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    Aromatic thermoplastic polyphosphonatocarbonate
    82.
    发明授权
    Aromatic thermoplastic polyphosphonatocarbonate 失效
    芳香族热塑性聚磷酸酯

    公开(公告)号：US4762905A

    公开(公告)日：1988-08-09

    申请号：US735635

    申请日：1985-05-20

    申请人： Manfred Schmidt ,  Ludwig Bottenbruch ,  Dieter Freitag ,  Werner Nouvertne

    发明人： Manfred Schmidt ,  Ludwig Bottenbruch ,  Dieter Freitag ,  Werner Nouvertne

    IPC分类号： C08G63/00 ,  C08G64/00 ,  C08G79/02 ,  C08G79/04 ,  C08G63/62

    CPC分类号： C08G79/04 ,  C08G64/083

    摘要： Thermoplastic polyphosphonatocarbonate prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a basic polycondensation catalyst at a temperature of from 80.degree. to 340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonate and phosphonic acid diaryl ester being from 0.91:1 to 0.99:1, and following polycondensation, neutralizing said basic catalyst.

    摘要翻译： 在碱性缩聚催化剂存在下，在80〜340℃的温度和600〜0.1mm的压力下，使至少一种芳族二羟基化合物与碳酸二芳基酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸酯 Hg在惰性气体气氛中，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯的摩尔比为0.91:1 至0.99:1，并进行缩聚后中和所述碱性催化剂。

    Thermoplastic, branched aromatic polyphosphonates, and a process for their production
    88.
    发明授权
    Thermoplastic, branched aromatic polyphosphonates, and a process for their production 失效
    热塑性支链芳族聚磷酸酯及其制备方法

    公开(公告)号：US4415719A

    公开(公告)日：1983-11-15

    申请号：US328383

    申请日：1981-12-07

    申请人： Manfred Schmidt ,  Ludwig Bottenbruch ,  Dieter Freitag ,  Klaus Reinking ,  Harry Rohr ,  Hans-Dieter Block

    发明人： Manfred Schmidt ,  Ludwig Bottenbruch ,  Dieter Freitag ,  Klaus Reinking ,  Harry Rohr ,  Hans-Dieter Block

    IPC分类号： C08G79/00 ,  C08G79/02 ,  C08G79/04

    CPC分类号： C08G79/04

    摘要： Thermoplastic, branched aromatic polyphosphonates with average molecular weights (number average M.sub.n) of from 11,000 to more than 200,000, obtainable by transesterifying (a) from 97 to 100 moles of at least one diaryl phosphonate, and (b) from 0 to 3 moles of at least one triaryl phosphate--the sum of the moles of (a) and (b) being 100--with (c) from 90 to 99 moles of at least one aromatic dihydroxy compound, and (d) from 0 to 3 moles of at least one aromatic trihydroxy or tetradhydroxy compound--with the proviso that at least one of the components (b) and (d) is present in a quantity of at least 0.001 mole and that, where (b) and (d) are used, the maximum limit on the moles is 3.0.

    摘要翻译： 平均分子量（数均Mn）为11,000至大于200,000的热塑性支链芳族聚膦酸酯，可通过（a）97-100摩尔的至少一种二芳基膦酸酯和（b）0-3摩尔的 至少一种磷酸三芳基酯（a）和（b）的摩尔数的总和为100-（c）90至99摩尔的至少一种芳族二羟基化合物，和（d）0至3摩尔的 至少一种芳族三羟基或四羟基化合物 - 条件是组分（b）和（d）中的至少一种以至少0.001摩尔的量存在，并且使用（b）和（d）时， 摩尔数的最大限度为3.0。