公开(公告)号：US20170062786A1

公开(公告)日：2017-03-02

申请号：US15120301

申请日：2015-02-19

申请人： The Regents of The University of Michigan

发明人： Nicholas A. KOTOV ,  Siu-On TUNG ,  Szu-Shen HO ,  Samantha RAHMANI

IPC分类号： H01M2/16 ,  H01M8/18 ,  H01M10/0525 ,  H01M8/20 ,  H01M2/14 ,  H01M4/38

CPC分类号： H01M2/1686 ,  H01M2/145 ,  H01M2/162 ,  H01M4/382 ,  H01M8/188 ,  H01M8/20 ,  H01M10/052 ,  H01M10/0525 ,  Y02E60/528 ,  Y02T10/7011

摘要： Ion conducting membranes based on aramid nanofibers (ANFs) can be prepared using layer-by-layer assembly, sol-gel processing, evaporation, spin coating, doctor blading, or other methods. Porosity is controlled through choice of additives and processing.

摘要翻译： 基于芳族聚酰胺纳米纤维（ANF）的离子导电膜可以使用逐层组装，溶胶 - 凝胶加工，蒸发，旋涂，刮涂或其它方法制备。 通过选择添加剂和加工来控制孔隙度。

公开(公告)号：US20170033389A1

公开(公告)日：2017-02-02

申请号：US15148048

申请日：2016-05-06

申请人： 24M Technologies, Inc.

发明人： Yet-Ming CHIANG ,  Mihai DUDUTA ,  Richard HOLMAN ,  Pimpa LIMTHONGKUL ,  Taison TAN

IPC分类号： H01M8/18 ,  H01M8/20

CPC分类号： H01M8/188 ,  H01M4/382 ,  H01M4/62 ,  H01M8/20 ,  H01M10/36

摘要： Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 μm to about 2,000 μm, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.

摘要翻译： 本文所述的实施方案一般涉及具有高速率能力的电化学电池，更具体地涉及生产具有相对较厚的半固体电极的高容量和高速率电池的装置，系统和方法。 在一些实施例中，电化学电池包括阳极和半固体阴极。 半固体阴极包括活性材料的悬浮液，其活性物质的量为活性物质的约35体积％至约75体积％，非水电解液中的导电材料为约0.5体积％至约8体积％。 离子透过膜设置在阳极和半固体阴极之间。 半固体阴极具有约250μm至约2,000μm的厚度，并且电化学电池在C / 4速率下具有至少约7mAh / cm 2的面积比容量。 在一些实施方案中，半固体阴极浆料具有至少约0.9的混合指数。

公开(公告)号：US09559375B2

公开(公告)日：2017-01-31

申请号：US14122885

申请日：2012-06-01

申请人： Robert F. Savinell ,  Jesse S. Wainright

发明人： Robert F. Savinell ,  Jesse S. Wainright

IPC分类号： H01M8/18 ,  H01M10/38 ,  H01M8/04 ,  H01M8/20

CPC分类号： H01M8/188 ,  H01M8/04186 ,  H01M8/20 ,  H01M10/38 ,  Y02E60/528

摘要： An iron based redox flow cell. The redox flow cell comprises a first half-cell comprising a first electrolyte providing a source of Fe2+ ions and an electrode disposed within the first half-cell; a second half-cell comprising a second electrolyte providing a source of Fe2+ and Fe3+ ions and an electrode disposed within the second half-cell; and a separator between the first and second half-cells, where (a) the second electrolyte comprises a Fe3+ stabilizing agent; (b) the first electrolyte comprises a hydrogen evolution suppressing agent; or (c) the first electrolyte comprises a hydrogen evolution suppressing agent, and the second electrolyte comprises a Fe3+ stabilizing agent.

摘要翻译： 铁基氧化还原流通池。 氧化还原流动池包括第一半电池，其包括提供Fe 2+离子源的第一电解质和设置在第一半电池内的电极; 第二半电池，包括提供Fe 2+和Fe 3+离子源的第二电解质和设置在第二半电池内的电极; 和第一和第二半电池之间的隔板，其中（a）第二电解质包含Fe 3+稳定剂; （b）第一电解质包含析氢抑制剂; 或（c）第一电解质包含析氢抑制剂，第二电解质包含Fe 3+稳定剂。

公开(公告)号：US20160359188A1

公开(公告)日：2016-12-08

申请号：US14913861

申请日：2014-09-03

申请人： SUMITOMO ELECTRIC INDUSTRIES, LTD.

发明人： Hiroyuki Nakaishi

IPC分类号： H01M8/18 ,  H01M8/0206 ,  H01M8/0228 ,  H01M8/20 ,  H01M8/2465

CPC分类号： H01M8/188 ,  H01M8/0206 ,  H01M8/0228 ,  H01M8/20 ,  H01M8/2465 ,  H01M10/4285 ,  Y02E60/528

摘要： Provided is a battery cell stack in which the electrical resistance between a current collector plate and an end bipolar plate is unlikely to increase when charging and discharging are repeated. A battery cell stack includes a current collector plate electrically connected to each of a pair of end bipolar plates located at both ends in the stacking direction. In the battery cell stack, two members in contact with each other between the current collector plate and the end bipolar plate are made of materials such that, when an accelerated test satisfying the following conditions 1 to 3 is performed, the electrical resistance value between the current collector plate and the end bipolar plate after the accelerated test is 1.05 times or less the electrical resistance value between the current collector plate and the end bipolar plate before the accelerated test: Condition 1 is that a cycle includes applying pressure over one minute to achieve a predetermined pressure, maintaining the predetermined pressure for one minute, and bringing the predetermined pressure back to the atmospheric pressure over one minute; Condition 2 is that the predetermined pressure is set to be the atmospheric pressure +0.1 MPa; and Condition 3 is that the number of cycles is set to 18.

公开(公告)号：US20160359187A1

公开(公告)日：2016-12-08

申请号：US14792681

申请日：2015-07-07

申请人： YUAN ZE UNIVERSITY ,  HOMYTECH CO., LTD.

发明人： CHI-YUAN LEE ,  CHIA-HUNG CHEN ,  CHIN-LUNG HSIEH ,  YEN-PU HUANG

IPC分类号： H01M8/18 ,  H01M8/04 ,  H01M8/20

CPC分类号： H01M8/188 ,  H01M8/0273 ,  H01M8/0432 ,  H01M8/0438 ,  H01M8/04552 ,  H01M8/04582 ,  H01M8/20 ,  Y02E60/528

摘要： A cell module includes an ion exchange membrane, a first electrode, a second electrode, a first current collector plate, and a second current collector plate. The first electrode and the second electrode are disposed at two sides of the ion exchange membrane, wherein a sensing element is disposed in the first electrode, and the first electrode includes an insulating frame. The first current collector plate is located at one side of the first electrode, and the second current collector plate is located at one side of the second electrode.

摘要翻译： 电池模块包括离子交换膜，第一电极，第二电极，第一集电板和第二集电板。 第一电极和第二电极设置在离子交换膜的两侧，其中感测元件设置在第一电极中，并且第一电极包括绝缘框架。 第一集电板位于第一电极的一侧，第二集电板位于第二电极的一侧。

公开(公告)号：US20160351926A1

公开(公告)日：2016-12-01

申请号：US14721674

申请日：2015-05-26

申请人： FU-TZU HSU ,  Chieh-Sen Tu

发明人： FU-TZU HSU ,  Chieh-Sen Tu

IPC分类号： H01M8/04 ,  H01M8/20 ,  H01M8/18

CPC分类号： H01M8/18 ,  H01M8/04291 ,  Y02E60/528

摘要： An electrolyte conveyance device for flow battery includes a first permanent magnet direct current (PMDC) motor, a second PMDC motor, a power-output shaft, a first screw rod conveyance unit, and a second screw rod conveyance unit. The power-output shaft is a common power-output shaft of the first and second PMDC motors for driving the first and second screw rod conveyance units to operate at the same time, so as to convey a positive and a negative electrolyte, respectively, from positive and negative electrolyte tanks to a battery cell of the flow battery. The first and second PMDC motors serve as filters on a charging and a discharging circuit of the flow battery, and are driven by the electrical energy of removed surges to operate for conveying the electrolytes without consuming the electrical energy stored in the flow battery.

摘要翻译： 用于流动电池的电解液输送装置包括第一永久磁铁直流（PMDC）电动机，第二PMDC电动机，动力输出轴，第一螺杆输送单元和第二螺杆输送单元。 动力输出轴是第一和第二PMDC电动机的公共动力输出轴，用于驱动第一和第二螺杆输送单元同时操作，以便分别将正极和负极电解质从 正极和负极的电解液罐到流动电池的电池单元。 第一和第二PMDC电动机用作流动电池的充电和放电电路上的滤波器，并且由除去的电涌的电能驱动以操作以输送电解质，而不消耗存储在流动电池中的电能。

公开(公告)号：US20160322662A1

公开(公告)日：2016-11-03

申请号：US15105286

申请日：2014-12-16

申请人： TREOFAN GERMANY GMBH & CO. KG

发明人： Bertram SCHMITZ ,  Detlef BUSCH ,  Melanie WISNIEWSKI

IPC分类号： H01M8/1069 ,  H01M8/1011 ,  H01M8/20 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1086 ,  H01M8/106 ,  H01M8/1067 ,  H01M8/18 ,  B29C55/14 ,  B29C47/00 ,  C08J5/22 ,  H01M8/1053

CPC分类号： H01M8/1083 ,  B29C48/0018 ,  B29C55/14 ,  B29K2023/12 ,  B29L2031/3468 ,  B29L2031/755 ,  C08J5/22 ,  C08J5/2231 ,  C08J2323/10 ,  C08J2323/12 ,  H01M2/1653 ,  H01M2/1686 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1053 ,  H01M8/106 ,  H01M8/1067 ,  H01M8/1081 ,  H01M8/1086 ,  H01M8/188 ,  H01M8/20 ,  H01M2008/1095 ,  H01M2300/008 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02E60/528 ,  Y02P70/56

摘要： The invention describes an ion exchange membrane formed from a biaxially orientated single or multiple-layered β-porous polypropylene film which comprises at least one β-nucleating agent and an ion-conducting polymer and has a Gurley value of at least 10000 s.

摘要翻译： 本发明描述了由双轴取向的单层或多层β-多孔聚丙烯膜形成的离子交换膜，其包含至少一种β-成核剂和离子导电聚合物，并且具有至少10000s的古利值。

公开(公告)号：US20160308233A1

公开(公告)日：2016-10-20

申请号：US14690224

申请日：2015-04-17

申请人： Battelle Memorial Institute

发明人： Tianbiao Liu ,  Bin Li ,  Xiaoliang Wei ,  Zimin Nie ,  Wei Wang ,  Jun Liu ,  Vincent L. Sprenkle

IPC分类号： H01M8/18 ,  H01M8/20

CPC分类号： H01M8/188 ,  H01M8/20 ,  H01M2300/0002 ,  Y02E60/528

摘要： An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.

摘要翻译： 水性氧化还原液流电池系统包括水性阴极电解液和阳极电解液。 含水阴极电解液可以包含（i）任选取代的硫脲或硝酰自由基化合物和（ii）阴极电解液水性支持溶液。 水性阳极电解液可以包含（i）金属阳离子或紫色化合物和（ii）阳极电解液水性支持溶液。 阴极电解液水性支持溶液和阳极电解液水性支持溶液独立地可以包括（i）质子源，（ii）卤素源，或（iii）质子源和卤素源。

公开(公告)号：US20160240868A1

公开(公告)日：2016-08-18

申请号：US15024344

申请日：2014-09-22

申请人： LOCKHEED MARTIN ADVANCED ENERGY STORAGE, LLC

发明人： Curtis WARRINGTON ,  Oleg GREBENYUK ,  Paravastu BADRINARAYANAN ,  Thomas H. MADDEN

IPC分类号： H01M8/0258 ,  H01M8/20

CPC分类号： H01M8/026 ,  H01M8/0223 ,  H01M8/0258 ,  H01M8/0263 ,  H01M8/20

摘要： The present inventions are directed to fluid flow assemblies, and systems incorporating such assemblies, each assembly comprising a conductive element disposed within a non-conductive element; the non-conductive element being characterized as framing the conductive central element and the elements together defining a substantially planar surface when engaged with one another; each of the conductive and non-conductive elements comprising channels which, when taken together, form a flow pattern on the substantially planar surface; and wherein the channels are restricted, terminated, or both restricted and terminated in the non-conductive element.

摘要翻译： 本发明涉及流体流动组件和包括这种组件的系统，每个组件包括设置在非导电元件内的导电元件; 所述非导电元件的特征在于，当所述导电中心元件和所述元件在彼此接合时限定基本平坦的表面; 导电和非导电元件中的每一个包括通道，当它们一起在基本平坦的表面上形成流动图案时; 并且其中所述通道在所述非导电元件中被限制，终止或者被限制和终止。

公开(公告)号：US20160218375A1

公开(公告)日：2016-07-28

申请号：US14840810

申请日：2015-08-31

申请人： 24M Technologies, Inc.

发明人： Yet-Ming CHIANG ,  W. Craig CARTER ,  Mihai DUDUTA ,  Pimpa LIMTHONGKUL

IPC分类号： H01M8/0234 ,  H01M8/0221 ,  H01M8/0206 ,  H01M8/0215 ,  H01M8/18 ,  H01M8/20

CPC分类号： H01M8/0234 ,  B60L11/1879 ,  H01M8/0206 ,  H01M8/0215 ,  H01M8/0221 ,  H01M8/0228 ,  H01M8/188 ,  H01M8/20 ,  Y02E60/528 ,  Y02T10/7005 ,  Y02T10/7011 ,  Y02T10/705

摘要： Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

摘要翻译： 描述了氧化还原流动装置，其包括正极集电器，负极集电器和分离所述正集电器和负极集电器的离子可渗透膜，所述正和负集电器被定位和布置以限定正电活性区和负电活性区; 其中所述正电活性区和负电活性区中的至少一个包含可流动的半固体组合物，其包含能够在电池操作期间吸收或释放所述离子的离子存储化合物颗粒，并且其中所述离子存储化合物颗粒具有多分散尺寸分布 其中最细颗粒以总体积的至少5体积％存在，至少比总体积的至少5体积％中存在的最大颗粒小5倍。