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    Use of Solvent to Decrease Caustic Scrubber Fouling
    73.
    发明申请
    Use of Solvent to Decrease Caustic Scrubber Fouling 审中-公开
    使用溶剂降低苛性洗涤剂结垢

    公开(公告)号：US20140228611A1

    公开(公告)日：2014-08-14

    申请号：US14182646

    申请日：2014-02-18

    Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY

    Inventor： Jean-Pierre Thoret Bauchet

    IPC: C07C7/10

    CPC classification number: C07C7/10 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2252/61 ,  C07C1/20 ,  C10G19/02 ,  C10G21/14 ,  C10G53/04 ,  C10G53/12 ,  C10G70/06 ,  C10G75/04 ,  C10G2300/207 ,  C10G2300/4075 ,  C10G2300/44 ,  C10G2300/80 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

    Abstract: A method of reducing the formation of fouling deposits occurring in a caustic scrubber used to remove acid gases can include providing a caustic scrubber fed with an alkaline aqueous solution including essentially one or more of NaOH, KOH or LiOH. The method can include providing an olefin-containing hydrocarbon stream that is contaminated with oxygenated compounds and acid gases. The oxygenated compounds can be capable of making polymeric fouling deposits in the presence of the alkaline solution of the scrubber. The method can include sending the hydrocarbon stream to the caustic scrubber to recover an olefin-containing hydrocarbon stream that is essentially free of acid gases. An efficient amount of a solvent capable of reducing the formation of fouling deposits can be introduced in the caustic scrubber and/or in the alkaline solution fed to the scrubber. The solvent can be separated from the alkaline solution.

    Abstract translation: 减少在用于除去酸性气体的苛性碱洗涤器中发生的结垢沉积物的形成的方法可以包括提供碱性洗涤器，所述碱洗涤器用碱性水溶液进料，该碱性水溶液基本上包含一种或多种NaOH，KOH或LiOH。 该方法可以包括提供被含氧化合物和酸性气体污染的含烯烃的烃流。 含氧化合物能够在洗涤器的碱性溶液存在下制备聚合物结垢沉积物。 该方法可以包括将烃流送至苛性碱洗涤器以回收基本上不含酸性气体的含烯烃的烃流。 有效量的能够减少结垢沉积物形成的溶剂可引入苛性碱洗涤器和/或供给洗涤器的碱性溶液中。 溶剂可以与碱性溶液分离。

    Use of solvent to decrease caustic scrubber fouling
    75.
    发明授权
    Use of solvent to decrease caustic scrubber fouling 失效
    使用溶剂来减少苛性碱洗涤器污垢

    公开(公告)号：US08722954B2

    公开(公告)日：2014-05-13

    申请号：US13695076

    申请日：2011-05-03

    Applicant: Jean-Pierre Thoret Bauchet

    Inventor： Jean-Pierre Thoret Bauchet

    IPC: C10G75/04

    CPC classification number: C07C7/10 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2252/61 ,  C07C1/20 ,  C10G19/02 ,  C10G21/14 ,  C10G53/04 ,  C10G53/12 ,  C10G70/06 ,  C10G75/04 ,  C10G2300/207 ,  C10G2300/4075 ,  C10G2300/44 ,  C10G2300/80 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

    Abstract: The present invention is a method of reducing the formation of fouling deposits occurring in a caustic scrubber used to remove acid gases comprising: a) providing a caustic scrubber fed with an alkaline aqueous solution comprising essentially one or more of NaOH, KOH or LiOH, b) providing an olefin-containing hydrocarbon stream, contaminated with oxygenated compounds and acid gases, and said oxygenated compounds are capable to make polymeric fouling deposits in the presence of the alkaline solution of the scrubber, c) sending the above hydrocarbon stream to the caustic scrubber to recover an olefin-containing hydrocarbon stream essentially free of acid gases, wherein, d) an efficient amount of a solvent capable to reduce the formation of fouling deposits is introduced in the caustic scrubber and/or in the alkaline solution fed to the scrubber, e) the liquid outlet of the scrubber is sent to means to separate the solvent from the alkaline solution, and wherein the caustic scrubber has several stages with various caustic concentrations, and wherein the solvent injection and removal can be located at each stage.

    Abstract translation: 本发明是一种减少在用于除去酸性气体的苛性碱洗涤器中发生的结垢沉积物的形成的方法，包括：a）提供碱性洗涤器，所述苛性碱洗涤器用基本上包含NaOH，KOH或LiOH，b ）提供含氧化合物烃流，被氧化的化合物和酸性气体污染，所述含氧化合物能够在洗涤器的碱性溶液存在下形成聚合物结垢沉积物; c）将上述烃流送入苛性碱洗涤器 以回收基本上不含酸性气体的含烯烃的烃流，其中，d）将有效量的能够减少结垢沉积物形成的溶剂引入苛性碱洗涤器和/或供给洗涤器的碱性溶液中， e）将洗涤器的液体出口送入将溶剂与碱性溶液分离的装置，其中苛性碱洗涤器具有 具有各种苛性碱浓度的几个阶段，并且其中溶剂注入和去除可以位于每个阶段。

    Sulfone removal from an oxidized hydrocarbon fuel
    77.
    发明授权
    Sulfone removal from an oxidized hydrocarbon fuel 有权
    从氧化烃燃料中除去砜

    公开(公告)号：US08574429B2

    公开(公告)日：2013-11-05

    申请号：US12872055

    申请日：2010-08-31

    Applicant: Tiejun Zhang ,  Nachiketa Anand ,  Theodore Sidney Hoover

    Inventor： Tiejun Zhang ,  Nachiketa Anand ,  Theodore Sidney Hoover

    IPC: C10G19/00

    CPC classification number: C10G27/06 ,  C10G19/02 ,  C10G25/003 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

    Abstract: A one-step process for desulfurizing an oxidized sulfone-containing fuel stream, such as a diesel stream, is disclosed where mass transfer and conversion of sulfone occurs simultaneously such that the sulfur atom in sulfone molecule is removed as sulfite to provide a low-sulfur diesel stream. The diesel stream for treatment is obtained as a result of the oxidation of a thiophene-rich diesel stream with an oxidant to provide a sulfone-containing diesel stream. The one-step process uses a single vessel having a shroud of vertical hanging fibers to affect the mass transfer of sulfones in diesel into contacting with an aqueous solution of alkali metal hydroxide where it is converted to sulfite and biphenyls. The sulfite-rich aqueous solution and low sulfur diesel are then separately removed from the vessel.

    Abstract translation: 公开了一种用于脱硫含氧化砜的燃料流（例如柴油流）的一步法，其中同时发生砜的传质和转化，使得砜分子中的硫原子被亚硫酸盐除去以提供低硫 柴油流。 由于富含噻吩的柴油流与氧化剂的氧化而得到用于处理的柴油流，以提供含砜的柴油流。 一步法使用具有垂直悬挂纤维的护罩的单个容器，以影响柴油中的砜的质量传递，使其与碱金属氢氧化物的水溶液接触，并转化成亚硫酸盐和联苯。 然后从容器中分离除去富含亚硫酸盐的水溶液和低硫柴油。

    METHODS FOR CONVERTING PETROLEUM BASED OIL INTO FUEL
    78.
    发明申请
    METHODS FOR CONVERTING PETROLEUM BASED OIL INTO FUEL 有权
    将石油基油转化为燃料的方法

    公开(公告)号：US20130281746A1

    公开(公告)日：2013-10-24

    申请号：US13939129

    申请日：2013-07-10

    Applicant: OTG RESEARCH, LLC

    Inventor： Philip Allen Boe

    IPC: C10G53/14

    CPC classification number: C10L1/08 ,  C10G17/02 ,  C10G19/02 ,  C10G27/14 ,  C10G53/00 ,  C10G53/14 ,  C10G2300/1007 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/06 ,  C10L2290/24 ,  C10M175/0016

    Abstract: Methods for converting petroleum based oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to petroleum based oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.

    Abstract translation: 将石油基油转化为燃料的方法通常包括形成醇和碱的转化混合物，并将转化混合物加入到石油基油（例如二手机油）中以形成反应混合物。 所述方法还可以包括向反应混合物中加入高硝酸盐化合物和氨基酸，并使反应混合物臭氧化。 方法的结果可以包括三相系统，其中底相是沥青油，中间相是柴油燃料或喷气燃料，顶相是硫酸。 这三个阶段可以分开，以获得最终的柴油燃料或喷气燃料产品。

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