摘要:
Ethylenically unsaturated carboxyl monomers, such as acrylic or methacrylic acid or their esters, are protected from premature polymerization during manufacture and storage in the presence or absence of water by the incorporation therein of an effective stabilizing amount of a blend two or more nitroxides. Some of these blends provide synergistic stabilization efficacy much superior to the stabilization results obtained by use of either nitroxide alone.
摘要:
Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
摘要:
Polyolefins, especially those containing a phenolic antioxidant, are prone to discoloration upon improper processing at elevated temperatures or upon prolonged aging. Such discolored polyolefins can be reclaimed and recycled as essentially non-colored useful polymers by the addition thereto of a hydroxylamine of the formulaT.sub.1 T.sub.2 NOHwhere T.sub.1 and T.sub.2 are independently alkyl, cycloalkyl, benzyl or substituted benzyl.
摘要:
Substituted 1,3,2-benzoxazaphospholidines of formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4, and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.
摘要:
6-(4-hydroxyphenyl)-4,5-dihydro-3(2H)-pyridazinones of formula I ##STR1## where R.sub.1 and R.sub.2 are independently alkyl, cycloalkyl, aryl or aralkyl, R.sub.3 and R.sub.4 are independently hydrogen or alkyl, n is 1 to 4 and T is hydrogen, alkyl, substituted alkyl, alkylene or arylene, are effective in stabilizing organic materials against oxidative, thermal and actinic degradation.
摘要:
Aminic orthoester derivatives of the formulae ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation.
摘要:
Substituted (4-hydroxyphenylthioalkyl) derivatives of the formula ##STR1## are prepared by the reaction of the appropriate ring and hydroxybenzene thiol compounds and are useful stabilizers of organic materials.
摘要:
1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
摘要:
Substituted-(hydroxyphenyl)-pyrrolidine-2,5-dione derivatives of the formula ##STR1## are prepared by the reaction of the appropriate maleimide and phenolic compounds and are useful as stabilizers for organic polymers.
摘要:
Acylated calixarene derivatives of the formula ##STR1## are prepared by the reaction of the appropriate hydroxyphenyl alkanoate and paraformaldehyde and are useful stabilizers of organic materials.