公开(公告)号：US20080275183A1

公开(公告)日：2008-11-06

申请号：US12111249

申请日：2008-04-29

申请人： Robert Q. Kluttz ,  Keith E. Stephens

发明人： Robert Q. Kluttz ,  Keith E. Stephens

IPC分类号： C08L95/00

CPC分类号： C08L95/00 ,  C08F297/04 ,  C08F297/044 ,  C08L53/02 ,  C08L2555/22 ,  C08L2555/84 ,  C08L2666/02 ,  C08L2666/24

摘要： The present invention is directed to a process for preparing a polymer modified bituminous binder composition in the substantial absence of crosslinking agents by heating a bitumen component in a stirred tank to a temperature from 160° C. to 221° C.; adding a block copolymer composition to the bitumen component while the bitumen component is being stirred to form a homogeneous mixture of the bitumen component and the block copolymer composition; and continuing to stir the homogeneous mixture while maintaining the temperature from 180° C. to 221° C. for a total period of time from 4 hours to 30 hours thereby forming a cured polymer modified bituminous binder composition. The block copolymer composition utilized in the process comprises one or more block copolymers having at least one monovinylaromatic block and either (I) at least one polybutadiene block having a vinyl content of less than 15 mol percent and at least one polybutadiene block having a vinyl content of greater than 25 mol percent or (II) at least one polybutadiene block having a vinyl content that tapers from a vinyl content of less than 15 mol percent at the first end adjacent to the monovinylaromatic block to a vinyl content that is greater than 25 mol percent at the second end which is furthest from the monovinylaromatic block and optionally at least one polybutadiene block having a vinyl content of less than 15 mol percent.The present invention is further related to an alternative to this process, a specific class of bituminous binder compositions and concentrates and a specific class of block copolymer compositions.

摘要翻译： 本发明涉及通过将搅拌釜中的沥青组分加热至160℃至221℃的温度，基本上不存在交联剂制备聚合物改性沥青粘合剂组合物的方法。 在沥青组分被搅拌以形成沥青组分和嵌段共聚物组合物的均匀混合物时，向沥青组分中加入嵌段共聚物组合物; 并继续搅拌均匀混合物，同时将温度保持在180℃至221℃，总时间为4小时至30小时，从而形成固化的聚合物改性沥青粘合剂组合物。 在该方法中使用的嵌段共聚物组合物包含一种或多种嵌段共聚物，其具有至少一个单乙烯基芳族嵌段和（I）至少一种乙烯基含量小于15摩尔％的聚丁二烯嵌段和至少一个具有乙烯基含量的聚丁二烯嵌段 大于25摩尔％或（II）至少一个聚乙烯基含量低于乙烯基含量小于15摩尔％的乙烯基含量的聚丁二烯嵌段在与单乙烯基芳族嵌段相邻的第一端成为大于25摩尔的乙烯基含量 在距离单乙烯基芳族嵌段最远的第二端和任选的至少一种乙烯基含量低于15摩尔％的聚丁二烯嵌段的百分比。 本发明还涉及该方法的替代方案，特定类型的沥青粘合剂组合物和浓缩物以及特定类型的嵌段共聚物组合物。

公开(公告)号：US20080258105A1

公开(公告)日：2008-10-23

申请号：US11547189

申请日：2005-03-22

申请人： Shizuo Kitahara

发明人： Shizuo Kitahara

IPC分类号： C08F210/16 ,  C09K3/00

CPC分类号： B01J20/26 ,  B01J20/264 ,  C08F8/46 ,  C08F8/48 ,  C08F297/02 ,  C08F297/04 ,  C08J5/18 ,  C08L53/02 ,  C08L2666/02

摘要： The invention provides a novel block copolymer which can significantly improve the adhesion between a molded product composed of a nonpolar polymer such as polypropylene or polyethylene and a coating material or a molded product composed of a polar polymer, as well as a method for producing the same. Disclosed is a block copolymer comprising at least one poly (aromatic vinyl) block having a weight-average molecular weight of 1,000 to 500,000 and at least one cyclized poly (conjugated diene) block, as well as an oxygen scavenger and a modifier for polymer molding material, which comprise the block copolymer as an active ingredient.

摘要翻译： 本发明提供了一种新颖的嵌段共聚物，其可以显着提高由聚丙烯或聚乙烯等非极性聚合物构成的成型体与涂料或者由极性聚合物构成的成型体的密合性，以及其制造方法 。 公开了包含至少一种重均分子量为1,000至500,000的聚（芳族乙烯基）嵌段和至少一个环化聚（共轭二烯）嵌段的嵌段共聚物，以及除氧剂和用于聚合物成型的改性剂 材料，其包含嵌段共聚物作为活性成分。

公开(公告)号：US07429549B2

公开(公告)日：2008-09-30

申请号：US10966192

申请日：2004-10-15

申请人： Adel Farhan Halasa ,  Wen-Liang Hsu

发明人： Adel Farhan Halasa ,  Wen-Liang Hsu

IPC分类号： B01J31/00

CPC分类号： C08F297/04 ,  C08F297/044

摘要： Rubbery polymers made by anionic polymerization can be coupled with tin halides or silicon halides to improve the characteristics of the rubber for use in some applications, such as fire treads. In cases where the rubbery polymer was synthesized utilizing a polar modifier it is difficult to attain a high level of coupling. This invention is based upon the unexpected finding that coupling efficiency can be significantly improved by conducting the coupling reaction in the presence of a lithium salt of a saturated aliphatic alcohol, such as lithium t-amylate. This invention discloses a process for coupling a living rubbery polymer that comprises reacting the living rubbery polymer with coupling agent selected from the group consisting of tin halides and silicon halides in the presence of a lithium salt of a saturated aliphatic alcohol. The lithium salt of the saturated aliphatic alcohol can be added immediately prior to the coupling reaction or it can be present throughout the polymerization and coupling process. Lithium t-amylate reacts with water to form t-amyl alcohol during steam stripping. Since t-amyl alcohol forms an azeotrope with hexane, it co-distills with hexane and can contaminate recycle feed streams. This problem of recycle stream contamination can be solved by using metal salts of cyclic alcohols that do not co-distill with hexane or form compounds during steam stripping which co-distill with hexane. Thus, the use of metal salts of cyclic alcohols is preferred for this reason and because they are considered to be environmentally safe.

摘要翻译： 通过阴离子聚合制备的橡胶聚合物可与锡卤化物或卤化硅偶联，以改善用于某些应用中的橡胶的特性，例如防火踏面。 在使用极性改性剂合成橡胶状聚合物的情况下，难以获得高水平的偶联。 本发明基于意想不到的发现，通过在饱和脂肪醇的锂盐如叔戊醇锂的存在下进行偶联反应可以显着改善偶联效率。 本发明公开了一种使活性橡胶状聚合物偶合的方法，其包括在饱和脂肪醇的锂盐存在下使活性橡胶状聚合物与选自锡卤化物和卤化硅的偶联剂反应。 饱和脂肪醇的锂盐可以在偶联反应之前立即加入，或者可以在整个聚合和偶联过程中存在。 在蒸汽汽提期间，叔戊醇钠与水反应形成叔戊醇。 由于叔戊醇与己烷形成共沸物，因此与己烷共蒸馏，可能污染再循环进料流。 循环流污染的这个问题可以通过使用在与汽油共蒸馏的汽提过程中不与己烷共蒸馏或形成化合物的环醇的金属盐来解决。 因此，由于这个原因，优选使用环状醇的金属盐，并且因为它们被认为是环境安全的。

公开(公告)号：US20080200602A1

公开(公告)日：2008-08-21

申请号：US12101368

申请日：2008-04-11

申请人： Toshihiro TADAKI ,  Naokazu Kobayashi ,  Iwakazu Hattori

发明人： Toshihiro TADAKI ,  Naokazu Kobayashi ,  Iwakazu Hattori

IPC分类号： C08K3/04 ,  C08K3/36

CPC分类号： C08F297/046 ,  C08F8/04 ,  C08F297/04

摘要： An objective of the present invention is to provide a block copolymer which is excellent in processability at the time of preparing a rubber composition and leads to a cross-linked rubber composition excellent in tensile property, wearing resistance, weatherability, ozone resistance and heat aging resistance when it is cross-linked, a rubber composition containing the block copolymer and a molded product. The block copolymer of the present invention comprises two polymer blocks each having an ethylenic unsaturated bond and other polymer block which is interposed between two polymer blocks, has a uniform weight average molecular weight in the range from 5,000 to 100,000. The weight average molecular weight of the polymer block having the ethylenic unsaturated bond is preferably in the range from 1,000 to 20,000.

公开(公告)号：US20080194716A1

公开(公告)日：2008-08-14

申请号：US12078571

申请日：2008-04-01

申请人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeki Takayama ,  Shigeru Sasaki ,  Katsumi Suzuki ,  Takahiro Hisasue ,  Kazuo Moritou

发明人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeki Takayama ,  Shigeru Sasaki ,  Katsumi Suzuki ,  Takahiro Hisasue ,  Kazuo Moritou

IPC分类号： C08L53/00 ,  C09J4/00

CPC分类号： C08F8/04 ,  C08F297/04

摘要： A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan δ) is observed at −10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at −20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.

公开(公告)号：US20080161448A1

公开(公告)日：2008-07-03

申请号：US11617774

申请日：2006-12-29

申请人： Mark N. DeDecker

发明人： Mark N. DeDecker

IPC分类号： C08F36/04 ,  C08L57/00 ,  C08K5/101 ,  C08K3/22 ,  C08K5/09 ,  C08J3/00 ,  C08L55/00 ,  C08L33/02 ,  C08L33/04 ,  C07C53/00

CPC分类号： C08F279/02 ,  C08C19/44 ,  C08F297/02 ,  C08F297/04 ,  C08L9/00 ,  C08L15/00 ,  C08L19/006 ,  C08L33/20 ,  C08L35/06 ,  C08L51/003 ,  C08L51/04 ,  C08L53/02 ,  C08L55/02 ,  C08L2666/08 ,  C08L2666/02 ,  C08L2666/04

摘要： A composition includes a baleable polymer resulting from the polymerization of at least one conjugated diene in the presence of an anionic initiator. The baleable polymer has carboxylate termination resulting from the addition of carbon dioxide to terminate the polymerization reaction. The polymer has Mooney ML1+4 viscosity of >35 and a solution viscosity of X, where X is >75 cP. The addition of an lonolizer to a composition that includes the polymer reduces the solution viscosity of the polymer from X to Y where Y meets the following formula: 0.4X≦Y≧0.58X. The baleable polymer is blended with impact-modified plastics resulting in improved izod values and optical qualities. Processes for making and utilizing the polymer composition, and ionolizer are also described.

摘要翻译： 组合物包含由阴离子引发剂存在下由至少一种共轭二烯聚合得到的可熔聚合物。 可膨胀聚合物具有由于加入二氧化碳而终止聚合反应而产生的羧酸酯末端。 该聚合物的Mooney ML 1 + 4粘度> 35，溶液粘度为X，其中X> 75cP。 在包含聚合物的组合物中加入孤胶体将聚合物的溶液粘度从X降低到Y，其中Y满足以下公式：0.4X≤= 0.58X。 可折叠聚合物与冲击改性塑料混合，从而提高了izod值和光学质量。 还描述了制备和利用聚合物组合物和离子化器的方法。

公开(公告)号：US20080153971A1

公开(公告)日：2008-06-26

申请号：US11643225

申请日：2006-12-21

申请人： Lydia Ann Salazar

发明人： Lydia Ann Salazar

IPC分类号： C08L53/00

CPC分类号： C08F297/04 ,  C08F297/044 ,  C08L2666/02 ,  C08L2666/24 ,  C09J153/02

摘要： The invention relates to a solvent sprayable contact adhesive composition comprising (i) one or more styrenic block copolymer compositions, (ii) a tackifying resin, (iii) a solvent and (iv) optionally one or more plasticizers, wherein said styrenic block copolymer composition comprises: a. a tetra-branched block copolymer (IV) represented by the general formula (A-B)4X; b. a tri-branched block copolymer (III) represented by the general formula (A-B)3X; c. a di-branched block copolymer (II) represented by the general formula (A-B)2X; and d. a linear diblock copolymer (I) represented by the general formula A-B; where: i. A represents a polymer block of a mono alkenyl arene; ii. B represents a polymer block of a mixture of isoprene and 1,3-butadiene in a weight ratio of isoprene to butadiene between about 70:30 and 30:70; iii. X represents the residue of a multi-functional coupling agent; iv. the weight percent of A blocks is between about 15% and about 35%; v. the relative amounts of copolymers IV, III, II, and I are from 0 to 20 weight percent IV, from 0 to 80 weight percent II, from 0 to 80 weight percent II and from 10 to 65 weight percent I, where the total of I, II, III and IV equals 100 weight percent.

摘要翻译： 本发明涉及一种溶剂可喷雾接触粘合剂组合物，其包含（i）一种或多种苯乙烯类嵌段共聚物组合物，（ii）增粘树脂，（iii）溶剂和（iv）任选的一种或多种增塑剂，其中所述苯乙烯嵌段共聚物组合物 包括：a。 由通式（A-B）表示的四支链嵌段共聚物（Ⅳ） b。 由通式（A-B）3 X表示的三支链嵌段共聚物（III）; C。 由通式（A-B）2 X表示的二支链嵌段共聚物（II） 和d。 由通式A-B表示的直链二嵌段共聚物（I） 其中：i。 A表示单烯基芳烃的聚合物嵌段; ii。 B表示异戊二烯与1,3-丁二烯的混合物的聚合物嵌段，其异戊二烯与丁二烯的重量比为约70:30至30:70; iii。 X表示多官能偶联剂的残基; iv。 A块的重量百分比在约15％至约35％之间; v。共聚物IV，III，II和I的相对量为0至20重量％IV，0至80重量％II，0至80重量％II和10至65重量％I，其中 I，II，III和IV的总和等于100重量％。

公开(公告)号：US20080153970A1

公开(公告)日：2008-06-26

申请号：US11643106

申请日：2006-12-21

申请人： Lydia Ann Salazar

发明人： Lydia Ann Salazar

IPC分类号： C08L53/00

CPC分类号： C09J153/025 ,  C08F287/00 ,  C08F297/04 ,  C08F297/044 ,  C08L2666/02 ,  C08L2666/24 ,  C09J151/006

摘要： The invention relates to a solvent sprayable contact adhesive composition comprising (i) one or more styrenic block copolymer compositions, (ii) a tackifying resin, (iii) a solvent and (iv) optionally one or more plasticizers, wherein said styrenic block copolymer composition comprises a selectively hydrogenated and functionalized controlled distribution block copolymer having monoalkenyl arene end blocks and hydrogenated controlled distribution mid blocks containing certain mixtures of monoalkenyl arene and conjugated diene.

摘要翻译： 本发明涉及一种溶剂可喷雾接触粘合剂组合物，其包含（i）一种或多种苯乙烯类嵌段共聚物组合物，（ii）增粘树脂，（iii）溶剂和（iv）任选的一种或多种增塑剂，其中所述苯乙烯嵌段共聚物组合物 包括具有单烯基芳烃末端嵌段和含有某些单烯基芳烃和共轭二烯混合物的氢化控制分配中间嵌段的选择性氢化和官能化的控制分布嵌段共聚物。

公开(公告)号：US07390856B2

公开(公告)日：2008-06-24

申请号：US10362145

申请日：2001-08-24

申请人： Kimberly A Johnson ,  Wouter de Jong ,  David K. Schisla

发明人： Kimberly A Johnson ,  Wouter de Jong ,  David K. Schisla

IPC分类号： C08C19/02 ,  C08F236/10

CPC分类号： C08F297/04 ,  C08F8/04

摘要： Disclosed is a method for making selectively hydrogenated block copolymers of vinyl aromatic hydrocarbons and conjugated dienes comprising: a) anionically polymerizing vinyl aromatic hydrocarbons and conjugated dienes to produce block copolymers with living chain ends; b) terminating the living chain ends; to produce a terminated block copolymer, with a member from the group consisting of an alcohol, hydrogen, and mixtures thereof, to prepare a terminated block copolymer; and c) contacting the terminated block copolymers with hydrogen at a temperature of from 20 to 175° C. in the presence of a catalyst prepared by combining a cobalt carboxylate with an aluminum alkyl, wherein: (i) if the polymer is terminated with an alcohol and the alcohol is a linear alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ratio is from 0.05 to 1.2: (ii) if the polymer is terminated with an alcohol and the alcohol is a branched alcohol, the branched alcohol is used to terminate the living chain ends in an amount such that the alcohol:living chain end molar ration is from 0.05 to about 3.0: an (iii) if the polymer is terminated with an alcohol and the alcohol is a mixture of a linear alcohol and a branched alcohol, the linear alcohol is used to terminate the living chain ends in an amount such that the linear alcohol:living chain end molar ration is from 0.05 to 1.2.

摘要翻译： 公开了一种制备乙烯基芳烃和共轭二烯的选择性氢化嵌段共聚物的方法，包括：a）阴离子聚合乙烯基芳族烃和共轭二烯以产生具有活性链末端的嵌段共聚物; b）终止生命终端; 以制备封端的嵌段共聚物，其中包含醇，氢及其混合物的成员，以制备封端的嵌段共聚物; 和c）在通过将羧酸钴与烷基铝结合而制备的催化剂存在下，在20至175℃的温度下使封端的嵌段共聚物与氢接触，其中：（i）如果聚合物用 醇和醇是直链醇，直链醇用于终止活性链末端，使得醇：活性链末端摩尔比为0.05至1.2：（ii）如果聚合物用醇终止 并且醇是支链醇，支链醇用于终止活性链末端，其量使得醇：活性链末端摩尔比为0.05至约3.0：（iii）如果聚合物以 醇和醇是直链醇和支链醇的混合物，直链醇用于以直链醇：活性链末端摩尔比为0.05至1.2的量终止活性链末端。

公开(公告)号：US20080015306A1

公开(公告)日：2008-01-17

申请号：US11686188

申请日：2007-03-14

申请人： Kathryn Wright ,  Carl Willis ,  Tomomi Nishi ,  Norio Masuko ,  Dale Handlin ,  Robert Bening

发明人： Kathryn Wright ,  Carl Willis ,  Tomomi Nishi ,  Norio Masuko ,  Dale Handlin ,  Robert Bening

IPC分类号： C08L53/00

CPC分类号： C08L53/025 ,  C08F8/04 ,  C08F287/00 ,  C08F297/04 ,  C08L51/006 ,  C08L53/02 ,  C08L2666/02 ,  C08L2666/24

摘要： The present invention relates to novel compositions comprising (a) anionic block copolymers of mono alkenyl arenes and conjugated dienes where one of the blocks is a controlled distribution copolymer of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.

摘要翻译： 本发明涉及包含（a）单烯基芳烃和共轭二烯的阴离子嵌段共聚物的新型组合物，其中一个嵌段是共聚物嵌段中具有单体特异排列的共轭二烯和单烯基芳烃的受控分布共聚物 ，和（b）定制的软化改性剂具有导致组合物性能惊人改进的特定结构。 还包括用于制造这种新型组合物和各种最终用途和用于这种组合物的方法。