公开(公告)号：US09650250B2

公开(公告)日：2017-05-16

申请号：US14416495

申请日：2013-07-24

申请人： NIPPON SODA CO., LTD.

发明人： Michiaki Maruyama

IPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0568 ,  H01M10/0567

CPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0567 ,  H01M10/0568

摘要： The present invention provides an industrially advantageous method for producing bis(halosulfonyl)amine that makes it possible to inhibit the rapid generation of gas and reduce the amount of halogenating agent used by controlling the reaction rate among sulfamic acid, the halogenating agent and a halosulfonic acid to nearly a constant rate from the initial stage to the final stage of the reaction. The method for producing bis(halosulfonyl)amine of the present invention allows the obtaining of a bis(halosulfonyl)amine such as N-(fluorosulfonyl)-N-(chlorosulfonyl)amine or bis(chlorosulfonyl)amine by a production method that includes heating a mixture containing sulfamic acid and a halosulfonic acid to a temperature higher than room temperature, adding a halogenating agent thereto, and allowing to react while adjusting to a prescribed temperature.

公开(公告)号：US20160308247A1

公开(公告)日：2016-10-20

申请号：US15101149

申请日：2014-12-03

申请人： RHODIA OPERATIONS

发明人： Olivier BUISINE

IPC分类号： H01M10/0568 ,  C01B21/086 ,  C01B21/093

CPC分类号： H01M10/0568 ,  C01B21/086 ,  C01B21/093 ,  C01B21/0935 ,  H01M2300/0025

摘要： The invention relates to a method for preparing bis(fluorosulfonyl)imide acid, comprising: the reaction of sulphamic acid or one of the salts thereof with a halogenosulfuric acid and at least one fluorinating agent selected from SOF2, F—SO2—F and SF4, and the subsequent recovery of bis(fluorosulfonyl)imide acid. The invention also relates to a method for producing salts of bis(fluorosulfonyl)imide from the bis(fluorosulfonyl)imide acid thus produced.

摘要翻译： 本发明涉及一种制备双（氟磺酰基）酰亚胺酸的方法，包括：将氨基磺酸或其盐之一与卤代硫酸和至少一种选自SOF 2，F-SO 2 -F和SF 4的氟化剂反应， 并随后回收双（氟磺酰基）酰亚胺酸。 本发明还涉及由此制备的双（氟磺酰基）酰亚胺生产双（氟磺酰基）酰亚胺盐的方法。

公开(公告)号：US20160016797A1

公开(公告)日：2016-01-21

申请号：US14773964

申请日：2014-03-05

申请人： NIPPON SODA CO., LTD.

发明人： Hideki Maekawa ,  Masamichi Yasuhara ,  Ken-ichi Hayashi

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C07C303/40 ,  C07C311/48 ,  H01M10/0525 ,  H01M10/0568

摘要： The present invention provides a method for producing a disulfonylamine alkali metal salt, including a step of subjecting a disulfonylamine onium salt represented by formula [I] (wherein each of R1 and R2 independently represents a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms, provided that at least one of R1 and R2 represents a fluorine atom, and each of R3, R4, R5 and R6 independently represents a hydrogen atom or the like) to a cation exchange reaction in an organic solvent, thereby producing a disulfonylamine alkali metal salt represented by formula [II] (wherein M+ represents an alkali metal cation, and R1 and R2 are as defined in formula [I]), and a step of filtering the organic solvent solution containing the disulfonylamine alkali metal salt through a filter having a particle retention size of 0.1 to 10 μm to obtain a filtrate.

摘要翻译： 本发明提供了制备二磺酰胺碱金属盐的方法，包括使式[I]表示的二磺酰胺鎓盐（其中R 1和R 2各自独立地表示氟原子或具有1〜6个氟代烷基的步骤） 碳原子，条件是R 1和R 2中的至少一个表示氟原子，并且R 3，R 4，R 5和R 6各自独立地表示氢原子等）与有机溶剂中的阳离子交换反应，从而制备二磺酰胺 由式[II]表示的碱金属盐（其中M +表示碱金属阳离子，R 1和R 2如式[I]中所定义），以及通过过滤器过滤含有二磺酰胺碱金属盐的有机溶剂溶液的步骤 保持粒径为0.1〜10μm，得到滤液。

公开(公告)号：US09233849B2

公开(公告)日：2016-01-12

申请号：US13985915

申请日：2012-02-28

申请人： Shiro Tsubokura ,  Toru Suzuki ,  Michiaki Maruyama ,  Yasuyuki Aiura

发明人： Shiro Tsubokura ,  Toru Suzuki ,  Michiaki Maruyama ,  Yasuyuki Aiura

IPC分类号： C07C303/40 ,  C01B21/087 ,  C01B21/093 ,  C01B21/086

CPC分类号： C01B21/086 ,  C01B21/087 ,  C01B21/093 ,  C07C303/40 ,  C07C311/48

摘要： By reacting a fluorine-containing sulfonylimide ammonium salt such as ammonium N,N-di(fluorosulfonyl)imide with an alkali metal hydroxide such as lithium hydroxide, potassium hydroxide or sodium hydroxide under reduced pressure and at a low temperature of approximately 40° C., a fluorine-containing sulfonylimide alkali metal salt such as lithium N,N-di(fluorosulfonyl)imide, potassium N,N-di(fluorosulfonyl)imide or sodium N,N-di(fluorosulfonyl)imide is obtained.

摘要翻译： 使N，N-二（氟磺酰基）酰亚胺铵等含氟磺酰亚胺铵盐与碱金属氢氧化物如氢氧化锂，氢氧化钾或氢氧化钠在减压下和约40℃的低温下反应。 得到N，N-二（氟磺酰基）酰亚胺锂，N，N-二（氟磺酰基）酰亚胺钾，N，N-二（氟磺酰基）酰亚胺钠等含氟磺酰亚胺碱金属盐。

公开(公告)号：US20150175422A1

公开(公告)日：2015-06-25

申请号：US14416495

申请日：2013-07-24

申请人： NIPPON SODA CO., LTD.

发明人： Michiaki Maruyama

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0567 ,  H01M10/0568

摘要： The present invention provides an industrially advantageous method for producing bis(halosulfonyl)amine that makes it possible to inhibit the rapid generation of gas and reduce the amount of halogenating agent used by controlling the reaction rate among sulfamic acid, the halogenating agent and a halosulfonic acid to nearly a constant rate from the initial stage to the final stage of the reaction. The method for producing bis(halosulfonyl)amine of the present invention allows the obtaining of a bis(halosulfonyl)amine such as N-(fluorosulfonyl)-N-(chlorosulfonyl)amine or bis(chlorosulfonyl)amine by a production method that includes heating a mixture containing sulfamic acid and a halosulfonic acid to a temperature higher than room temperature, adding a halogenating agent thereto, and allowing to react while adjusting to a prescribed temperature.

摘要翻译： 本发明提供了一种工业上有利的双（卤代磺酰基）胺的制备方法，其可以通过控制氨基磺酸，卤化剂和卤代磺酸之间的反应速率来抑制气体的快速产生和减少所用的卤化剂的量 从初始阶段到反应的最后阶段几乎恒定的速率。 本发明的双（卤代磺酰基）胺的制备方法可以通过包括加热的制备方法得到双（卤代磺酰基）胺如N-（氟磺酰基）-N-（氯磺酰基）胺或双（氯磺酰基）胺 将含有氨基磺酸和卤代磺酸的混合物加热至高于室温的温度，向其中加入卤化剂，并允许在调节至规定温度下反应。

公开(公告)号：US20140241973A1

公开(公告)日：2014-08-28

申请号：US14352175

申请日：2012-09-25

申请人： SUMITOMO ELECTRIC INDUSTRIES, LTD.

发明人： Atsushi Fukunaga ,  Shinji Inazawa ,  Koji Nitta ,  Shoichiro Sakai

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C01D13/00

摘要： A mixture of sulphamic acid, a halogenated sulphonic acid and thionyl chloride is heated to allow the reaction to proceed, to thereby produce first intermediate products. The first intermediate products are then subjected to reaction with an alkali metal fluoride MF to produce second intermediate products. The second intermediate products is then subjected to reaction with the alkali metal fluoride MF in a polar solvent to obtain a desired product MN(SO2F)2 (where M is an alkali metal).

摘要翻译： 将氨基磺酸，卤代磺酸和亚硫酰氯的混合物加热以使反应进行，从而产生第一中间产物。 然后将第一中间产物与碱金属氟化物MF反应以产生第二中间产物。 然后将第二中间产物在极性溶剂中与碱金属氟化物MF反应，得到所需产物MN（SO2F）2（其中M为碱金属）。

公开(公告)号：US20140142338A1

公开(公告)日：2014-05-22

申请号：US14081817

申请日：2013-11-15

申请人： Trinapco, Inc.

发明人： Martin R. Johnson

IPC分类号： C07C209/68

CPC分类号： C07C311/48 ,  C01B21/086 ,  C07C209/68 ,  C07C211/63

摘要： The present invention is directed to methods comprising adding ammonia, either as an ammonium salt or as a gas at pressures below 0.01 MPa, to a sulfuryl fluoride solution to form the anion of bis(fluorosulfonyl)amine under conditions well suited for large-scale production. The bis(fluorosulfonyl)amine so produced can be isolated by methods described in the prior art, or isolated as an organic ion pair, such as an alkylammonium solid salt, or as an ionic liquid.

摘要翻译： 本发明涉及包括在低于0.01Mpa的压力下将氨作为铵盐或作为气体加入到硫酰氟溶液中以在适合于大规模生产的条件下形成双（氟磺酰基）胺的阴离子的方法 。 如此生产的双（氟磺酰基）胺可以通过现有技术中描述的方法分离，或分离为有机离子对，如烷基铵固体盐，或作为离子液体。

公开(公告)号：US20070043231A1

公开(公告)日：2007-02-22

申请号：US11465954

申请日：2006-08-21

申请人： Amer Hammami ,  Benoit Marsan

发明人： Amer Hammami ,  Benoit Marsan

IPC分类号： C07F7/10 ,  C01B21/00

CPC分类号： C01B21/0935 ,  C01B21/086 ,  C07C311/48

摘要： There are provided processes for preparing compounds of formula (I): wherein each of the R1 is independently F, Cl, Br, or I; and R2 is H, Li, Na, K, or Cs. The processes are particularly useful for preparing compounds used in the field of electrochemistry.

摘要翻译： 提供制备式（I）化合物的方法：其中R 1和R 2各自独立地为F，Cl，Br或I; R 2是H，Li，Na，K或Cs。 该方法特别适用于制备电化学领域中使用的化合物。

公开(公告)号：US5441720A

公开(公告)日：1995-08-15

申请号：US93422

申请日：1993-07-13

申请人： William M. Koppes ,  Michael E. Sitzmann

发明人： William M. Koppes ,  Michael E. Sitzmann

IPC分类号： C01B21/086 ,  C06B25/34 ,  C06B31/00 ,  C06B41/00 ,  C01B17/45

CPC分类号： C06B25/34 ,  C01B21/086 ,  C06B31/00 ,  C06B41/00

摘要： A pentafluorosulfanylnitramide salt that is ammonium pentafluorosulfanylnamide, sodium pentafluorosulfanylnitramide, potassium pentafluorosulfanylnitramide, lithium pentafluorosulfanylnitramide, or cesium pentafluorosulfanylnitramide. These salts are useful as energetic oxidizers in explosives and propellants.

摘要翻译： 五氟硫烷基硝酰胺铵，五氟硫代硫酰胺，五氟硫代硫酰胺，五氟硫代硫酰胺，五氟硫代硫酰胺等五氟硫烷基二胺盐。 这些盐可用作爆炸物和推进剂中的高能氧化剂。

公开(公告)号：US4268491A

公开(公告)日：1981-05-19

申请号：US88813

申请日：1979-10-26

申请人： Arthur J. Banister ,  Andrew J. Fielder ,  Zdenek V. Hauptman ,  Nigel R. M. Smith

发明人： Arthur J. Banister ,  Andrew J. Fielder ,  Zdenek V. Hauptman ,  Nigel R. M. Smith

IPC分类号： C01B21/086 ,  C01B17/00 ,  C01B17/45

CPC分类号： C01B21/086 ,  C01B21/0865 ,  Y10S505/81 ,  Y10S505/815

摘要： Compounds containing sulphur-nitrogen groups, such as S.sub.4 N.sub.4, S.sub.5 N.sub.5.sup.+ salts and poly(sulphur nitride), are made by reducing S.sub.4 N.sub.3 Cl or related compounds with anions (e.g. iodide) or metals (e.g. silver). Poly(sulphur nitride) may be made by passing S.sub.4 N.sub.3 Cl vapor or S.sub.5 N.sub.5 FeCl.sub.4 vapor through sulphidized silver wool and condensing the vapor.

摘要翻译： 通过用阴离子（例如碘化物）或金属（例如银）还原S4N3Cl或相关化合物制备含有硫 - 氮基团的化合物，例如S4N4，S5N5 +盐和聚（硫氮化物）。 聚（硫氮化物）可以通过使S4N3Cl蒸汽或S5N5FeCl4蒸气通过硫化银羊毛并冷凝蒸气来制备。