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    Thermally switchable ruthenium initiators
    73.
    发明授权
    Thermally switchable ruthenium initiators 失效
    可热切换的钌引发剂

    公开(公告)号：US08278449B2

    公开(公告)日：2012-10-02

    申请号：US13211388

    申请日：2011-08-17

    申请人： Ezat Khosravi ,  Osama M. Musa

    发明人： Ezat Khosravi ,  Osama M. Musa

    IPC分类号： C07F15/00 ,  C08F4/80

    CPC分类号： C07F15/0046 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/418

    摘要： This invention relates to ruthenium initiators for the ring-opening metathesis polymerization (ROMP) of cyclic olefins that are inactive at room temperature but activatable at elevated temperature (referred to as (“thermally switchable”). In general, these are compounds of ruthenium metal to which are bonded four or five ligands, in which one ligand is a pyridine ring in which the nitrogen is chelated to the ruthenium, or a five or six membered ring incorporating nitrogen and the ruthenium in which the nitrogen is chelated to the ruthenium.

    摘要翻译： 本发明涉及用于环状烯烃的开环易位聚合（ROMP）的钌引发剂，其在室温下是无活性的，但在高温下可激活（称为（可热切换）），通常是这些化合物，其中金属钌 键合四或五个配体，其中一个配体是吡啶环，其中氮与钌螯合，或五或六元环结合氮和钌，其中氮与钌螯合。

    LACTAM-BASED COMPOUNDS WITH A URETHANE OR UREA FUNCTIONAL GROUP, AND USES THEREOF
    74.
    发明申请
    LACTAM-BASED COMPOUNDS WITH A URETHANE OR UREA FUNCTIONAL GROUP, AND USES THEREOF 有权
    具有URETHANE或UREA功能组的基于LACTAM的化合物及其用途

    公开(公告)号：US20120149861A1

    公开(公告)日：2012-06-14

    申请号：US13390852

    申请日：2010-08-18

    申请人： Osama M. Musa

    发明人： Osama M. Musa

    IPC分类号： C08F126/10 ,  C07D223/10 ,  C08F226/10 ,  C07D207/12

    CPC分类号： C07D207/27 ,  C07D223/10 ,  C08G18/2855 ,  C08G18/8108

    摘要： Compounds comprising a lactam moiety, and a urethane or urea functional group are presented. By a preferred synthesis route, they are prepared using at least one polymerizable compound comprising an isocyanate moiety and reacting it with at least one hydroxyalkyl lactam compound or one aminoalkyl lactam compound. In preferred embodiments the lactam moiety is a pyrrolidone or caprolactam ring, and the polymerizable compound is a functionalized aryl isocyanate. The compounds and homopolymers and non-homopolymers thereof find useful application in a wide variety of arts, including: adhesive, agricultural, biocides, cleaning, coating, electronics, encapsulation, membrane, microelectronics, oilfield, performance chemical, personal care, sealant, and sensor applications.

    摘要翻译： 提供了包含内酰胺部分和氨基甲酸酯或脲官能团的化合物。 通过优选的合成途径，它们使用至少一种包含异氰酸酯部分的可聚合化合物制备，并使其与至少一种羟烷基内酰胺化合物或一种氨基烷基内酰胺化合物反应。 在优选的实施方案中，内酰胺部分是吡咯烷酮或己内酰胺环，并且可聚合化合物是官能化的芳基异氰酸酯。 化合物及其均聚物和非均聚物可用于广泛的领域，包括：粘合剂，农业，杀生物剂，清洁，涂料，电子，封装，膜，微电子学，油田，性能化学品，个人护理，密封剂和 传感器应用。

    FUNCTIONALIZED 4- AND 5-VINYL SUBSTITUTED REGIOISOMERS OF 1, 2, 3-TRIAZOLES VIA 1, 3-DIPOLAR CYCLOADDITION AND POLYMERS THEREOF
    76.
    发明申请
    FUNCTIONALIZED 4- AND 5-VINYL SUBSTITUTED REGIOISOMERS OF 1, 2, 3-TRIAZOLES VIA 1, 3-DIPOLAR CYCLOADDITION AND POLYMERS THEREOF 审中-公开
    通过1,3-DIPOLAR循环和其聚合物的1,2和3 - 三唑的官能化4-和5-乙烯基取代的二氧化物

    公开(公告)号：US20120041040A1

    公开(公告)日：2012-02-16

    申请号：US13255544

    申请日：2010-03-09

    申请人： Osama M. Musa ,  Brian Marr

    发明人： Osama M. Musa ,  Brian Marr

    IPC分类号： A61K31/4192 ,  C07D249/04 ,  C09D7/00 ,  C11D3/60 ,  C09J11/00 ,  C08F126/06 ,  C09D179/04 ,  A01N43/647 ,  C09K8/00

    CPC分类号： C07D249/04 ,  A01N43/647 ,  A61K8/496 ,  A61K8/817 ,  A61K2800/10 ,  A61Q19/00 ,  C07D295/155 ,  C08F26/06 ,  C09D139/04 ,  C09J139/04 ,  C11D3/28 ,  C11D3/3776 ,  A01N25/10

    摘要： The present invention provides novel functionalized mixtures 4- and 5-vinyl substituted regioisomers of 1,2,3-triazoles via 1,3-dipolar cycloaddition. Functionalized alkyne moieties with a terminal alcoholic functionality are reacted with functionalized organic moieties with a terminal leaving group and an azide to provide an alcoholic functionalized mixture of 4- and 5-substituted regioisomers of 1,2,3-triazole moieties. The mixture may be converted to a wide variety of useful functionalized mixtures of 4- and 5-vinyl substituted regioisomers of 1,2,3-triazole moieties, which in turn can be converted to a wide variety of useful polymers The novel alcoholic functionalized mixtures of 4- and 5-substituted regioisomers can be separated by chromatography to provide the purified 4- and 5-alcoholic functionalized substituted 1,2,3-triazole moieties. The novel compounds of the invention can be employed in a wide variety of compositions (Formulae (I), (II)); wherein R1, R2, R3, and R4, are defined herein.

    摘要翻译： 本发明通过1,3-偶极环加成提供了1,2,3-三唑的新型官能化混合物4-和5-乙烯基取代区域异构体。 具有末端醇官能团的官能化炔部分与官能化的有机部分与末端离去基团和叠氮化物反应，得到1,2,3-三唑部分的4-和5-取代的区域异构体的醇官能化混合物。 该混合物可以转化成1,2,3-三唑部分的4-和5-乙烯基取代区域异构体的多种有用的官能化混合物，其又可以转化为多种有用的聚合物。新的醇官能化混合物 的4-和5-取代的区域异构体可以通过色谱分离以提供纯化的4-和5-醇官能化的取代的1,2,3-三唑部分。 本发明的新化合物可用于多种组合物中（式（I），（II））; 其中R1，R2，R3和R4在本文中定义。

    Thermally Switchable Ruthenium Initiators
    77.
    发明申请
    Thermally Switchable Ruthenium Initiators 失效
    可开关的钌引发剂

    公开(公告)号：US20110301297A1

    公开(公告)日：2011-12-08

    申请号：US13211388

    申请日：2011-08-17

    申请人： Ezat Khosravi ,  Osama M. Musa

    发明人： Ezat Khosravi ,  Osama M. Musa

    IPC分类号： C08F4/80 ,  C07F15/00 ,  C08F112/08 ,  C08F132/08

    CPC分类号： C07F15/0046 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/418

    摘要： This invention relates to ruthenium initiators for the ring-opening metathesis polymerization (ROMP) of cyclic olefins that are inactive at room temperature but activatable at elevated temperature (referred to as (“thermally switchable”). In general, these are compounds of ruthenium metal to which are bonded four or five ligands, in which one ligand is a pyridine ring in which the nitrogen is chelated to the ruthenium, or a five or six membered ring incorporating nitrogen and the ruthenium in which the nitrogen is chelated to the ruthenium.

    摘要翻译： 本发明涉及环烯烃的开环易位聚合（ROMP）的钌引发剂，其在室温下是无活性的，但在高温下可被激活（称为“可热切换的”），通常这些是钌金属化合物 其中一个配体是其中氮被螯合到钌上的吡啶环，或五个或六元环结合氮和其中氮与钌螯合的钌键合到四个或五个配体上。

    Ring-Opening Metathesis Polymerization Of Norbornene And Oxanorbornene Moieties And Uses Thereof
    78.
    发明申请
    Ring-Opening Metathesis Polymerization Of Norbornene And Oxanorbornene Moieties And Uses Thereof 有权
    降冰片烯和氧代降冰片烯的开环复分解聚合及其用途

    公开(公告)号：US20110065880A1

    公开(公告)日：2011-03-17

    申请号：US12887795

    申请日：2010-09-22

    申请人： Osama M. Musa

    发明人： Osama M. Musa

    IPC分类号： C08F132/08

    CPC分类号： C08F132/08 ,  C08G61/12 ,  C08G2261/11 ,  C08G2261/12 ,  C08G2261/126 ,  C08G2261/1426 ,  C08G2261/3342 ,  C08G2261/418 ,  C08G2261/724

    摘要： The present invention provides homopolymers resulting from ROMP of oxanorbornene dicarboxylic anhydride moieties and non-homopolymers resulting from ROMP of norbornene dicarboxylic anhydrides and oxanorbornene dicarboxylic anhydrides with co-monomer moieties. The invention further provides hydrogenated homopolymers resulting from ROMP of oxanorbornene dicarboxylic anhydrides and hydrogenated non-homopolymers resulting from ROMP of norbornene dicarboxylic anhydrides and oxanorbornene dicarboxylic anhydrides with co-monomer moieties. The invention further provides a wide variety of compositions comprising the novel ROMP moieties. Some of the novel ROMP moiety structures are set out below, wherein R1, R2, X, n, and m are defined herein.

    摘要翻译： 本发明提供由衍生物二恶酐部分的ROMP产生的均聚物和由降冰片烯二羧酸酐和具有共聚单体部分的氧代降冰片烯二羧酸酐的ROMP得到的非均聚物。 本发明还提供了由降冰片烯二羧酸酐和具有共聚单体部分的氧代降冰片烯二羧酸酐的ROMP产生的由恶二酮二羧酸酐制成的ROMP和氢化非均聚物得到的氢化均聚物。 本发明还提供了包含新型ROMP部分的多种组合物。 一些新的ROMP部分结构如下所示，其中R1，R2，X，n和m如本文所定义。

    Ultraviolet-Absorbing Compounds
    79.
    发明申请
    Ultraviolet-Absorbing Compounds 有权
    紫外线吸收化合物

    公开(公告)号：US20110020251A1

    公开(公告)日：2011-01-27

    申请号：US12841716

    申请日：2010-07-22

    申请人： Jenn S. Shih ,  Osama M. Musa

    发明人： Jenn S. Shih ,  Osama M. Musa

    IPC分类号： A61K8/44 ,  C07C229/34 ,  A61Q17/04

    CPC分类号： A61Q17/04 ,  A61K8/86

    摘要： Disclosed are novel ultraviolet-absorbing compounds produced by two embodiments. By a first embodiment, the ultraviolet-absorbing compound is derived from at a first reactant being a UV absorber comprising a carbon-nitrogen triple bond and a second reactant having amine functionality. By a second embodiment, the ultraviolet-absorbing compound is derived from a first reactant being a UV absorber comprising amine functionality and a second reactant comprising a carbon-nitrogen triple bond. In both embodiments of the invention, the second reactant may be a small molecule, a monomer, a macromolecule, a biomolecule, or a polymer.The invention's ultraviolet-absorbing compounds are directed toward formulations and applications that serve to protect against UV radiation in any art. Exemplary uses of the ultraviolet-absorbing compounds are in adhesive, agriculture, cleaning/polishing, coating, containers, encapsulation, fragrances, imaging, hoses/tubing, household/industrial/institutional, medical, membrane, molded parts, oilfield, packaging, personal care, personal protective equipment, pharmaceutical, printing, veterinary, and wood-care applications. Highly preferred uses of the ultraviolet-absorbing compounds are in personal care and performance chemicals. wherein R═

    摘要翻译： 公开了由两个实施方案制备的新型紫外线吸收化合物。 在第一个实施方案中，紫外线吸收化合物是由第一反应物衍生的，其是包含碳 - 氮三键的紫外线吸收剂和具有胺官能团的第二反应物。 通过第二个实施方案，紫外线吸收化合物衍生自第一反应物，其是包含胺官能团的UV吸收剂和包含碳 - 氮三键的第二反应物。 在本发明的两个实施方案中，第二反应物可以是小分子，单体，大分子，生物分子或聚合物。 本发明的紫外线吸收化合物涉及用于在任何领域中防止UV辐射的制剂和应用。 紫外线吸收化合物的示例性用途是粘合剂，农业，清洁/抛光，涂料，容器，包封，香料，成像，软管/管材，家用/工业/制药，医疗，膜，模制零件，油田，包装，个人 护理，个人防护设备，制药，印刷，兽医和木材护理应用。 紫外线吸收化合物的非常优选的用途是个人护理和性能化学品。 其中R =

    POLYVINYLAMIDE POLYMERS CONTAINING POLYMERIZABLE FUNCTIONALITIES
    80.
    发明申请
    POLYVINYLAMIDE POLYMERS CONTAINING POLYMERIZABLE FUNCTIONALITIES 有权
    包含可聚合功能的聚乙烯酰胺聚合物

    公开(公告)号：US20100190947A1

    公开(公告)日：2010-07-29

    申请号：US12698583

    申请日：2010-02-02

    申请人： David K. Hood ,  Osama M. Musa

    发明人： David K. Hood ,  Osama M. Musa

    IPC分类号： C08F26/06

    CPC分类号： C08F226/02 ,  C08F226/10 ,  C08F220/18 ,  C08F220/60 ,  C08F220/06 ,  C08F222/10 ,  C08F220/14 ,  C08F220/32 ,  C08F220/42 ,  C08F220/34 ,  C08F220/36

    摘要： The present invention relates to a polymerizable polymer formed from an N-vinyl amide monomer and containing a polymerizable functionality. In one approach, a dual functional monomer may be employed. In the case where the dual functional monomer incorporates glycidyl methacrylate, a third polymerizable monomer is also included. In a second approach, a monomer with polymerizable functionality can be grafted onto a pre-existing, suitable N-vinyl amide co-polymeric material, yielding a co-polymer comprising a polymerizable functionality. where x+y+z+a=100

    摘要翻译： 本发明涉及由N-乙烯基酰胺单体形成并含有可聚合官能团的可聚合聚合物。 在一种方法中，可以使用双官能单体。 在双官能单体引入甲基丙烯酸缩水甘油酯的情况下，也包括第三可聚合单体。 在第二种方法中，具有可聚合官能团的单体可以接枝到预先存在的合适的N-乙烯基酰胺共聚物材料上，产生包含可聚合官能团的共聚物。 其中x + y + z + a = 100