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公开(公告)号：US20150184087A1
公开(公告)日：2015-07-02
申请号：US14584514
申请日：2014-12-29
申请人： Luigi PATRON , Alberto MALANDRINO , Mario MOLINARI
发明人： Luigi PATRON , Alberto MALANDRINO , Mario MOLINARI
IPC分类号： C10G65/00
CPC分类号： C10G65/00 , C10G47/02 , C10G47/26 , C10G49/04 , C10G2300/1003 , C10G2300/1014 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/207 , Y02P30/20
摘要： A process for the conversion of heavy oils comprising sending the heavy oil to hydrotreatment, of the high severity type, in the presence of high concentrations of a suitable hydrogenation catalyst dispersed in slurry phase, effected in a suitable solid accumulation reactor capable of operating stably in the presence of solids deriving from and generated by the feedstock charged, wherein the hydrogen or mixtures thereof is fed at suitable flow-rates and suitably distributed, obtaining the conversion products in vapour phase directly in the reactor.
摘要翻译： 一种重油转化方法，包括在高浓度的分散在淤浆相中的合适的氢化催化剂存在下将重油送入高浓度类型的加氢处理剂，该合适的固体积聚反应器能够稳定地运行 由所加入的原料产生的固体的存在，其中氢气或其混合物以合适的流速进料并适当分布，直接在反应器中获得汽相转化产物。
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公开(公告)号：US20100200463A1
公开(公告)日：2010-08-12
申请号：US12601343
申请日：2008-05-19
申请人： Luigi Patron , Alberto Malandrino , Mario Molinari
发明人： Luigi Patron , Alberto Malandrino , Mario Molinari
CPC分类号： C10G65/00 , C10G47/02 , C10G47/26 , C10G49/04 , C10G2300/1003 , C10G2300/1014 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/207 , Y02P30/20
摘要： A process for the conversion of heavy oils comprising sending the heavy oil to hydrotreatment, of the high severity type, in the presence of high concentrations of a suitable hydrogenation catalyst dispersed in slurry phase, effected in a suitable solid accumulation reactor capable of operating stably in the presence of solids deriving from and generated by the feedstock charged, wherein the hydrogen or mixtures thereof is fed at suitable flow-rates and suitably distributed, obtaining the conversion products in vapour phase directly in the reactor.
摘要翻译： 一种重油转化方法，包括在高浓度的分散在淤浆相中的合适的氢化催化剂存在下将重油送入高浓度类型的加氢处理剂，该合适的固体积聚反应器能够稳定地运行 由所加入的原料产生的固体的存在，其中氢气或其混合物以合适的流速进料并适当分布，直接在反应器中获得汽相转化产物。
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3.发明申请公开(公告)号：US20070258878A1
公开(公告)日：2007-11-08
申请号：US11754672
申请日：2007-05-29
IPC分类号： C01B31/20
摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with the solid fed at its maximum oxidation degree (over-oxidized form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with the reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein the solid contains at least en one element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.
摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 还进料，其与以最大氧化度（过氧化形式）进料的固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还被供给水的第二反应区（R 2），其与还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体至少包含一种选自元素的元素，所述元素除了金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对， 其特征在于，在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。
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4.发明申请Process for the production of hydrogen and the co-production of carbon dioxide 审中-公开生产氢气和二氧化碳共同生产的方法公开(公告)号：US20050232859A1
公开(公告)日：2005-10-20
申请号：US11085583
申请日：2005-03-22
摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with said solid fed at its maximum oxidation degree (over-reduced form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with said reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein said solid contains at least on element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.
摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 其还进料，其与以最大氧化度（过度还原形式）进料的所述固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还进料水的第二反应区（R 2），其与所述还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体包含至少一种选自元素的元素，所述元素除了金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对，其特征在于 因为在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。
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5.发明申请公开(公告)号：US20070066855A1
公开(公告)日：2007-03-22
申请号：US11520694
申请日：2006-09-14
IPC分类号： C07C41/01
CPC分类号： B01D3/009 , C07C41/09 , C07C41/42 , Y02P20/127 , C07C43/043
摘要： Process for the production of dimethyl ether and the co-production of H2O, starting from methanol, substantially comprising a dehydration reaction of methanol carried out in a reactive distillation column with a packing of the re-active, structured and distillation type.
摘要翻译： 生产二甲醚的方法和从甲醇开始的H 2 O 2的共同生产，其基本上包括在反应性蒸馏塔中进行甲醇的脱水反应，所述反应蒸馏塔具有重活性 ，结构和蒸馏式。
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6.发明授权公开(公告)号：US07404942B2
公开(公告)日：2008-07-29
申请号：US11754672
申请日：2007-05-29
摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with the solid fed at its maximum oxidation degree (over-oxidized form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with the reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein the solid contains at least one element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.
摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 还进料，其与以最大氧化度（过氧化形式）进料的固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还被供给水的第二反应区（R 2），其与还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体包含至少一种选自元素的元素，所述元素除了所述金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对，其特征在于 因为在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。
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