Process for the preparation of high chloride tabular grain emulsions (IV)
    82.
    发明授权
    Process for the preparation of high chloride tabular grain emulsions (IV) 失效
    制备高氯酸盐粒状乳液的方法(四)

    公开(公告)号:US5185239A

    公开(公告)日:1993-02-09

    申请号:US819712

    申请日:1992-01-13

    申请人: Joe E. Maskasky

    发明人: Joe E. Maskasky

    摘要: A process of preparing a radiation sensitive high chloride high aspect ratio tabular grain emulsion is disclosed wherein silver ion is introduced into a gelatino-peptizer dispersing medium containing a stoichiometric excess of chloride ions with respect to the silver ions further characterized by a chloride ion concentration of less than 0.5 molar, a pH of at least 4.6, and a triaminopyrimidine grain growth modifier containing mutually independent 4, 5 and 6 ring position amino substituents, the 4 and 6 ring position substituents being hydroamino substituents.

    摘要翻译: 公开了一种制备辐射敏感性高氯化物高纵横比片状颗粒乳剂的方法,其中将银离子引入相对于银离子含有化学计量过量氯离子的明胶溶胶分散介质中,其进一步特征在于氯离子浓度为 小于0.5摩尔,pH至少为4.6,以及含有相互独立的4,5位和6位环氨基取代基的三氨基嘧啶晶粒生长改性剂,4位和6位的环位取代基是氢氨基取代基。

    Process for the preparation of high chloride tabular grain emulsions (II)
    83.
    发明授权
    Process for the preparation of high chloride tabular grain emulsions (II) 失效
    制备高氯化物片状颗粒乳剂的方法(II)

    公开(公告)号:US5178997A

    公开(公告)日:1993-01-12

    申请号:US762971

    申请日:1991-09-20

    申请人: Joe E. Maskasky

    发明人: Joe E. Maskasky

    摘要: A process of preparing a radiation sensitive high chloride high aspect ratio tabular grain emulsion is disclosed wherein silver ion is introduced into a gelatino-peptizer dispersing medium containing a stoichiometric excess of chloride ions a chloride ion concentration of less than 0.5 molar and a grain growth modifier of the formula: ##STR1## where Z.sup.2 is --C(R.sup.2).dbd. or --N.dbd.;Z.sup.3 is --C(R.sup.3).dbd. or --N.dbd.;Z.sup.4 is --C(R.sup.4).dbd. or --N.dbd.;Z.sup.5 is --C(R.sup.5).dbd. or --N.dbd.;Z.sup.6 is --C(R.sup.6).dbd. or --N.dbd.;with the proviso that no more than one of Z.sup.4, Z.sup.5 and Z.sup.6 is --N.dbd.;R.sup.2 is H, NH.sub.2 or CH.sub.3 ;R.sup.3, and R.sup.4 and R.sup.5 are independently selected, R.sup.3 and R.sup.5 being hydrogen, hydroxy, halogen, amino or hydrocarbon and R.sup.4 being hydrogen, halogen or hydrocarbon, each hydrocarbon moiety containing from 1 to 7 carbon atoms; andR.sup.6 is H or NH.sub.2.

    Controlled site epitaxial sensitization
    86.
    发明授权
    Controlled site epitaxial sensitization 失效
    受控局部外延敏化

    公开(公告)号:US4435501A

    公开(公告)日:1984-03-06

    申请号:US431855

    申请日:1982-09-30

    申请人: Joe E. Maskasky

    发明人: Joe E. Maskasky

    IPC分类号: G03C1/005 G03C1/02

    CPC分类号: G03C1/0051

    摘要: High aspect ratio tabular grain silver halide emulsions, photographic elements incorporating these emulsions, and processes for the use of the photographic elements are disclosed. In the tabular grain emulsions the silver halide grains having a thickness of less than 0.5 micron (preferably less than 0.3 micron) and a diameter of at least 0.6 micron have a high aspect ratio and account for at least 50 percent of the total projected area of the silver halide grains present. Silver salt is epitaxially located on and substantially confined to selected surface sites of the tabular silver halide grains.

    摘要翻译: 公开了高纵横比的片状颗粒卤化银乳剂,并入这些乳液的照相元件,以及使用照相元件的方法。 在片状颗粒乳剂中,厚度小于0.5微米(优选小于0.3微米)和直径至少为0.6微米的卤化银颗粒具有高纵横比,并占总投影面积的至少50% 存在卤化银颗粒。 银盐外延地位于并且基本上限制在片状卤化银颗粒的选定表面位置上。

    Silver chloride emulsions of modified crystal habit and processes for
their preparation
    87.
    发明授权
    Silver chloride emulsions of modified crystal habit and processes for their preparation 失效
    改性晶体习惯的氯化银乳剂及其制备方法

    公开(公告)号:US4400463A

    公开(公告)日:1983-08-23

    申请号:US431455

    申请日:1982-09-30

    申请人: Joe E. Maskasky

    发明人: Joe E. Maskasky

    摘要: Radiation-sensitive photographic emulsions are disclosed comprised of a dispersing medium and silver halide grains the halide content of which is at least 50 mole percent chloride, based on silver. The silver halide grains include tabular grains having a thickness of less than 0.5 micron, a diameter of at least 0.6 micron, and an average aspect ratio greater than 8:1 which account for at least 50 percent of the total projected area of the silver halide grains. The tabular grains have two opposed substantially parallel major crystal faces lying in {111} crystal planes and exhibiting at least one of the following features: (1) at least one peripheral edge lying parallel to a crystallographic vector lying in the plane of one of the major faces and (2) bromide and/or iodide incorporated in a central grain region. The tabular grains are formed in the presence of an aminoazaindene and a peptizer having a thioether linkage.

    摘要翻译: 公开了辐射敏感的感光乳剂,其包含基于银的卤化物含量为至少50摩尔%氯化物的分散介质和卤化银颗粒。 卤化银颗粒包括厚度小于0.5微米,直径至少为0.6微米,平均长宽比大于8:1的片状颗粒,其占卤化银总投影面积的至少50% 谷物。 片状晶粒具有位于{111}晶面中的两个相对的基本上平行的主晶面并且具有以下特征中的至少一个:(1)平行于位于平面中的<211>晶体矢量的至少一个周边边缘 主要面之一和(2)掺入中心颗粒区域的溴化物和/或碘化物。 在具有硫醚键的氨基吖辛烯和胶溶剂的存在下形成片状颗粒。

    Processes for producing positive or negative dye images using high
iodide silver halide emulsions
    88.
    发明授权
    Processes for producing positive or negative dye images using high iodide silver halide emulsions 失效
    使用高碘化银卤化物乳剂产生正或负染料影像的方法

    公开(公告)号:US4158565A

    公开(公告)日:1979-06-19

    申请号:US874600

    申请日:1978-02-02

    申请人: Joe E. Maskasky

    发明人: Joe E. Maskasky

    IPC分类号: G03C1/035 G03C7/30 G03C7/00

    摘要: Processes are disclosed for producing dye images employing photographic elements which comprise a support and coated thereon, at least one radiation-sensitive colorforming layer unit. This layer unit includes a substantially uniform distribution of catalyst and a radiationsensitive, high iodide silver halide emulsion. A first method for producing dye images after imagewise exposure of the photographic element comprises the steps of imagewise poisoning the catalyst with iodide ion by developing the silver iodide containing silver halide emulsion and thereafter employing the remaining unpoisoned catalyst to permit a redox reaction between a peroxide oxidizing agent and a dye-image-generating reducing agent. In a preferred element the high iodide silver halide emulsion is comprised of multifaceted, radiation-receptive silver iodide crystals and silver chloride crystals forming epitaxial junctions with the silver iodide crystals. A dye image of opposite sense can be produced using the preferred element by the steps of poisoning the catalyst; selectively developing the silver chloride portion of the silver halide emulsion; and amplifying the resulting silver image using the peroxy redox amplification reaction.

    摘要翻译: 公开了用于生产染料图像的方法,所述染料图像使用包含载体并涂覆在其上的照相元件,至少一个辐射敏感着色形成层单元。 该层单元包括基本均匀的催化剂分布和辐射敏感的高碘化物卤化银乳剂。 用于在照相元件成像曝光之后生成染料图像的第一种方法包括以下步骤:通过显影含有碘化银乳剂的碘化银离子来形成图像中毒催化剂,然后使用剩余的未经过介质的催化剂以使过氧化物氧化 试剂和产生染料影像的还原剂。 在优选的元素中,高碘化物卤化银乳剂由多面体,辐射接受碘化银晶体和与碘化银晶体形成外延结的氯化银晶体组成。 使用优选元素可以通过使催化剂中毒的步骤来产生相反感的染料图像; 选择性地显影卤化银乳剂的氯化银部分; 并使用过氧氧化还原扩增反应扩增得到的银影像。