公开(公告)号：US12037319B2

公开(公告)日：2024-07-16

申请号：US17254053

申请日：2019-06-10

申请人： DAICEL CORPORATION

发明人： Daisuke Ito ,  Tsukasa Yoshida ,  Toshihiro Tai ,  Hitomi Tamaoki ,  Satoru Sumimoto

IPC分类号： C07D209/48 ,  C07C225/22 ,  C07D207/452 ,  C09D4/00 ,  C09D139/04 ,  C09D149/00 ,  C09J4/00 ,  C09J139/04 ,  C09J149/00 ,  C09K3/10

CPC分类号： C07D209/48 ,  C07C225/22 ,  C07D207/452 ,  C09D4/00 ,  C09D139/04 ,  C09D149/00 ,  C09J4/00 ,  C09J139/04 ,  C09J149/00 ,  C09K3/10 ,  C07C2601/16 ,  C09K2200/0615

摘要： Provided is a curable compound having a low melting temperature, having excellent workability as a result of having good solvent solubility, and being capable of forming a cured product having excellent heat resistance. The curable compound according to an embodiment of the present invention includes the following characteristics (a) to (e). (a) Number average molecular weight (calibrated with polystyrene standard): 1000 to 15000. (b) Proportion of a structure derived from an aromatic ring in the total amount of the curable compound: 50 wt. % or greater. (c) Solvent solubility at 25° C.: 1 g/100 g or greater. (d) Glass transition temperature: 280° C. or lower. (e) 5% Weight loss temperature (Td5) measured at a rate of temperature increase of 10° C./min (in nitrogen), for a cured product of the curable compound: 300° C. or higher.

公开(公告)号：US20240218216A1

公开(公告)日：2024-07-04

申请号：US18563549

申请日：2022-05-19

申请人： CEMEDINE CO., LTD.

发明人： Jun KOTANI ,  Makoto KONNO

IPC分类号： C09J139/04 ,  C09J4/06 ,  C09J11/08

CPC分类号： C09J139/04 ,  C09J4/06 ,  C09J11/08

摘要： An object of the present invention is to provide an acrylic adhesive having excellent high-temperature adhesive strength and excellent cured product elongation. Accordingly, provided is a two-part acrylic adhesive composition including, as essential components, (A) a urethane (meth)acrylate having a backbone including a low-crystallinity polytetramethylene glycol, (B) a polymerizable vinyl monomer, (C) an organic peroxide, and (D) a reducing agent.

公开(公告)号：US09080083B2

公开(公告)日：2015-07-14

申请号：US13887936

申请日：2013-05-06

申请人： tesa SE

发明人： Uwe Schümann ,  Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Thilo Dollase

IPC分类号： C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06

CPC分类号： C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06 ,  C08L39/04 ,  C08L39/06

摘要： The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, c) acrylic acid, one or more organofunctional silanes. Such primer provides reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass. The adhesion-promoting effect is retained even when the primer additionally contains functional fillers.

摘要翻译： 本发明涉及一种底漆，其包含溶解或分散在一种或多种溶剂中的混合物，所述混合物由通过共聚获得的共聚物，优选自由基共聚合得到的乙烯基己内酰胺和/或乙烯基吡咯烷酮以及一种或多种以下单体 a）在醇的烷基中含有2至10个碳原子的直链伯醇的丙烯酸酯，b）烷基中具有4至12个碳原子的支链非环状醇的丙烯酸酯 的醇，c）丙烯酸，一种或多种有机官能硅烷。 这种底漆在压敏粘合带和亲水表面之间，特别是玻璃上提供了可靠和优异的粘合性。 即使引物另外含有功能性填料也可以保持粘附促进效果。

公开(公告)号：US20150175853A1

公开(公告)日：2015-06-25

申请号：US14640835

申请日：2015-03-06

申请人： tesa SE

发明人： Uwe Schümann ,  Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Thilo Dollase

IPC分类号： C09J133/08

CPC分类号： C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06 ,  C08L39/04 ,  C08L39/06

摘要： The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, c) acrylic acid, one or more organofunctional silanes. Such primer provides reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass. The adhesion-promoting effect is retained even when the primer additionally contains functional fillers.

摘要翻译： 本发明涉及一种底漆，其包含溶解或分散在一种或多种溶剂中的混合物，所述混合物由通过共聚获得的共聚物，优选自由基共聚合得到的乙烯基己内酰胺和/或乙烯基吡咯烷酮以及一种或多种以下单体 a）在醇的烷基中含有2至10个碳原子的直链伯醇的丙烯酸酯，b）烷基中具有4至12个碳原子的支链非环状醇的丙烯酸酯 的醇，c）丙烯酸，一种或多种有机官能硅烷。 这种底漆在压敏粘合带和亲水表面之间，特别是玻璃上提供了可靠和优异的粘合性。 即使引物另外含有功能性填料也可以保持粘附促进效果。

公开(公告)号：US08791219B2

公开(公告)日：2014-07-29

申请号：US13781843

申请日：2013-03-01

申请人： Robert H. Grubbs ,  Hoyong Chung ,  Michael Richard Harrison

发明人： Robert H. Grubbs ,  Hoyong Chung ,  Michael Richard Harrison

IPC分类号： C08F22/40 ,  C08F12/30 ,  C08F16/34 ,  C08F222/40 ,  C04B37/00

CPC分类号： C09J139/04 ,  C09J133/26

摘要： The present inventions are directed to novel medical adhesives and their use, for example, in biomedical applications. These compositions and applications allow for improved adhesion with and between mammalian tissues.

摘要翻译： 本发明涉及新型医用胶粘剂及其在生物医学应用中的用途。 这些组合物和应用允许改善与哺乳动物组织之间和之间的粘附。

公开(公告)号：US20130289157A1

公开(公告)日：2013-10-31

申请号：US13978173

申请日：2011-08-12

申请人： Kaori Sato ,  Takaaki Hatori ,  Yasuhiro Fujiwara

发明人： Kaori Sato ,  Takaaki Hatori ,  Yasuhiro Fujiwara

IPC分类号： C09J9/00

CPC分类号： C09J9/00 ,  A61K9/0014 ,  A61K9/06 ,  A61K47/10 ,  A61K47/32 ,  C09J133/02 ,  C09J133/26 ,  C09J139/04

摘要： A composition for an adhesive hydrogel, comprising at least: a polymeric matrix former; water; and a polyhydric alcohol; the polymeric matrix former comprising at least: (a) (meth)acrylic acid, a (meth)acrylic acid derivative or a vinyl derivative having 2 carboxyl groups and 4 or 5 carbon atoms; (b) (meth)acrylamide or a (meth)acrylamide derivative; (c) N-vinyl-2-caprolactam and/or N-vinyl-2-valerolactam; and (d) a cross-linkable monomer, wherein the content percentage of the (b) in the composition for an adhesive hydrogel is 2 to 20% by weight.

摘要翻译： 一种用于粘合剂水凝胶的组合物，至少包含：聚合物基质成型剂; 水; 和多元醇; 所述聚合物基质原料至少包含：（a）（甲基）丙烯酸，（甲基）丙烯酸衍生物或具有2个羧基和4或5个碳原子的乙烯基衍生物; （b）（甲基）丙烯酰胺或（甲基）丙烯酰胺衍生物; （c）N-乙烯基-2-己内酰胺和/或N-乙烯基-2-戊内酰胺; 和（d）可交联单体，其中粘合性水凝胶组合物中（b）的含量百分比为2〜20重量％。

公开(公告)号：US20120288710A1

公开(公告)日：2012-11-15

申请号：US13521115

申请日：2010-01-07

申请人： Masayuki Okamoto ,  Masahito Niwa ,  Chie Kitano

发明人： Masayuki Okamoto ,  Masahito Niwa ,  Chie Kitano

IPC分类号： C09J177/02 ,  B05D3/02 ,  C08F2/46 ,  B32B27/30

CPC分类号： C09J139/04 ,  C09J7/385 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F226/06 ,  C08F2222/1013

摘要： An object of the present invention is to provide an acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive, which has excellent adhesiveness to an adherend having surface polarity of every kind and can exhibit excellent repulsion resistance even in a moist heat environment, and a pressure-sensitive adhesive sheet using the composition. The pressure-sensitive adhesive composition provided by the present invention contains a copolymerization reaction product of a monomer mixture. The monomer mixture contains an alkyl (meth)acrylate having an alkyl group with a carbon number of from 4 to 20 and N-vinylcaprolactam. The total sum amount thereof is 95% by mass or more of the whole of monomer components. An amount of N-vinylcaprolactam is from 12 to 40% by mass.

摘要翻译： 本发明的目的是提供一种能够形成粘合剂的丙烯酸类压敏粘合剂组合物，其对具有各种表面极性的被粘物具有优异的粘附性，并且即使在潮湿的热环境中也能表现出优异的抗斥性 和使用该组合物的压敏粘合片。 由本发明提供的压敏粘合剂组合物含有单体混合物的共聚反应产物。 单体混合物含有碳数为4〜20的烷基（甲基）丙烯酸烷基酯和N-乙烯基己内酰胺。 其总量为全部单体成分的95质量％以上。 N-乙烯基己内酰胺的量为12〜40质量％。

公开(公告)号：US2941980A

公开(公告)日：1960-06-21

申请号：US62102556

申请日：1956-11-08

申请人： GEN ANILINE & FILM CORP

发明人： GERALD ROBINSON

IPC分类号： C08K5/13 ,  C09J139/04

CPC分类号： C08K5/13 ,  C08L2666/34 ,  C09J139/04 ,  Y10S424/02 ,  C08L39/04

摘要： A composition of 1 to 3 parts by weight of a water-soluble polymer of vinyl pyrrolidone or vinyl-alkyl-pyrrolidone or of a co-polymer of a mixture of monomers containing at least 20% by weight of said vinyl pyrrolidones contains 1 part by weight of wherein R1, R2, R3 and R4 are each hydrogen or an alkyl radical of 1-9 carbon atoms, the carbon atoms in all the alkyl radicals totalling 4 to 18. Substituted N - vinyl - 2 - pyrrolidones mentioned are 3-methyl-, 4-methyl, 3,3-dimethyl, 4-ethyl, 5-methyl, 5-ethyl. Monomers suitable for making copolymers are allyl alcohol, diallyl phthalate, isobutyl vinyl ether, maleic anhydride, vinyl acetate, vinyl chloride, acrylic acid, vinyl laurate, vinyl stearate. A number of specific monomer combinations are listed. Many suitable phenols are mentioned. The mixtures of polymer and phenol are sometimes soluble in solvents which do not dissolve the polymer alone, e.g. hydrocarbons, ketones, halogenated hydrocarbons or dioxane. In examples: (1) a film with adhesive properties when wet is formed from an alcohol solution of polyvinyl-pyrrolidone and nonyl phenol; (2) to (6) are similar, employing dinonyl phenol; (7) employs nonyl phenol to make a film of laminating adhesive; (8), (9) and (10) use dioctyl phenol; and (11) diisobutyl phenol; (12) uses mixed polyvinylpyrrolidone of different mol. weights; (13) is similar to (7) but uses (a) dinonyl phenol, (b) dioctyl phenol, (c) octyl phenol, (d) hexyl phenol, (e) diisobutyl phenol, and (f) p-isoamyl phenol; (14) and (15) are similar to (7) using a variety of phenols in coatings for metals or for polythene paper laminates; (16) describes an ink containing polyvinylpyrrolidone, nonyl phenol, xylene, Rhodamine or Rubine, and cobalt naphthenate. A number of other examples are given in which solutions of polymers or copolymers of vinyl pyrrolidone or its deviations are incorporated with waxes, e.g. carnauba, candellilla or beeswax, siloxanes, or plasticizers, e.g. dioctyl phthalate, butanediol, or glycol. The compositions may also be mixed with other resins, e.g. polythene, epoxy resins, polyvinyl acetate, polyvinyl methyl ether. Fillers, e.g. carbon or silica may also be incorporated. Thus in Example (24) a pigmented sheet is produced from polyvinylpyrrolidone, dinonyl phenol, carbon black and polyethylene. In Example (27), resistors for printed circuits are produced from a composition containing epoxy resin, polyvinylpyrrolidone, dinonyl phenol, carbon black and diethylenetriamine. The compositions are used for coatings on metal, glass, wood, paper, polyethylene, &c., as inks, as adhesives, e.g. for laminating, as plasticizers, e.g. for polyethylene, or for sizing siliceous materials, e.g. glass fibres.

公开(公告)号：US11745482B2

公开(公告)日：2023-09-05

申请号：US17081090

申请日：2020-10-27

申请人： Showa Denko Materials Co., Ltd.

发明人： Kosuke Murai ,  Takao Tanigawa ,  Minoru Kakitani ,  Makoto Yanagida ,  Mami Shimada

IPC分类号： B32B27/32 ,  B32B7/12 ,  B32B15/085 ,  C09J7/24 ,  C09J7/30 ,  C09J139/04

CPC分类号： B32B27/322 ,  B32B7/12 ,  B32B15/085 ,  C09J7/241 ,  C09J7/30 ,  C09J139/04 ,  B32B2250/02 ,  B32B2250/03 ,  B32B2307/538 ,  B32B2457/08 ,  C09J2301/30 ,  C09J2427/006

摘要： The present disclosure relates to a fluororesin substrate laminate for a high-frequency circuit, the fluororesin substrate laminate including a fluororesin substrate and an adhesive layer provided on the fluororesin substrate, wherein the adhesive layer includes a resin composition containing: (A) a maleimide compound having a saturated or unsaturated divalent hydrocarbon group; and (B) an aromatic maleimide compound.

公开(公告)号：US09587144B2

公开(公告)日：2017-03-07

申请号：US13443284

申请日：2012-04-10

申请人： Matthias Gerst ,  Dirk Wulff ,  Heinrich Harrer

发明人： Matthias Gerst ,  Dirk Wulff ,  Heinrich Harrer

IPC分类号： C09J4/00 ,  C09J133/14 ,  C09J7/02 ,  C09J133/08 ,  C09J133/12 ,  C09J109/06 ,  C09J139/04 ,  C09J133/02 ,  C08F2/22 ,  C09J133/06

CPC分类号： C09J4/00 ,  C08F2/22 ,  C09J7/385 ,  C09J109/06 ,  C09J133/02 ,  C09J133/066 ,  C09J133/068 ,  C09J133/08 ,  C09J133/12 ,  C09J133/14 ,  C09J139/04 ,  C09J2201/606 ,  C09J2433/00 ,  Y10T428/287 ,  C08F2220/185 ,  C08F220/14 ,  C08F2220/387 ,  C08F220/20 ,  C08F220/06 ,  C08F212/08 ,  C08F2220/325

摘要： A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The monomer mixture comprises alternatively at least 0.05% by weight of glycidyl (meth)acrylate and/or the pressure-sensitive adhesive dispersion comprises at least one further polymer P2 which contains glycidyl groups.

摘要翻译： 给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。 聚合物P1由包含（a）至少40重量％的（甲基）丙烯酸C 4至C 20烷基酯的单体混合物形成，当聚均为均聚物的玻璃化转变温度为-30℃或更低时，（b） 至少0.05重量％的具有下式的取代基的（甲基）丙烯酸酯单体，其中X是CH 2，O，NH或NR，R是C 1至C 4烷基，（c）至少0.1重量％的酸单体 。 单体混合物可选地包含至少0.05重量％的（甲基）丙烯酸缩水甘油酯和/或压敏粘合剂分散体包含至少一种含有缩水甘油基的另外的聚合物P2。