利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

23 条记录 (耗时 0.019 秒)

    PROCESS FOR THE PRODUCTION OF HYDROGEN AND THE CO-PRODUCTION OF CARBON DIOXIDE
    1.
    发明申请
    PROCESS FOR THE PRODUCTION OF HYDROGEN AND THE CO-PRODUCTION OF CARBON DIOXIDE 失效
    生产氢气和二氧化碳的生产方法

    公开(公告)号：US20070258878A1

    公开(公告)日：2007-11-08

    申请号：US11754672

    申请日：2007-05-29

    申请人： Domenico SANFILIPPO ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    发明人： Domenico SANFILIPPO ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    IPC分类号： C01B31/20

    CPC分类号： C01B3/063 ,  Y02E60/36

    摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with the solid fed at its maximum oxidation degree (over-oxidized form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with the reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein the solid contains at least en one element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.

    摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 还进料，其与以最大氧化度（过氧化形式）进料的固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还被供给水的第二反应区（R 2），其与还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体至少包含一种选自元素的元素，所述元素除了金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对， 其特征在于，在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。

    Process for the production of hydrogen and the co-production of carbon dioxide
    2.
    发明申请
    Process for the production of hydrogen and the co-production of carbon dioxide 审中-公开
    生产氢气和二氧化碳共同生产的方法

    公开(公告)号：US20050232859A1

    公开(公告)日：2005-10-20

    申请号：US11085583

    申请日：2005-03-22

    申请人： Domenico Sanfilippo ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    发明人： Domenico Sanfilippo ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    IPC分类号： C01B32/50 ,  C01B3/06 ,  C01B3/26

    CPC分类号： C01B3/063 ,  Y02E60/36

    摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with said solid fed at its maximum oxidation degree (over-reduced form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with said reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein said solid contains at least on element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.

    摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 其还进料，其与以最大氧化度（过度还原形式）进料的所述固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还进料水的第二反应区（R 2），其与所述还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体包含至少一种选自元素的元素，所述元素除了金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对，其特征在于 因为在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。

    Process for the production of hydrogen and the co-production of carbon dioxide
    3.
    发明授权
    Process for the production of hydrogen and the co-production of carbon dioxide 失效
    生产氢气和二氧化碳共同生产的方法

    公开(公告)号：US07404942B2

    公开(公告)日：2008-07-29

    申请号：US11754672

    申请日：2007-05-29

    申请人： Domenico Sanfilippo ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    发明人： Domenico Sanfilippo ,  Franco Mizia ,  Alberto Malandrino ,  Stefano Rossini

    IPC分类号： C01B31/20 ,  C01B3/10 ,  C01B3/24

    CPC分类号： C01B3/063 ,  Y02E60/36

    摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with the solid fed at its maximum oxidation degree (over-oxidized form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with the reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein the solid contains at least one element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state, characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.

    摘要翻译： 用于生产氢气和在分开的流中共同生产二氧化碳的方法包括以下操作：将固体进料到第一反应区（R 1），其中液态或气态烃，优选天然气或甲烷为 还进料，其与以最大氧化度（过氧化形式）进料的固体反应，导致燃烧产物二氧化碳和水以及固体以其最小氧化度（还原形式）形成; 将还原形式的固体进料到还被供给水的第二反应区（R 2），其与还原形式的固体反应，以中等氧化度（氧化形式）产生氢气，蒸汽和固体; 将氧化形式的固体进料到也进料空气的第三反应区（R 3），从固体的进一步氧化中得到过热氧化形式的固体，以再循环至第一反应区 （R 1），其中所述固体包含至少一种选自元素的元素，所述元素除了所述金属状态之外具有至少三种不同的氧化态，因此能够以氧化态的顺序产生两个氧化还原对，其特征在于 因为在第一反应区（R 1）中，过氧化形式的固体和液态或气态烃以逆流方式进料。

    Integrated process for producing olefins from methane-containing gas mixtures
    5.
    发明授权
    Integrated process for producing olefins from methane-containing gas mixtures 失效
    从含甲烷气体混合物生产烯烃的综合方法

    公开(公告)号：US5430219A

    公开(公告)日：1995-07-04

    申请号：US128712

    申请日：1993-09-30

    申请人： Domenico Sanfilippo ,  Stefano Rossini

    发明人： Domenico Sanfilippo ,  Stefano Rossini

    IPC分类号： C07C5/333 ,  C07C2/84 ,  C07C5/32 ,  C07C11/02 ,  C07C2/00

    CPC分类号： C07C2/84 ,  C07C11/02 ,  C07C5/322 ,  C07C5/325 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/42 ,  Y02P20/125 ,  Y02P20/52

    摘要： Disclosed is an integrated process for producing olefins by starting from methane containing gas mixture, which process essentially comprises the following steps:converting methane into higher hydrocarbons by oxidative coupling carried out in the presence of air and/or oxygen;dehydrogenating, with the aid of a catalyst, said higher hydrocarbons, with an olefin-rich mixture being obtained;removing H.sub.2 O, CO.sub.2, CO and H.sub.2 from the resulting olefinic mixture;removing from said olefinic mixture any not converted methane, and recycling it upstream from the oxidating coupling;separating ethylene from the olefinic mixture;separating any not dehydrogenated ethane from the olefinic mixture.

    摘要翻译： 公开了一种通过从含甲烷气体混合物开始制备烯烃的综合方法，该方法基本上包括以下步骤：通过在空气和/或氧气存在下进行氧化偶合将甲烷转化成高级烃; 在催化剂的帮助下，将所述高级烃脱氢，得到富含烯烃的混合物; 从所得烯烃混合物中除去H 2 O，CO 2，CO和H 2; 从所述烯烃混合物中除去任何未转化的甲烷，并将其从氧化偶合器的上游再循环; 从烯烃混合物中分离乙烯; 从烯烃混合物中分离任何未脱氢的乙烷。

    Process for the removal of contaminant compounds containing one or more heteroatoms of sulfur, nitrogen and/or oxygen from hydrocarbon streams
    7.
    发明授权
    Process for the removal of contaminant compounds containing one or more heteroatoms of sulfur, nitrogen and/or oxygen from hydrocarbon streams 失效
    从烃流中除去含有一个或多个硫，氮和/或氧的杂原子的污染化合物的方法

    公开(公告)号：US6118037A

    公开(公告)日：2000-09-12

    申请号：US56628

    申请日：1998-04-08

    申请人： Valerio Piccoli ,  Stefano Rossini ,  Domenico Sanfilippo

    发明人： Valerio Piccoli ,  Stefano Rossini ,  Domenico Sanfilippo

    IPC分类号： C07C7/12 ,  C10G25/00 ,  C10G25/12 ,  C10G53/08 ,  B01J20/02 ,  B01J20/10 ,  B01J20/34 ,  C10C25/00

    CPC分类号： C10G25/12 ,  C07C7/12 ,  C10G25/00 ,  C10G25/003 ,  C10G53/08

    摘要： Process for the removal of contaminant compounds containing one or more heteroatoms of sulfur, nitrogen and/or oxygen from hydrocarbon streams characterized in that it comprises:an adsorption step in which said compounds are adsorbed by means of an adsorber essentially consisting of silica gel, possibly modified with one or more metals selected from the elements of groups IVb, Vb, VIb, VIII, Ib, IIb or from tin, lead or bismuth, carried out at a temperature of between 0.degree. and 150.degree. C. and at a pressure of between 1 and 20 atm;an optional washing step with polar solvents or hydrocarbons;and a regeneration step for removing the substances adsorbed by means of thermal treatment in a flow of inert gas carried out at a temperature of between 100.degree. and 200.degree. C.

    摘要翻译： 从烃流中除去含有一个或多个硫，氮和/或氧的杂原子的污染化合物的方法，其特征在于其包括：吸附步骤，其中所述化合物通过基本上由硅胶组成的吸附剂吸附，可能 用选自元素IVb，Vb，VIb，VIII，Ib，IIb中的一种或多种金属或锡，铅或铋进行改性，在0〜150℃的温度和 1至20 atm之间; 可选的洗涤步骤与极性溶剂或烃类; 以及在100〜200℃的温度下进行的惰性气体流中除去通过热处理吸附的物质的再生步骤。

    PROCESS FOR STABILIZING THE PERFORMANCES OF A CATALYST FOR FISCHER TROPSCH REACTION
    9.
    发明申请
    PROCESS FOR STABILIZING THE PERFORMANCES OF A CATALYST FOR FISCHER TROPSCH REACTION 有权
    用于稳定FISCHER TROPSCH反应的催化剂性能的方法

    公开(公告)号：US20110039953A1

    公开(公告)日：2011-02-17

    申请号：US12811383

    申请日：2008-12-29

    申请人： Andrea Tasso ,  Stefano Rossini ,  Paolo Pollesel

    发明人： Andrea Tasso ,  Stefano Rossini ,  Paolo Pollesel

    IPC分类号： C07C1/06

    CPC分类号： C10G2/342 ,  B01J8/22 ,  B01J23/8476 ,  B01J23/8913 ,  B01J35/023 ,  B01J35/1061 ,  B01J2219/00162 ,  C07C1/047 ,  C10G2/332

    摘要： Process for maintaining the stability of performances of a catalyst for Fischer-Tropsch reaction, performed in a slurry bubble column reactor under a triphase system which comprises gradually increasing the PH2O/PH2 ratio and the PH2O/Z ratio, during the start-up phase, with Z=P0·(T/T1)4·e−(K2/(t·K3)) from 0.4 to 0.8, for a period of time not shorter than 100-150 hrs and not longer than 200-300 hours and, at the end of the start-up phase, maintaining the PH2O/PH2 and PH2O/Z ratios substantially equal to or lower than 0.8.

    摘要翻译： 用于维持费 - 托反应催化剂性能的稳定性的方法，其在三相体系中的淤浆鼓泡塔反应器中进行，其包括在起动阶段逐渐增加PH 2 O / PH 2比和PH 2 O / Z比， Z = P0·（T / T1）4·e-（K2 /（t·K3））为0.4〜0.8，时间不低于100-150小时，不大于200-300小时， 在启动阶段结束时，保持PH2O / PH2和PH2O / Z比基本上等于或低于0.8。