公开(公告)号：US06268403B1

公开(公告)日：2001-07-31

申请号：US09637954

申请日：2000-08-11

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08G5920

CPC classification number: C08G59/68 ,  B33Y70/00 ,  C08G65/105 ,  C08G65/22

Abstract: A method of accelerating the cure rate of an epoxy curing composition includes combining a cycloaliphatic epoxyalcohol monomer, a non-hydroxyl-containing epoxy monomer and a cationic photoinitiator to form an epoxy curing composition, and exposing the curing composition to a source of radiation. The resulting polymers and copolymers are branched polyethers containing hydroxyl functionality.

Abstract translation: 一种加速环氧固化组合物固化速率的方法包括组合环脂族环氧醇单体，非含羟基环氧单体和阳离子光引发剂以形成环氧固化组合物，并将固化组合物暴露于辐射源。 所得的聚合物和共聚物是含有羟基官能团的支链聚醚。

公开(公告)号：US06075155A

公开(公告)日：2000-06-13

申请号：US102448

申请日：1998-06-22

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C07D303/22 ,  C07D493/10 ,  C08F2/46 ,  C08G59/24 ,  C08G59/32 ,  C08G65/14 ,  C08G65/22 ,  G03F7/038 ,  C07D303/06 ,  C07D303/00 ,  C07D307/02 ,  C07D315/00 ,  C07D493/00

CPC classification number: C07D303/22 ,  C07D493/10 ,  C08G59/24 ,  C08G59/3218 ,  C08G65/14 ,  C08G65/22 ,  G03F7/038

Abstract: Disclosed are compounds of the formulas ##STR1## which are useful as monomers in photopolymerizable compositions. Also disclosed are methods of polymerizing these monomers, and polymers produced thereby.

Abstract translation: 公开了在光聚合组合物中可用作单体的式的化合物。 还公开了聚合这些单体的方法和由此制备的聚合物。

公开(公告)号：US5747172A

公开(公告)日：1998-05-05

申请号：US521234

申请日：1995-08-30

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C09K3/00 ,  C07F7/08 ,  C07F7/21 ,  C08G77/38 ,  C08L83/04 ,  C08L83/06 ,  C09D183/06 ,  C09J7/02 ,  B32B9/04

CPC classification number: C08G77/38 ,  C09D183/06 ,  Y10T428/31663

Abstract: Silicone release agents comprising propenyl-ether functionalized silicones exhibit a rapid cationic induce photo-cure. Such propenyl-ether functionalized silicones are synthesized by the hydrosilation of various .alpha.-allyloxy-.omega.-(1-propenoxy) alkanes with various linear and cyclic hydrogen functional siloxanes.

Abstract translation: 包含丙烯基醚官能化硅氧烷的硅酮脱模剂显示快速阳离子诱导光固化。 这种丙烯基醚官能化的硅氧烷通过各种α-烯丙氧基-ω-（1-丙烯氧基）烷烃与各种线性和环状氢官能硅氧烷的氢化硅烷化而合成。

公开(公告)号：US5446172A

公开(公告)日：1995-08-29

申请号：US769520

申请日：1991-10-02

Applicant: James V. Crivello ,  Julia L. Lee

Inventor： James V. Crivello ,  Julia L. Lee

IPC: C07F9/206 ,  C07C381/12 ,  C07F9/90 ,  C08G59/68 ,  C07D333/34

CPC classification number: C07C381/12

Abstract: A method for making a triarylsulfonium hexafluoro metal or metalloid salt is provided by effecting reaction between a diarylsulfoxide and an aromatic substrate, such as an arylalkylether in the presence of a solution of phosphorus pentoxide and methanesulfonic acid to produce a triarylsulfonium complex. A metathesis of the resulting triarylsulfonium complex is effected with an alkali metal hexafluoro metal or metalloid salt.

Abstract translation: 制备三芳基锍六氟金属或准金属盐的方法是通过在五氧化二磷和甲磺酸溶液的存在下，通过在二芳基亚砜和芳基底物（如芳基烷基醚）之间的反应产生三芳基锍络合物而提供的。 所得三芳基锍络合物的复分解是用碱金属六氟金属或准金属盐进行的。

公开(公告)号：US5362607A

公开(公告)日：1994-11-08

申请号：US195275

申请日：1994-02-14

Applicant: James V. Crivello ,  Michael J. O'Brien ,  Julia L. Lee

Inventor： James V. Crivello ,  Michael J. O'Brien ,  Julia L. Lee

IPC: G03F7/004 ,  G03F7/30 ,  G03F7/38 ,  G03F7/40

CPC classification number: G03F7/0045

Abstract: A method for preparing a positive photoresist substrate composite is provided which can be used in the presence or absence of atmospheric moisture. There is used a major amount of a commercially available resin, such as a novolak, a dissolution inhibitor with thermally labile t-butyl ether or ester groups, and an aryl onium salt.

Abstract translation: 提供一种制备正性光致抗蚀剂基材复合材料的方法，其可用于存在或不存在大气湿气。 使用主要量的市售树脂，例如酚醛清漆，具有热不稳定的叔丁基醚或酯基的溶解抑制剂和芳基鎓盐。

公开(公告)号：US5274148A

公开(公告)日：1993-12-28

申请号：US926426

申请日：1992-08-10

Applicant: James A. Dougherty ,  James V. Crivello

Inventor： James A. Dougherty ,  James V. Crivello

IPC: C07C323/20 ,  C07C381/12 ,  C07F9/90 ,  C07F9/92 ,  C08F2/00 ,  C08F2/48 ,  C08F2/54 ,  C08F4/00 ,  C09D5/20 ,  G03F7/029 ,  C07F9/02

CPC classification number: G03F7/029 ,  C07C381/12 ,  C07F9/902

Abstract: This invention relates to C.sub.14 to C.sub.20 alkoxy monophenyl sulfonium salt initiators having the formula ##STR1## wherein R is C.sub.14 to C.sub.20 alkyl; R.sub.1 and R.sub.2 are each independently C.sub.4 to C.sub.20 alkyl and X.sup.- is a non-basic, nonnucleophilic anion, which initiators are employed in the polymerization of mono- and poly- functional glycidyl ethers, alpha-olefin oxides and vinyl monomers or oligomers.

Abstract translation: 本发明涉及具有下式的C14至C20烷氧基单苯基锍盐引发剂：其中R为C14至C20烷基; R1和R2各自独立地为C4至C20烷基，X-是非碱性，非亲核阴离子，其引发剂用于单官能和多功能缩水甘油醚，α-烯烃氧化物和乙烯基单体或低聚物的聚合。

公开(公告)号：US5189191A

公开(公告)日：1993-02-23

申请号：US883733

申请日：1992-05-15

Applicant: Gary W. Yeager ,  James V. Crivello

Inventor： Gary W. Yeager ,  James V. Crivello

IPC: C08G64/08 ,  C08G64/18

CPC classification number: C08G64/085 ,  C08G64/08 ,  C08G64/18

Abstract: Bisphenols containing free-radical generating groups, such as bissilylpinacolate groups, are provided. These bisphenols can be used to make free-radical generating polycarbonate macroinitiators having thermally labile groups which can be heated with vinyl monomers, such as styrene to make polycarbonate block copolymers.

Abstract translation: 提供了含有自由基生成基团的双酚，例如双联苯二酚基辛酸酯基团。 这些双酚可用于制备具有热不稳定基团的自由基产生聚碳酸酯大分子引发剂，其可用乙烯基单体如苯乙烯加热以制备聚碳酸酯嵌段共聚物。

公开(公告)号：US5128431A

公开(公告)日：1992-07-07

申请号：US473802

申请日：1990-02-02

Applicant: Karen D. Riding ,  James V. Crivello ,  Julia L. Lee

Inventor： Karen D. Riding ,  James V. Crivello ,  Julia L. Lee

IPC: C08G59/68 ,  C08G65/16 ,  C08G77/48 ,  C08G77/50 ,  C08K5/5419 ,  C08K5/549 ,  C08L83/04 ,  C08L83/06

CPC classification number: C08K5/5419 ,  C08G59/68 ,  C08G65/16 ,  C08K5/549 ,  C08L83/06

Abstract: There is provided a curable composition, comprising:A. a heterocyclic compound selected from the group consisting of epoxy-functional silicones, epoxy-functional acrylic polymers, and monomers selected from the group consisting of tetrahydrofurans, oxetanes, lactones, spirocarbonates, spiroesters, cyclic sulfur and cyclic nitrogen compounds;B. an Si-H functional silicon compound; andC. a platinum catalyst.There is further provided a method for polymerizing a heterocyclic compound using a platinum catalyst.

Abstract translation: 提供了一种可固化组合物，其包含：A.选自环氧官能硅氧烷，环氧官能丙烯酸聚合物和选自四氢呋喃，氧杂环丁烷，内酯，螺环碳酸酯，螺环酯，环状 硫和环状氮化合物; B.一种Si-H官能化硅化合物; 和C.一种铂催化剂。 还提供了使用铂催化剂使杂环化合物聚合的方法。

公开(公告)号：US5064882A

公开(公告)日：1991-11-12

申请号：US645778

申请日：1991-01-25

Applicant: Erik W. Walles ,  John H. Lupinski ,  James V. Crivello

Inventor： Erik W. Walles ,  John H. Lupinski ,  James V. Crivello

IPC: C08G59/68 ,  C08K3/36 ,  H01B3/40

CPC classification number: H01B3/40 ,  C08G59/68 ,  C08K3/36

Abstract: A heat curable composition is provided which is useful for encapsulating microelectronic devices using a heat curable epoxy composition having a diaryliodonium hexafluoroantimonate salt as a catalyst in combination with an effective amount of a free radical generating aromatic compound as a cocatalyst.

Abstract translation: 提供了一种热固化性组合物，其可用于使用具有二芳基碘鎓六氟锑酸盐作为催化剂的热固化性环氧组合物与有效量的产生自由基的芳族化合物作为助催化剂组合来封装微电子器件。

公开(公告)号：US4992571A

公开(公告)日：1991-02-12

申请号：US429744

申请日：1989-10-31

Applicant: James M. Fukuyama ,  Julia L. Lee ,  James V. Crivello

Inventor： James M. Fukuyama ,  Julia L. Lee ,  James V. Crivello

IPC: B01J31/02 ,  C07B61/00 ,  C07C41/01 ,  C07C43/225 ,  C07F9/90

CPC classification number: C07F9/902 ,  C07C43/225

Abstract: A one pot method is provided for preparing an (octyloxyphenyl) phenyliodonium tosylate and the corresponding hexafluorometalloid salt. n-Octylphenyl ether is initially prepared using a halooctane and phenol in the presence of a phase transfer catalyst followed by the addition of iodobenzene, a peracid, and p-toluene sulfonic acid. The resulting (octyloxyphenyl)phenyl iodonium tosylate can be directly metathesized after an optional treatment step with an alkali metal hexafluoroantimonate salt. The (octyloxyphenyl)phenyl iodonium hexafluorometalloid salt can be used as a photoinitiator for UV curable organic materials such as epoxy resins.