布。 出版物WO89 / 01717 日本特开1989年2月23日。一种内燃机用火花塞的制造方法，其特征在于，在火花塞的至少一个金属电极的端面上配置由贵金属构成的金属片，将激光束导向外表面 所述金属片面向所述火花隙以在所述一个金属电极和面向所述火花隙的耐磨层之间形成合金区，所述合金区由所述金属电极和所述金属片的材料构成，所述合金区的材料的比例 金属电极从与金属电极邻接的仅由金属电极材料构成的区域连续地减小到仅由金属片的材料构成的耐磨层的区域。
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公开(公告)号：US4939409A
公开(公告)日：1990-07-03
申请号：US290168
申请日：1988-12-07
IPC分类号： H01T13/52
CPC分类号： H01T13/52
摘要： A spark plug with a surface discharge section for internal combustion engines comprising an insulation body having an inner cavity for receiving a mass of an electrically conductive material, and a bore extending from the inner cavity and through which extends a central electrode which is formed integral with the surface discharge surface, is made of an electrically non-conductive material, and has on an outer surface thereof in the area of the mass and the bore an electrically conductive film, and, in the area defining the surface discharge section a film having no intrinsic conductivity after sintering.
摘要翻译： PCT No.PCT / DE87 / 00235 Sec。 371日期：1988年12月7日 102（e）日期1988年12月7日PCT提交1987年5月23日PCT公布。 出版物WO87 / 07778 日本1987年12月17日。一种具有用于内燃机的表面放电部分的火花塞，包括具有用于接纳大量导电材料的内腔的绝缘体和从内腔延伸的孔， 与表面放电表面一体形成的中心电极由不导电材料制成，并且在其外表面上具有导电膜，并且在限定 表面放电部分是烧结后没有固有导电性的膜。
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公开(公告)号：US4532492A
公开(公告)日：1985-07-30
申请号：US620717
申请日：1984-06-14
IPC分类号： G01N27/12
CPC分类号： G01N27/12
摘要： To simplify manufacture and assembly of a temperature-compensated titanium dioxide oxygen sensor, the sensor (9, 9') is applied as a layer on the thermistor body (1), with an electrode (8) interposed; preferably, the thermistor body is densely sintered titanium dioxide, in the form of a closed tube (1, 1') which may have a central opening (FIG. 1: 2) therethrough, with the sensor body being porous titanium dioxide and located either on the inside (FIG. 1) surface of the thermistor body (1) or on the outside (FIG. 2) surface, and supported by the thermistor body, which forms the substrate and support surface for the sensor body.
摘要翻译： 为了简化温度补偿二氧化钛氧传感器的制造和组装，将传感器（9,9'）作为层施加在热敏电阻体（1）上，其中插入电极（8）; 优选地，热敏电阻体是致密烧结的二氧化钛，其形式为密封管（1,1'），其可以具有穿过其的中心开口（图1：2），传感器体是多孔二氧化钛，并且位于 在热敏电阻体（1）的内部（图1）表面或外部（图2）表面上，由形成基板的热敏电阻体和传感器体的支撑面支撑。
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公开(公告)号：US4406968A
公开(公告)日：1983-09-27
申请号：US297353
申请日：1981-08-28
摘要： A sparkplug for internal combustion engines which has a central electrode extending to the ignition end. The central electrode has an electrically non-conductive core pin with an electrically conductive outer layer on the cylindrical surface of the core pin. The central electrode is positioned in the lengthwise bore of the sparkplug insulator portion, preferably without any clearance between the insulator and the ignition end portion of the central electrode. The core pin is preferably made of a material which has shrinkage characteristics and a thermal coefficient of expansion substantially the same as those of the insulator. Most preferably the same material is used for both components. The electrically conductive coating layer of the central electrode is preferably a conductive metal-ceramic mixture. The coating layer may be in the form of a resistance element and/or contain a pre-ignition discharge gap. The sparkplug may also be formed with a recessed electrically conductive coating portion of the central electrode to form a surface gap sparkplug.
摘要翻译： 用于内燃机的火花塞，其具有延伸到点火端的中心电极。 中心电极具有在芯销的圆柱形表面上具有导电外层的非导电芯销。 中心电极定位在火花塞绝缘体部分的纵向孔中，优选地在绝缘体和中心电极的点火端部之间没有任何间隙。 芯销优选由具有收缩特性和与绝缘体基本上相同的热膨胀系数的材料制成。 最优选地，相同的材料用于两种组分。 中心电极的导电涂层优选为导电金属 - 陶瓷混合物。 涂层可以是电阻元件的形式和/或包含预点火放电间隙。 火花塞也可以形成有中心电极的凹入的导电涂覆部分，以形成表面间隙火花塞。
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公开(公告)号：US4339320A
公开(公告)日：1982-07-13
申请号：US193944
申请日：1980-10-06
IPC分类号： G01N27/409 , G01N27/14 , G01N27/406 , G01N27/407 , G01N27/416 , G01N27/48 , G01N27/46
CPC分类号： G01N27/4077 , G01N27/4067
摘要： To permit efficient heat transfer from a carrier tube (22) surrounding a tubular solid electrolyte body (11') having outer and inner electrodes (14, 18) applied thereto, the tubular heater element carrier body (22) supports a wire or resistance track heating element (25) at the inner surface thereof, the heater element (25) being spaced from the outer surface of the solid electrolyte tube (11') forming part of the sensor element (11) by a distance at the most of 1 mm, preferably less than 0.5 mm, the wall thickness of the heater element carrier tube (22) preferably being between 0.3 and 0.8 mm thick, the carrier tube being made of ceramic, such as aluminum oxide, or internally insulated metal.
摘要翻译： 为了允许从其上施加有外部和内部电极（14,18）的管状固体电解质体（11'）周围的载体管（22）进行有效的热传递，管状加热器元件载体主体（22）支撑线或阻力轨道 所述加热元件（25）在其内表面处与所述固体电解质管（11'）的外表面间隔开所述传感器元件（11）的一部分距离最大为1mm ，优选小于0.5mm，加热器载体管（22）的壁厚优选为0.3至0.8mm厚，载体管由陶瓷制成，例如氧化铝或内部绝缘金属。
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76.发明授权
公开(公告)号：US4292158A
公开(公告)日：1981-09-29
申请号：US157303
申请日：1980-06-09
申请人： Klaus Muller , Helmut Maurer , Hermann Dietz , Karl-Hermann Friese , Wolfgang Leibfried , Gunther Stecher , Ernst Linder
发明人： Klaus Muller , Helmut Maurer , Hermann Dietz , Karl-Hermann Friese , Wolfgang Leibfried , Gunther Stecher , Ernst Linder
IPC分类号： G01N27/41 , G01N27/407 , G01N27/413 , G01N27/416 , G01N27/48 , G01N33/00 , G01N27/58
CPC分类号： G01N27/4075 , G01N27/4072 , G01N27/48 , G01N33/0011
摘要： To simplify manufacture and provide a polarographic sensor of high response speed, operating according to the current limiting principle, an oxygen molecule migration barrier is provided leading to the cathode by separating the cathode from the space where the gas to be tested exists by a wall through which a hole is provided which extends therethrough to a small space immediately above the cathode defined by support elements placed immediately on the cathode. The hole, or a plurality of holes, is so dimensioned that the diameter thereof, with respect to its length, is small, with diameters of between 0.01 to 0.06 mm and a length of at least about 1 mm being suitable.
摘要翻译： 为了简化制造并提供具有高响应速度的极谱传感器，根据电流限制原理进行操作，通过将阴极从被测试气体存在的空间通过壁穿过而分离出阴极，从而提供氧分子迁移屏障 其中提供了一个孔，其延伸穿过其中直接位于阴极正上方的支撑元件限定的阴极正上方的小空间。 孔或多个孔的尺寸被设计成使得其直径相对于其长度小，直径在0.01至0.06mm之间，长度至少约1mm是合适的。
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公开(公告)号：US4221650A
公开(公告)日：1980-09-09
申请号：US910385
申请日：1978-05-30
IPC分类号： C04B35/48 , C04B14/32 , C04B35/119 , C04B35/488 , G01N27/12 , G01N27/407 , G01N27/409 , G01N27/413 , H01M8/1253 , G01N27/58
CPC分类号： G01N27/4073 , C04B35/119 , C04B35/4885 , H01M8/1253 , Y02E60/525 , Y02P70/56
摘要： Oxygen sensors having a fine-grained stabilized cubic zirconium dioxide electrolyte contact respective electrodes. The zirconium dioxide contains between 15% and 50% by volume of Al.sub.2 O.sub.3 in a crystalline state and has good mechanical and thermal properties. The oxygen sensor may have a composite zirconium dioxide solid electrolyte element. The invention also includes a wider range of related Al.sub.2 O.sub.3 - containing stabilized cubic zirconium dioxides containing between about 8% and 85% by volume Al.sub.2 O.sub.3. The invention further provides methods of manufacturing such Al.sub.2 O.sub.3 - containing zirconium dioxide and for manufacturing oxygen sensors.
摘要翻译： 具有细粒度稳定的立方二氧化锆电解质的氧传感器与相应的电极接触。 二氧化锆在结晶状态下含有15体积％至50体积％的Al 2 O 3，具有良好的机械和热性能。 氧传感器可以具有复合二氧化锆固体电解质元件。 本发明还包括含有约8％至85％（体积）Al 2 O 3的更广泛的相关的含Al 2 O 3的稳定的立方二氧化锆。 本发明还提供制造这种含Al 2 O 3的二氧化锆和用于制造氧传感器的方法。
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78.发明授权Stabilized zirconium dioxide compositions and oxygen sensors utilizing said compositions 失效使用所述组合物的稳定二氧化锆组合物和氧传感器
公开(公告)号：US4183798A
公开(公告)日：1980-01-15
申请号：US888161
申请日：1978-03-20
IPC分类号： C04B35/48 , C04B35/486 , G01N27/58
CPC分类号： C04B35/486
摘要： Stabilized zirconium dioxide compositions sintered with a silicate flux and stabilized with (i) calcium oxide and (ii) magnesium oxide. The stabilized zirconium dioxide can be sintered at temperatures between 1460.degree. C. and 1480.degree. C. to form solids having high mechanical strength and a specific resistance of 1M.OMEGA.cm at a low temperature. The invention also provides oxygen sensors containing at least one measuring cell which is an oxygen concentration cell having two electrodes separated by and in ionic communication through a solid stabilized zirconium dioxide electrolyte which is prepared from the said compositions.
摘要翻译： 稳定的二氧化锆组合物用硅酸盐助熔剂烧结并用（i）氧化钙和（ii）氧化镁稳定化。 稳定的二氧化锆可以在1460℃和1480℃之间的温度下烧结，以在低温下形成具有高机械强度和1MΩEGAcm电阻率的固体。 本发明还提供了含有至少一个测量池的氧传感器，该测量池是具有通过由所述组合物制备的固体稳定的二氧化锆电解质分离和离子连通的两个电极的氧浓度池。
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