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公开(公告)号：US4221650A
公开(公告)日：1980-09-09
申请号：US910385
申请日：1978-05-30
IPC分类号： C04B35/48 , C04B14/32 , C04B35/119 , C04B35/488 , G01N27/12 , G01N27/407 , G01N27/409 , G01N27/413 , H01M8/1253 , G01N27/58
CPC分类号： G01N27/4073 , C04B35/119 , C04B35/4885 , H01M8/1253 , Y02E60/525 , Y02P70/56
摘要： Oxygen sensors having a fine-grained stabilized cubic zirconium dioxide electrolyte contact respective electrodes. The zirconium dioxide contains between 15% and 50% by volume of Al.sub.2 O.sub.3 in a crystalline state and has good mechanical and thermal properties. The oxygen sensor may have a composite zirconium dioxide solid electrolyte element. The invention also includes a wider range of related Al.sub.2 O.sub.3 - containing stabilized cubic zirconium dioxides containing between about 8% and 85% by volume Al.sub.2 O.sub.3. The invention further provides methods of manufacturing such Al.sub.2 O.sub.3 - containing zirconium dioxide and for manufacturing oxygen sensors.
摘要翻译： 具有细粒度稳定的立方二氧化锆电解质的氧传感器与相应的电极接触。 二氧化锆在结晶状态下含有15体积％至50体积％的Al 2 O 3，具有良好的机械和热性能。 氧传感器可以具有复合二氧化锆固体电解质元件。 本发明还包括含有约8％至85％（体积）Al 2 O 3的更广泛的相关的含Al 2 O 3的稳定的立方二氧化锆。 本发明还提供制造这种含Al 2 O 3的二氧化锆和用于制造氧传感器的方法。
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公开(公告)号：US5773894A
公开(公告)日：1998-06-30
申请号：US769182
申请日：1996-12-18
IPC分类号： B32B18/00 , G01N27/406 , G01N27/407 , H01B3/12 , C04B35/48
CPC分类号： G01N27/407 , B32B18/00 , C04B37/001 , C04B37/021 , G01N27/4067 , G01N27/4071 , G01N27/4075 , H01B3/12 , C04B2237/064 , C04B2237/068 , C04B2237/32 , C04B2237/341 , C04B2237/343 , C04B2237/348 , C04B2237/40 , C04B2237/401 , C04B2237/68 , C04B2237/704 , C04B2237/708 , C04B2237/72 , C04B2237/76 , C04B2237/86
摘要： An insulation layer system, in particular for gas sensors, is proposed, having at least one electrically conductive solid-electrolyte layer (10), an electrically conductive layer (20) and at least one electrically insulating layer (13) between the solid-electrolyte layer (10) and the electrically conductive layer (20). The material of the insulating layer (13) contains, prior to sintering, pentavalent metal oxides of niobium or tantalum as an additive, it being possible for the additive to diffuse into the adjoining solid-electrolyte layer (10) during sintering.
摘要翻译： 提出了一种特别用于气体传感器的绝缘层系统，其具有至少一个导电固体电解质层（10），导电层（20）和固体电解质之间的至少一个电绝缘层（13） 层（10）和导电层（20）。 绝缘层（13）的材料在烧结之前含有铌或钽的五价金属氧化物作为添加剂，在烧结期间添加剂可能扩散到相邻的固体电解质层（10）中。
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公开(公告)号：US06408680B1
公开(公告)日：2002-06-25
申请号：US09171717
申请日：1999-04-08
IPC分类号： G01N2712
摘要： A sensor for determining an oxygen content in an exhaust gas of an internal combustion engine includes a receptacle, arranged in a longitudinal bore of a metal housing, for a sensing element. The sensing element is received in the receptacle in a gas-tight fashion via a sensing element seal, which includes a glass seal. The receptacle has a measured-gas-side ceramic shaped element and a connector-side ceramic shaped element, which are arranged axially one behind the other. A cavity into which the glass seal is pressed while hot is configured between the two ceramic shaped elements.
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公开(公告)号：US6164120A
公开(公告)日：2000-12-26
申请号：US171688
申请日：1999-02-22
IPC分类号： G01N27/409 , G01N27/12 , G01N27/407
CPC分类号： G01N27/4078 , G01N27/407
摘要： A sensor for determining an oxygen level in an exhaust gas of an internal combustion engine includes a receptacle arranged in a longitudinal bore of a metallic enclosure for a sensor element. The sensor element is accommodated in a gas-tight manner using a sensor element seal. The receptacle has a measured gas-side ceramic molded component and a connection-side ceramic molded component, which are arranged one behind the other axially. A hollow space is formed between the measured gas-side ceramic molded component and the connection-side ceramic molded component, in which a metallic sealing element is hot-pressed.
摘要翻译： PCT No.PCT / DE97 / 02916 Sec。 一九九九年二月二十二日 102（e）1999年2月22日PCT 1997年12月16日PCT公布。 第WO98 / 38500号公报 日期1998年9月3日用于确定内燃机排气中的氧气含量的传感器包括布置在用于传感器元件的金属外壳的纵向孔中的容器。 使用传感器元件密封件以气密方式容纳传感器元件。 容器具有一个沿轴向布置的测量气体侧陶瓷成型部件和连接侧陶瓷成形部件。 在被测量的气体侧陶瓷成型部件和连接侧陶瓷成型部件之间形成中空空间，其中金属密封元件被热压。
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公开(公告)号：US5030602A
公开(公告)日：1991-07-09
申请号：US381716
申请日：1989-02-27
申请人： Thomas Frey , Karl-Hermann Friese , Heinz Geier
发明人： Thomas Frey , Karl-Hermann Friese , Heinz Geier
IPC分类号： C04B35/10 , C04B35/111
CPC分类号： C04B35/111
摘要： A ceramic consisting substantially of Al.sub.2 O.sub.3 as ceramic support, ceramic cover layer and/or ceramic supporting structure for heating conductors is described, which is electrochemically stable, which, in other words, does not decompose on application of a heating voltage, even in long-term operation at temperatures above 600.degree.. Such a ceramic exhibits a very small alkali metal content, of less than 0.2% by weight Na.sub.2 O and K.sub.2 O respectively. Particularly favorable processing, in particular pressing properties are exhibited by such a ceramic if it has 2.5 to 10% by weight of barium silicate or strontium silicate fluxes, the proportions of Na.sub.2 O, K.sub.2 O, CaO and MgO together make up less than 1% by weight, and the BaO or SrO:SiO.sub.2 molar ratio is between 2:1 and 1:12.5. Such a ceramic with a BaO:SiO.sub.2 ratio of 2.6:1 parts by weight is electrochemically stable up to approximately 1400.degree. C., and at 1300.degree. C. still exhibits a bending strength of approximately 300 N/mm.sup.2.
摘要翻译： PCT No.PCT / DE87 / 00285 Sec。 371日期1989年2月27日 102（e）日期1989年2月27日PCT Filed 1987年6月24日PCT公布。 出版物WO88 / 01610 日期：1988年3月10日。描述了一种基本上由作为陶瓷载体的Al 2 O 3组成的陶瓷，描述了用于加热导体的陶瓷覆盖层和/或陶瓷支撑结构，其是电化学稳定的，换句话说，其不应用于 加热电压，即使在高于600度的温度下长期运行。 这种陶瓷表现出非常小的碱金属含量，分别小于0.2重量％的Na 2 O和K 2 O 3。 如果具有2.5至10重量％的硅酸钡或硅酸锶焊剂，则通过这种陶瓷表现出特别有利的加工，特别是压制性能，Na 2 O，K 2 O，CaO和MgO的比例一起构成小于1重量％ ，BaO或SrO：SiO2的摩尔比为2:1〜1:12.5。 这种BaO:SiO 2比例为2.6:1重量份的陶瓷的电化学稳定性高达约1400℃，在1300℃下仍具有约300N / mm2的弯曲强度。
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公开(公告)号：US06347543B1
公开(公告)日：2002-02-19
申请号：US09434667
申请日：1999-11-05
IPC分类号： G01N2704
CPC分类号： G01N27/4078 , G01N27/407 , Y10T29/49211
摘要： A measuring sensor, in particular, for determining the oxygen content in exhaust gases of internal combustion engines, includes a ceramic molding arranged in a metal housing for the accommodation of a sensor element, in particular, planar, the sensor element being sealed by a seal element made of warm-deformable temperature-resistant material. The molded housing is designed in one piece and has a cylindrically shaped longitudinal hole on the connector side, around the sensor element, and the seal element is compressed between a first compressing element on the measuring-gas side and a second compressing element on the connector side, such that it tightly encloses the sensor element and hermetically seals the sensor element with respect to the molded housing.
摘要翻译： 特别地，用于确定内燃机排气中的氧含量的测量传感器包括布置在金属壳体中用于容纳传感器元件，特别是平面的陶瓷模制件，传感器元件由密封件 元件由耐温变形的耐温材料制成。 模制壳体被设计成一体并且在连接器侧上具有围绕传感器元件的圆柱形纵向孔，并且密封元件在测量气体侧的第一压缩元件和连接器上的第二压缩元件之间被压缩 使得其紧密地包围传感器元件并相对于模制壳体气密地密封传感器元件。
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7.发明授权Electrochemical sensor, particularly for oxygen determination in combustion gases 失效电化学传感器，特别用于燃烧气体中的氧气测定
公开(公告)号：US4282080A
公开(公告)日：1981-08-04
申请号：US121632
申请日：1980-02-14
申请人： Klaus Muller , Ernst Linder , Helmut Mauer , Karl-Hermann Friese , Franz Rieger , Heinz Geier
发明人： Klaus Muller , Ernst Linder , Helmut Mauer , Karl-Hermann Friese , Franz Rieger , Heinz Geier
IPC分类号： G01N27/41 , G01N27/406 , G01N27/407 , G01N27/409 , G01N27/413 , G01N27/416 , G01N27/48 , G01N27/58
CPC分类号： G01N27/4071 , G01N27/4067 , G01N27/407 , G01N27/48
摘要： To facilitate mass production and permit ready introduction of a substance which provides an oxygen partial pressure reference level, for example the oxygen in ambient air, an elongated plane flat plate-like solid electrolyte body is provided with electrodes thereon, and one of the electrodes is covered by a trough-like cover element to form the reference electrode, the space beneath the trough-like element and the electrode itself being available for the substance which may, but need not be, the oxygen of air, and may be a solid material providing a reference oxygen partial pressure level. The cover plate may, itself, be made of solid electrolyte material and may form a portion of another sensing element, so that a plurality of sensing elements can be superimposed in sandwich-like fashion. A heater element can be applied to a flat plate element of the assembly where desired. The sensors can operate in the potentiometric or polarographic mode.
摘要翻译： 为了促进批量生产并准许准备引入提供氧分压参考水平的物质，例如环境空气中的氧气，细长平面平板状固体电解质体在其上设置有电极，并且其中一个电极是 由槽状盖元件覆盖以形成参考电极，槽状元件下面的空间和电极本身可用于可以但不必须是空气氧的物质，并且可以是固体材料 提供参考氧分压水平。 盖板本身可以由固体电解质材料制成并且可以形成另一感测元件的一部分，使得多个感测元件可以以夹层状的方式重叠。 如果需要，加热器元件可以应用于组件的平板元件。 传感器可以以电位或极谱方式工作。
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公开(公告)号：US06922007B2
公开(公告)日：2005-07-26
申请号：US10463975
申请日：2003-06-17
申请人： Heinz Geier , Rudolf Pollner
发明人： Heinz Geier , Rudolf Pollner
摘要： A spark plug includes a ceramic component, whose surface is at least in part coated with a glaze, with the glaze containing 0.6% to 4% by weight of fluoride and 6% to 11.2% by weight of zinc oxide.
摘要翻译： 火花塞包括陶瓷组分，其表面至少部分地涂覆有釉料，釉料含有0.6重量％至4重量％的氟化物和6重量％至11.2重量％的氧化锌。
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公开(公告)号：US20060162422A1
公开(公告)日：2006-07-27
申请号：US10516723
申请日：2003-05-15
申请人： Heinz Geier , Helmut Weyl , Siegfried Nees , Bernhard Wild , Rainer Maier , Michael Liebler , Peter Dettling , Bettina Schneider , Craig Magera
发明人： Heinz Geier , Helmut Weyl , Siegfried Nees , Bernhard Wild , Rainer Maier , Michael Liebler , Peter Dettling , Bettina Schneider , Craig Magera
IPC分类号： G01N33/497
CPC分类号： G01N27/4078 , G01N27/407
摘要： A gas sensor, whose purpose is to determine a physical property of a measuring gas, e.g., to determine the concentration of a gas component or the temperature of an exhaust gas. The gas sensor includes a sensor element arranged in a metal housing which is sealed by at least one sealing element arranged in a metal receptacle. The metal receptacle is affixed to the housing. The sealing element surrounds the sensor element in a centered position along its longitudinal extension L or on its half facing the measuring gas.
摘要翻译： 气体传感器的目的是确定测量气体的物理性能，例如确定气体成分的浓度或废气的温度。 气体传感器包括布置在金属壳体中的传感器元件，其被布置在金属容器中的至少一个密封元件密封。 金属插座固定在外壳上。 密封元件围绕传感器元件沿着其纵向延伸部L在其中心位置或其半个面对测量气体的中心位置。
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公开(公告)号：US06636142B2
公开(公告)日：2003-10-21
申请号：US09980472
申请日：2001-11-30
申请人： Heinz Geier , Gert Lindemann , Friederike Lindner , Thomas Brinz , Ulrich Eisele
发明人： Heinz Geier , Gert Lindemann , Friederike Lindner , Thomas Brinz , Ulrich Eisele
IPC分类号： H01C104
CPC分类号： G01K7/183
摘要： A sensor element, especially a temperature sensor (5) is proposed, having a sensitive area (11), whose electrical resistance changes under the influence of a temperature to which the sensitive area (11) is exposed. In this case, sensitive area (11) has a glass ceramic fusion (15) of a starting material containing at least one component which is furnished at least substantially with a surface metallization. The proposed temperature sensor (5) is especially suitable for use at temperatures in excess of 1000° C., at which it shows resistance characteristics like that of a platinum resistor.
摘要翻译： 提出了一种传感器元件，特别是温度传感器，其具有敏感区域，其敏感区域在敏感区域暴露的温度的影响下变化。 在这种情况下，敏感区域具有包含至少基本上具有表面金属化的至少一种成分的起始材料的玻璃陶瓷熔合。 所提出的温度传感器特别适合在超过1000℃的温度下使用，在此温度传感器显示出如铂电阻器的电阻特性。
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